c********************************************************************** subroutine paramfoto_compact $(ig,nlayer,chemthermod,lswitch,tx,timestep,zenit,zx,rm,nesptherm) c may 2008 FGG+MALV,GG c********************************************************************** use iono_h use param_v4_h implicit none c arguments integer lswitch,ig,nesptherm,chemthermod,nlayer real zdens(nlayer) real tx(nlayer) real zenit real zx(nlayer) real rm(nlayer,nesptherm) real timestep c local variables real*8 deltat,timefrac_sec real*8 co2xnew,o2xnew,o3pxnew,coxnew,hxnew,ohxnew real*8 ho2xnew,h2xnew real*8 h2o2xnew,o1dxnew,o3xnew,h2oxnew real*8 noxnew, nxnew, n2xnew, n2dxnew,no2xnew real*8 oplusxnew, o2plusxnew,co2plusxnew real*8 nplusxnew, n2plusxnew,noplusxnew, hplusxnew real*8 electxnew,coplusxnew, cplusxnew, hco2plusxnew real*8 co2xoutput,o2xoutput,o3pxoutput,coxoutput real*8 ho2xoutput,h2xoutput,hxoutput,ohxoutput real*8 h2o2xoutput,o1dxoutput,o3xoutput,h2oxoutput real*8 nxoutput,noxoutput,n2xoutput,n2dxoutput,no2xoutput real*8 co2plusxoutput,coplusxoutput,oplusxoutput,o2plusxoutput real*8 cplusxoutput,noplusxoutput,n2plusxoutput,hplusxoutput real*8 electxoutput,nplusxoutput,hco2plusxoutput real*8 electxoutput_timemarching, electxoutput_neutrality real*8 co2xinput,o2xinput,o3pxinput,coxinput real*8 ho2xinput,h2xinput,hxinput,ohxinput real*8 h2o2xinput,o1dxinput,o3xinput,h2oxinput real*8 nxinput,noxinput,n2xinput,n2dxinput,no2xinput real*8 co2plusxinput,coplusxinput,oplusxinput,o2plusxinput real*8 cplusxinput,noplusxinput,n2plusxinput,hplusxinput real*8 electxinput,nplusxinput,hco2plusxinput real*8 co2xini,o2xini,o3pxini,coxini real*8 ho2xini,h2xini,hxini,ohxini real*8 h2o2xini,o1dxini,o3xini,h2oxini real*8 nxini,noxini,n2xini,n2dxini,no2xini real*8 co2plusxini,coplusxini,oplusxini,o2plusxini real*8 cplusxini,noplusxini,n2plusxini,hplusxini real*8 electxini,nplusxini,hco2plusxini real*8 dco2x,do2x,do3px,dcox,dhx,dohx,dho2x,dh2x real*8 dh2ox,dh2o2x,do1dx,do3x,dnx,dnox,dn2x,dn2dx,dno2x real*8 dco2plusx,dcoplusx,doplusx,do2plusx real*8 dcplusx,dnoplusx,dn2plusx,dhplusx,dhco2plusx real*8 delectx,dnplusx real*8 jdistot8(nabs,nlayer) real*8 jdistot8_b(nabs,nlayer) real*8 jion8(nabs,nlayer,4) real*8 tx8 real*8 alfa_laststep, IonMostAbundant real*8 tmin(nlayer) real*8 fmargin1,critere integer compmin(nlayer) integer i,j,k integer numpasos integer n_comp_en_EQ(nlayer), paso ! Tracer indexes in the thermospheric chemistry: !!! ATTENTION. These values have to be identical to those in chemthermos.F90 !!! If the values are changed there, the same has to be done here !!! integer,parameter :: i_co2=1 integer,parameter :: i_o2=2 integer,parameter :: i_o=3 integer,parameter :: i_co=4 integer,parameter :: i_h=5 integer,parameter :: i_oh=6 integer,parameter :: i_ho2=7 integer,parameter :: i_h2=8 integer,parameter :: i_h2o=9 integer,parameter :: i_h2o2=10 integer,parameter :: i_o1d=11 integer,parameter :: i_o3=12 integer,parameter :: i_n2=13 integer,parameter :: i_n=14 integer,parameter :: i_no=15 integer,parameter :: i_n2d=16 integer,parameter :: i_no2=17 integer,parameter :: i_co2plus=18 integer,parameter :: i_oplus=19 integer,parameter :: i_o2plus=20 integer,parameter :: i_coplus=21 integer,parameter :: i_cplus=22 integer,parameter :: i_nplus=23 integer,parameter :: i_noplus=24 integer,parameter :: i_n2plus=25 integer,parameter :: i_hplus=26 integer,parameter :: i_hco2plus=27 integer,parameter :: i_elec=28 c formats c********************************************************************** C Start: altitude loop timefrac_sec=dble(timestep) do i=nlayer,lswitch,-1 c Concentrations to real*8 c Hay dos maneras de adaptar estos a los flags fotoquimicos: c 1. Se definen todas las concentraciones, dejando como 0 las que no c se utilicen en la quimica requerida. Esto es posiblemente lo mas c sencillo, ya que no habria que modificar las llamadas a las subrutinas c pero puede ser menos seguro y mas caro computacionalmente c 2. Se definen nuevas variables rmini, rminput, rmoutput como arrays c con dimension ajustable al numero de compuestos. Esto es posiblemente c mas seguro, compacto y rapido, pero implica cambiar las llamadas a c todas las subrutinas. c Empiezo probando la primera manera. tx8=dble(tx(i)) co2xini=dble(rm(i,i_co2)) o2xini=dble(rm(i,i_o2)) o3pxini=dble(rm(i,i_o)) coxini=dble(rm(i,i_co)) hxini=dble(rm(i,i_h)) ohxini=dble(rm(i,i_oh)) ho2xini=dble(rm(i,i_ho2)) h2xini=dble(rm(i,i_h2)) h2oxini=dble(rm(i,i_h2o)) h2o2xini=dble(rm(i,i_h2o2)) o1dxini=dble(rm(i,i_o1d)) !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) o3xini=dble(rm(i,i_o3)) !Only if N or ion chemistry requested if(chemthermod.ge.2) then n2xini=dble(rm(i,i_n2)) nxini=dble(rm(i,i_n)) noxini=dble(rm(i,i_no)) n2dxini=dble(rm(i,i_n2d)) no2xini=dble(rm(i,i_no2)) endif !Only if ion chemistry requested if(chemthermod.eq.3) then co2plusxini=dble(rm(i,i_co2plus)) oplusxini=dble(rm(i,i_oplus)) o2plusxini=dble(rm(i,i_o2plus)) coplusxini=dble(rm(i,i_coplus)) cplusxini=dble(rm(i,i_cplus)) nplusxini=dble(rm(i,i_nplus)) n2plusxini=dble(rm(i,i_n2plus)) noplusxini=dble(rm(i,i_noplus)) hplusxini=dble(rm(i,i_hplus)) hco2plusxini=dble(rm(i,i_hco2plus)) electxini=dble(rm(i,i_elec)) endif !Calculation of photodissociation and photoionization rates !from photoabsorption rates and ionization-to-dissociation !branching ratios call phdisrate(ig,nlayer,chemthermod,zenit,i) ! Conversion to double precision do j=1,nabs jdistot8(j,i) = dble(jdistot(j,i)) jdistot8_b(j,i) = dble(jdistot_b(j,i)) do k=1,4 jion8(j,i,k)=dble(jion(j,i,k)) enddo end do !Reaction rates call getch( ig, chemthermod,tx8, zx(i)) !Lifetimes and temporal integration call lifetimes(ig,i,nlayer,chemthermod,zenit,zx, $ jdistot8,jdistot8_b,jion8, $ tmin(i),compmin(i), $ n_comp_en_EQ(i),co2xini,o2xini,o3pxini,coxini,hxini, $ ohxini,ho2xini,h2xini,h2oxini,h2o2xini,o1dxini,o3xini, $ n2xini,nxini,noxini,no2xini,n2dxini,co2plusxini,oplusxini, $ o2plusxini,coplusxini,cplusxini,nplusxini,noplusxini, $ n2plusxini,hplusxini,hco2plusxini,electxini ) !Calculation of the internal timestep and revision of the !validity of the photochemical equilibrium approximation !for each species ! JYC criteria added to avoid instabilities in (H) + (O+) <-> (H+) + (O) reactions when H+ is important fmargin1=5 !Only if ion chemistry requested if(chemthermod.eq.3) then critere=hplusxini/(o3pxini+hxini+h2xini) if (critere .gt. 5d-4) then fmargin1=2000.