module generic_cloud_common_h use comcstfi_mod, only: r, cpp, mugaz implicit none real, save :: m ! molecular mass of the specie (g/mol) real, save :: delta_vapH ! Enthalpy of vaporization (J/mol) real,save :: Tref ! Ref temperature for Clausis-Clapeyron (K) real,save :: Pref ! Reference pressure for Clausius Clapeyron (Pa) real, save :: epsi ! fractionnal molecular mass (m/mugaz) real,save :: RLVTT !Latent heat of vaporization (J/kg) real,save :: metallicity_coeff ! Coefficient to take into account the metallicity contains subroutine specie_parameters(specname) implicit none !============================================================================ ! Load the adequate set of parameters for specname ! We use Clausius Clapeyron. ! Values are based on Vissher (2010) and Morley (2012). ! ! Also set up few others useful parameters, such as epsi=m/mugaz, RLVTT and ! the metallicity_coeff. ! Authors ! -------- ! Lucas Teinturier (2022) !============================================================================ ! Inputs character(*), intent(in) :: specname print*,"entree dans specie_parameters avec specname = ",specname if (trim(specname) .eq. "Mg") then print*,"Loading data for Mg" delta_vapH = 521.7E3 !J/mol Tref = 2303.0 !K Pref = 1.0E5 !in Pa m = 140.6931 RLVTT = delta_vapH/(m/1000.) metallicity_coeff=1.0*log(10.0) else if (trim(specname) .eq. "Na") then print*,"Loading data for Na" delta_vapH = 265.9E3 Tref = 1624.0 Pref = 1.0E5 m = 78.04454 !Na2S RLVTT = delta_vapH/(m/1000.) metallicity_coeff=0.5*log(10.0) else if (trim(specname) .eq. "Fe") then print*,"Loading data for Fe" delta_vapH = 401.9E3 Tref = 2903.0 Pref = 1.0E5 m = 55.8450 RLVTT = delta_vapH/(m/1000.) metallicity_coeff=0.0*log(10.0) else if (trim(specname) .eq. "Cr") then print*,"Loading data for Cr" delta_vapH = 394.2E3 Tref = 2749.0 Pref = 1.0E5 m = 51.9961 RLVTT = delta_vapH/(m/1000.) metallicity_coeff=0.0*log(10.0) else if (trim(specname) .eq. "KCl") then print*,"Loading data for KCl" delta_vapH = 217.9E3 Tref = 1495.0 Pref = 1.0E5 metallicity_coeff=0.0*log(10.0) m = 74.5498 RLVTT = delta_vapH/(m/1000.) else if (trim(specname) .eq. "Mn") then print*,"Loading data for Mn" delta_vapH = 455.8E3 Tref = 2064.0 Pref = 1.0E5 metallicity_coeff=1.0*log(10.0) m = 87.003049 RLVTT = delta_vapH/(m/1000.) else if (trim(specname) .eq. "Zn") then print*,"Loading data for Zn" delta_vapH = 303.9E3 Tref = 1238.0 Pref = 1.0E5 metallicity_coeff=1.0*log(10.0) m = 97.445 RLVTT = delta_vapH/(m/1000.) else print*,"Unknow species (not in Mg, Fe, Na, KCl, Cr, Mn or Zn)" endif epsi = m/mugaz end subroutine specie_parameters subroutine specie_parameters_table(specname) implicit none !============================================================================ ! Load the adequate set of parameters for specname ! From a table of traceurs ! ! Also set up few others useful parameters, such as epsi=m/mugaz, RLVTT and ! the metallicity_coeff. ! Authors ! -------- ! Noé Clément (2022) !============================================================================ character(*), intent(in) :: specname integer :: ios character(len=500):: table_traceurs_line ! table_traceurs_line lines with parameters open(117,file='table_tracers_condensable',form='formatted',status='old') read(117,'(A)') table_traceurs_line do read(117,'(A)', iostat=ios) table_traceurs_line if (index(table_traceurs_line,specname) /= 0) then if (index(table_traceurs_line,'delta_vapH=' ) /= 0) then read(table_traceurs_line(index(table_traceurs_line,'delta_vapH=')+len('delta_vapH='):),*) delta_vapH print*, 'delta_vapH ', delta_vapH end if if (index(table_traceurs_line,'Tref=' ) /= 0) then read(table_traceurs_line(index(table_traceurs_line,'Tref=')+len('Tref='):),*) Tref print*, 'Tref', Tref end if if (index(table_traceurs_line,'Pref=' ) /= 0) then read(table_traceurs_line(index(table_traceurs_line,'Pref=')+len('Pref='):),*) Pref print*, 'Pref', Pref end if if (index(table_traceurs_line,'mass=' ) /= 0) then read(table_traceurs_line(index(table_traceurs_line,'mass=')+len('mass='):),*) m print*, 'mass', m end if if (index(table_traceurs_line,'metallicity_coeff=' ) /= 0) then read(table_traceurs_line(index(table_traceurs_line,'metallicity_coeff=')+len('metallicity_coeff='):),*) metallicity_coeff print*, 'metallicity_coeff', metallicity_coeff end if ios=1 end if if (ios /= 0) exit end do ! RLVTT !if (is_master) close(117) RLVTT=delta_vapH/(m/1000.) write(*,*) 'RLVTT', RLVTT epsi = m/mugaz end subroutine specie_parameters_table subroutine Psat_generic(T,p,metallicity,psat,qsat) IMPLICIT NONE !============================================================================ ! Clausius-Clapeyron relation : ! d(Ln(psat))/dT = delta_vapH/(RT^2) ! ->Psat = Pref * exp(-delta_vapH/R*(1/T-1/Tref)) ! ! Authors ! -------- ! Lucas Teinturier (2022) adapted from Psat_water of Jeremy Leconte (2012) !============================================================================ !Inputs real, intent(in) :: T, p ! Temperature and pressure of the layer (in K and Pas) real, intent(in) :: metallicity ! metallycity (log10) !Outputs real, intent(out) :: psat,qsat !saturation vapor pressure (Pa) and mass mixing ratio at saturation (kg/kg) of the layer psat = pref*exp(-delta_vapH/(r*mugaz/1000.)*(1/T-1/Tref)-metallicity_coeff*metallicity) ! in Pa (because pref in Pa) if (psat .gt. p) then qsat = 1. else qsat = epsi *psat/(p-(1-epsi)*psat) endif end subroutine Psat_generic subroutine Lcpdqsat_generic(T,p,psat,qsat,dqsat,dlnpsat) implicit none !=============================================================================== ! Compute dqsat = L/cp* d(qsat)/dT and d(Ln(psat)) = L/cp*d(Ln(psat))/dT ! we have d(ln(psat))/dT = delta_vapH/R*(1/T^2) for clausius-clapeyron ! r*mugaz/1000. is the perfect gaz constant in the computation of "dummy" ! Authors ! -------- ! Lucas Teinturier (2022) adapted from Lcpdqsat_water of Jeremy Leconte (2012) !=============================================================================== ! Inputs real, intent(in) :: T ! Temperature (K) real, intent(in) :: p ! Pressure (Pa) real, intent(in) :: psat ! Saturation vapor pressure (Pa) real, intent(in) :: qsat ! Mass mixing ratio at saturation (kg/kg) ! Outputs real, intent(out) :: dqsat,dlnpsat ! Variables real :: dummy ! used to store d(ln(psat))/dT dummy = delta_vapH/((r*mugaz/1000.)*(T**2)) if (psat .gt. p) then dqsat =0. else dqsat = (RLVTT/cpp) *qsat*(p/(p-(1-epsi)*psat))*dummy dlnpsat = (RLVTT/cpp) * dummy endif end subroutine Lcpdqsat_generic end module generic_cloud_common_h