*critere if (fmargin1 .gt. 50.) fmargin1=50 ! print*,'long time step chimie',ig,i,critere,fmargin1 endif endif !Of chemthermod.eq.3 call timemarching ( ig,i,nlayer,chemthermod,n_comp_en_EQ, . compmin,tmin,timefrac_sec, deltat,fmargin1) !Number of timesteps numpasos = int( timefrac_sec / deltat ) alfa_laststep = 1.d0 + timefrac_sec/deltat - dble(numpasos) do paso=1,numpasos !Concentrations at the first step if(paso.eq.1) then co2xinput=co2xini o2xinput=o2xini o3pxinput=o3pxini coxinput=coxini hxinput=hxini ohxinput=ohxini ho2xinput=ho2xini h2xinput=h2xini h2oxinput=h2oxini h2o2xinput=h2o2xini o1dxinput=o1dxini o3xinput=o3xini nxinput=nxini noxinput=noxini n2xinput=n2xini n2dxinput=n2dxini no2xinput=no2xini ! co2plusxinput = co2plusxini oplusxinput = oplusxini o2plusxinput = o2plusxini coplusxinput = coplusxini cplusxinput = cplusxini nplusxinput = nplusxini n2plusxinput = n2plusxini noplusxinput = noplusxini hplusxinput = hplusxini hco2plusxinput= hco2plusxini electxinput = electxini else !Concentrations for the new step co2xinput=co2xinput+dco2x o2xinput=o2xinput+do2x o3pxinput=o3pxinput+do3px coxinput=coxinput+dcox hxinput=hxinput+dhx ohxinput=ohxinput+dohx ho2xinput=ho2xinput+dho2x h2xinput=h2xinput+dh2x h2oxinput=h2oxinput+dh2ox h2o2xinput=h2o2xinput+dh2o2x o1dxinput=o1dxinput+do1dx !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) o3xinput=o3xinput+do3x !Only if N or ion chemistry requested if(chemthermod.ge.2) then nxinput=nxinput+dnx noxinput=noxinput+dnox n2xinput=n2xinput+dn2x n2dxinput=n2dxinput+dn2dx no2xinput=no2xinput+dno2x endif !Only if ion chemistry requested if(chemthermod.eq.3) then co2plusxinput = co2plusxinput + dco2plusx oplusxinput = oplusxinput + doplusx o2plusxinput = o2plusxinput + do2plusx coplusxinput = coplusxinput + dcoplusx cplusxinput = cplusxinput + dcplusx nplusxinput = nplusxinput + dnplusx n2plusxinput = n2plusxinput + dn2plusx noplusxinput = noplusxinput + dnoplusx hplusxinput = hplusxinput + dhplusx hco2plusxinput= hco2plusxinput+ dhco2plusx electxinput = electxinput + delectx endif end if !Calculation of productions and losses call prodsandlosses (ig,i,nlayer,chemthermod,zenit, zx, & jdistot8, jdistot8_b, jion8, & co2xinput, o2xinput, o3pxinput, & coxinput, h2xinput, o3xinput, & h2oxinput, nxinput, noxinput, & h2o2xinput, n2xinput, & o1dxinput, ohxinput, ho2xinput, & hxinput, n2dxinput, no2xinput, & co2plusxinput, o2plusxinput, coplusxinput, & oplusxinput, cplusxinput, noplusxinput, & n2plusxinput, hplusxinput, nplusxinput, & hco2plusxinput,electxinput ) !New abundances, implicit scheme for the timemarching !First, for the 11 species that can not be in PE !( CO2, O2, O3P, CO, H2, H2O, H2O2, O3, N, NO, N2 ) call implicito ( ig, co2xoutput, ' CO2', & co2xinput, Pco2tot(i), Lco2tot(i), deltat ) call implicito ( ig, o2xoutput, ' O2', & o2xinput, Po2tot(i), Lo2tot(i), deltat ) call implicito ( ig, o3pxoutput, ' O3P', & o3pxinput, Po3ptot(i), Lo3ptot(i), deltat ) call implicito ( ig, coxoutput, ' CO', & coxinput, Pcotot(i), Lcotot(i), deltat ) call implicito ( ig, h2xoutput, ' H2', & h2xinput, Ph2tot(i), Lh2tot(i), deltat ) call implicito ( ig, h2oxoutput, ' H2O', & h2oxinput, Ph2otot(i), Lh2otot(i), deltat ) call implicito ( ig, h2o2xoutput, 'H2O2', & h2o2xinput, Ph2o2tot(i), Lh2o2tot(i), deltat ) !only if O3, N or ion chemistry requested if(chemthermod.ge.1) $ call implicito ( ig, o3xoutput, ' O3', & o3xinput, Po3tot(i), Lo3tot(i), deltat ) !Only if N or ion chemistry requested if(chemthermod.ge.2) then call implicito ( ig, nxoutput, ' N', & nxinput, Pntot(i), Lntot(i), deltat ) call implicito ( ig, noxoutput, ' NO', & noxinput, Pnotot(i), Lnotot(i), deltat ) call implicito ( ig, n2xoutput, ' N2', & n2xinput, Pn2tot(i), Ln2tot(i), deltat ) endif !Second, 6+10 species that can be in PE, but are not ! 6 neutral , O1D, OH, HO2, H, N2D, NO2 if(o1d_eq(i).eq.'N') then call implicito ( ig, o1dxoutput, ' O1D', & o1dxinput, Po1dtot(i), Lo1dtot(i), deltat ) end if if(oh_eq(i).eq.'N') then call implicito ( ig, ohxoutput, ' OH', & ohxinput, Pohtot(i), Lohtot(i), deltat ) end if if(ho2_eq(i).eq.'N') then call implicito ( ig, ho2xoutput, ' HO2', & ho2xinput, Pho2tot(i), Lho2tot(i), deltat ) end if if(h_eq(i).eq.'N') then call implicito ( ig, hxoutput, ' H', & hxinput, Phtot(i), Lhtot(i), deltat ) end if !Only if N or ion chemistry requested if(chemthermod.ge.2) then if(n2d_eq(i).eq.'N') then call implicito ( ig, n2dxoutput, ' N2D', & n2dxinput, Pn2dtot(i), Ln2dtot(i), deltat ) end if if(no2_eq(i).eq.'N') then call implicito ( ig, no2xoutput, ' NO2', & no2xinput, Pno2tot(i), Lno2tot(i), deltat ) end if endif ! 9 ions (all of them) and electrons !Only if ion chemistry requested if(chemthermod.ge.3) then if(n2plus_eq(i).eq.'N') then call implicito ( ig, n2plusxoutput, ' N2+', & n2plusxinput,Pn2plustot(i),Ln2plustot(i),deltat) end if if(cplus_eq(i).eq.'N') then call implicito ( ig, cplusxoutput, ' C+', & cplusxinput,Pcplustot(i),Lcplustot(i),deltat) end if if(coplus_eq(i).eq.'N') then call implicito ( ig, coplusxoutput, ' CO+', & coplusxinput,Pcoplustot(i),Lcoplustot(i),deltat) end if if(co2plus_eq(i).eq.'N') then call implicito ( ig, co2plusxoutput, 'CO2+', & co2plusxinput,Pco2plustot(i),Lco2plustot(i),deltat) end if if(oplus_eq(i).eq.'N') then call implicito ( ig, oplusxoutput, ' O+', & oplusxinput,Poplustot(i),Loplustot(i),deltat) end if if(hplus_eq(i).eq.'N') then call implicito ( ig, hplusxoutput, ' H+', & hplusxinput,Phplustot(i),Lhplustot(i),deltat) end if if(o2plus_eq(i).eq.'N') then call implicito ( ig, o2plusxoutput, ' O2+', & o2plusxinput,Po2plustot(i),Lo2plustot(i),deltat) end if if(noplus_eq(i).eq.'N') then call implicito ( ig, noplusxoutput, ' NO+', & noplusxinput,Pnoplustot(i),Lnoplustot(i),deltat) end if if(nplus_eq(i).eq.'N') then call implicito ( ig, nplusxoutput, ' N+', & nplusxinput,Pnplustot(i),Lnplustot(i),deltat) end if if(hco2plus_eq(i).eq.'N') then call implicito ( ig, hco2plusxoutput, 'CO2+', & hco2plusxinput,Phco2plustot(i),Lhco2plustot(i), $ deltat) end if ! elect call implicito ( ig, electxoutput_timemarching, 'elec', & electxinput,Pelecttot(i),Lelecttot(i),deltat) endif !Of chemthermod.eq.3 !Third, those species (among the 16 that can be in PE) that are in PE call EF_oscilacion & ( ig,i,nlayer, paso,chemthermod,zenit, zx, & jdistot8, jdistot8_b,jion8, & deltat, $ co2xoutput, co2xinput, $ o2xoutput, o2xinput, $ o3pxoutput, o3pxinput, $ coxoutput, coxinput, $ h2xoutput, h2xinput, $ h2oxoutput, h2oxinput, $ h2o2xoutput, h2o2xinput, $ o3xoutput, o3xinput, $ nxoutput, nxinput, $ noxoutput, noxinput, $ n2xoutput, n2xinput, & o1dxoutput, o1dxinput, & ohxoutput, ohxinput, & ho2xoutput, ho2xinput, & hxoutput, hxinput, & n2dxoutput, n2dxinput, & no2xoutput, no2xinput, & co2plusxoutput, co2plusxinput, & o2plusxoutput, o2plusxinput, & coplusxoutput, coplusxinput, & oplusxoutput, oplusxinput, & cplusxoutput, cplusxinput, & noplusxoutput, noplusxinput, & n2plusxoutput, n2plusxinput, & hplusxoutput, hplusxinput, & nplusxoutput, nplusxinput, $ hco2plusxoutput,hco2plusxinput, & electxoutput, electxinput, & electxoutput_timemarching ) !Electrons given by the condition of global neutrality !Only if ion chemistry requested if(chemthermod.eq.3) then electxoutput = o2plusxoutput + @ co2plusxoutput + @ coplusxoutput + @ oplusxoutput + @ cplusxoutput + @ n2plusxoutput + @ nplusxoutput + @ noplusxoutput + @ hplusxoutput + $ hco2plusxoutput electxoutput_neutrality = electxoutput ! IonMostAbundant = o2plusxoutput IonMostAbundant = max( co2plusxoutput, IonMostAbundant) IonMostAbundant = max( coplusxoutput, IonMostAbundant) IonMostAbundant = max( oplusxoutput, IonMostAbundant) IonMostAbundant = max( cplusxoutput, IonMostAbundant) IonMostAbundant = max( n2plusxoutput, IonMostAbundant) IonMostAbundant = max( noplusxoutput, IonMostAbundant) IonMostAbundant = max( nplusxoutput, IonMostAbundant) IonMostAbundant = max( hplusxoutput, IonMostAbundant) IonMostAbundant = max( hco2plusxoutput, IonMostAbundant) IonMostAbundant = IonMostAbundant / electxoutput endif !Of chemthermod.eq.3 !Concentration changes for this time step dco2x=co2xoutput-co2xinput do2x=o2xoutput-o2xinput do3px=o3pxoutput-o3pxinput dcox=coxoutput-coxinput dhx=hxoutput-hxinput dohx=ohxoutput-ohxinput dho2x=ho2xoutput-ho2xinput dh2x=h2xoutput-h2xinput dh2ox=h2oxoutput-h2oxinput dh2o2x=h2o2xoutput-h2o2xinput do1dx=o1dxoutput-o1dxinput !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) do3x=o3xoutput-o3xinput !Only if N or ion chemistry requested if(chemthermod.ge.2) then dnx=nxoutput-nxinput dnox=noxoutput-noxinput dn2x=n2xoutput-n2xinput dn2dx=n2dxoutput-n2dxinput dno2x=no2xoutput-no2xinput endif !Only if ion chemistry requested if(chemthermod.eq.3) then dco2plusx=co2plusxoutput-co2plusxinput do2plusx=o2plusxoutput-o2plusxinput doplusx=oplusxoutput-oplusxinput dcoplusx=coplusxoutput-coplusxinput dcplusx=cplusxoutput-cplusxinput dnplusx=nplusxoutput-nplusxinput dn2plusx=n2plusxoutput-n2plusxinput dnoplusx=noplusxoutput-noplusxinput dhplusx=hplusxoutput-hplusxinput dhco2plusx=hco2plusxoutput-hco2plusxinput delectx=electxoutput- electxinput endif if(paso.eq.numpasos) then !Final concentrations after last time step co2xnew = co2xinput + dco2x * alfa_laststep if(co2xnew.lt.0)co2xnew=1.e-30 o2xnew = o2xinput + do2x * alfa_laststep if(o2xnew.lt.0)o2xnew=1.e-30 o3pxnew = o3pxinput + do3px * alfa_laststep if(o3pxnew.lt.0)o3pxnew=1.e-30 coxnew = coxinput + dcox * alfa_laststep if(coxnew.lt.0)coxnew=1.e-30 hxnew = hxinput + dhx * alfa_laststep if(hxnew.lt.0)hxnew=1.e-30 ohxnew = ohxinput + dohx * alfa_laststep if(ohxnew.lt.0)ohxnew=1.e-30 ho2xnew = ho2xinput + dho2x * alfa_laststep if(ho2xnew.lt.0)ho2xnew=1.e-30 h2xnew = h2xinput + dh2x * alfa_laststep if(h2xnew.lt.0)h2xnew=1.e-30 h2oxnew = h2oxinput + dh2ox * alfa_laststep if(h2oxnew.lt.0)h2oxnew=1.e-30 h2o2xnew = h2o2xinput + dh2o2x * alfa_laststep if(h2o2xnew.lt.0)h2o2xnew=1.e-30 o1dxnew = o1dxinput + do1dx * alfa_laststep if(o1dxnew.lt.0)o1dxnew=1.e-30 !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) then o3xnew = o3xinput + do3x * alfa_laststep if(o3xnew.lt.0)o3xnew=1.e-30 endif !Only if N or ion chemistry requested if(chemthermod.ge.2) then nxnew = nxinput + dnx * alfa_laststep if(nxnew.lt.0)nxnew=1.e-30 noxnew = noxinput + dnox * alfa_laststep if(noxnew.lt.0)noxnew=1.e-30 n2xnew = n2xinput + dn2x * alfa_laststep if(n2xnew.lt.0)n2xnew=1.e-30 n2dxnew = n2dxinput + dn2dx * alfa_laststep if(n2dxnew.lt.0)n2dxnew=1.e-30 no2xnew = no2xinput + dno2x * alfa_laststep if(no2xnew.lt.0)no2xnew=1.e-30 endif !Only if ion chemistry requested if(chemthermod.ge.3) then co2plusxnew = co2plusxinput+dco2plusx*alfa_laststep if(co2plusxnew.lt.0)co2plusxnew=1.e-30 o2plusxnew = o2plusxinput+do2plusx*alfa_laststep if(o2plusxnew.lt.0)o2plusxnew=1.e-30 oplusxnew = oplusxinput+doplusx*alfa_laststep if(oplusxnew.lt.0)oplusxnew=1.e-30 coplusxnew = coplusxinput+dcoplusx*alfa_laststep if(coplusxnew.lt.0)coplusxnew=1.e-30 nplusxnew = nplusxinput +dnplusx*alfa_laststep if(nplusxnew.lt.0)nplusxnew=1.e-30 n2plusxnew = n2plusxinput+dn2plusx*alfa_laststep if(n2plusxnew.lt.0)n2plusxnew=1.e-30 noplusxnew = noplusxinput+dnoplusx*alfa_laststep if(noplusxnew.lt.0)noplusxnew=1.e-30 hplusxnew = hplusxinput+dhplusx*alfa_laststep if(hplusxnew.lt.0)hplusxnew=1.e-30 cplusxnew = cplusxinput+dcplusx*alfa_laststep if(cplusxnew.lt.0)cplusxnew=1.e-30 hco2plusxnew = hco2plusxinput+dhco2plusx*alfa_laststep if(hco2plusxnew.lt.0)hco2plusxnew=1.e-30 electxnew = electxinput+delectx*alfa_laststep if(electxnew.lt.0)electxnew=1.e-30 endif !Of chemthermod.ge.3 endif !Of paso.eq.numpasos end do !New concentrations to be returned rm(i,i_co2) = real(co2xnew) rm(i,i_o2) = real(o2xnew) rm(i,i_o) = real(o3pxnew) rm(i,i_co) = real(coxnew) rm(i,i_h) = real(hxnew) rm(i,i_oh) = real(ohxnew) rm(i,i_ho2) = real(ho2xnew) rm(i,i_h2) = real(h2xnew) rm(i,i_h2o) = real(h2oxnew) rm(i,i_h2o2) = real(h2o2xnew) rm(i,i_o1d) = real(o1dxnew) !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) $ rm(i,i_o3) = real(o3xnew) !Only if N or ion chemistry requested if(chemthermod.ge.2) then rm(i,i_n) = real(nxnew) rm(i,i_n2) = real(n2xnew) rm(i,i_no) = real(noxnew) rm(i,i_n2d) = real(n2dxnew) rm(i,i_no2) = real(no2xnew) endif !Only if ion chemistry requested if(chemthermod.eq.3) then rm(i,i_co2plus) = real(co2plusxnew) rm(i,i_oplus) = real(oplusxnew) rm(i,i_o2plus) = real(o2plusxnew) rm(i,i_coplus) = real(coplusxnew) rm(i,i_cplus) = real(cplusxnew) rm(i,i_nplus) = real(nplusxnew) rm(i,i_n2plus) = real(n2plusxnew) rm(i,i_noplus) = real(noplusxnew) rm(i,i_hplus) = real(hplusxnew) rm(i,i_hco2plus)= real(hco2plusxnew) rm(i,i_elec) = real(electxnew) endif end do cccccc End altitude loop return end c********************************************************************** c********************************************************************** subroutine implicito ( ig,c_output, text, & c_input, Prod, Loss, tstep ) c Given the productions and losses, calculates new concentrations using c an implicit integration scheme. Checks if there are negative values and c avoids underflows. c jul 2008 MA Version en subrutina c********************************************************************** implicit none c arguments c integer ig real*8 c_output ! O. real*8 c_input ! I. real*8 tstep ! I. real*8 Prod ! I. real*8 Loss ! I. character*4 text ! I. ccccccccccccccc CODE STARTS c_output = (c_input + Prod * tstep) / (1.d0 + Loss * tstep) ! Stop is negative prods, losses, concentrations or times ! if ( c_output.lt.0.d0 ) then write(*,*) text//' < 0 !!!' write (*,*) ' Terms of the implicit equation: ' write (*,*) ' c_input =', c_input write (*,*) ' Prod = ', Prod write (*,*) ' Loss = ', Loss write (*,*) ' tstep = ', tstep write (*,*) ' c_output =', c_output write (*,*) ' ig = ', ig stop ' Stop at IMPLICIT , PHCHEM ' endif ! Avoid underflow ! if ( c_output.lt.1.d-30) c_output=1.d-30 return c END end c*********************************************************************** function ionsec_nplus (zenit, alt) c Calcula la eficiencia de produccion de N+ por electrones secundarios c siguiendo Nicholson et al. 2009 c FGG sep 2010 first version c*********************************************************************** implicit none ! Arguments real*8 ionsec_nplus real zenit real alt ! Local variables real*8 a0,a1,a2,a3,a4,a5,a6,a7,a8,a9,a10,a11,a12,a13,a14 real*8 b0,b1,b2,b3,b4 real*8 altaux real*8 zenit_rad !!!!!!! Program starts zenit_rad=dble(zenit*3.141592/180.) if(zenit.le.90.) then altaux=dble(alt)+ $ 15.*cos(zenit_rad)-40.*sqrt(cos(zenit_rad))+25. else altaux=dble(alt) endif if(altaux.gt.108.4) then a0 = 1.139925703d3 a1 = -4.742398258d1 a2 = 8.404232989d-1 a3 = -8.108229906d-3 a4 = 4.420892285d-5 a5 = -1.154901432d-7 a6 = -3.514073816d-11 a7 = 8.790819159d-13 a8 = -1.320788149d-16 a9 = -8.202233732d-18 a10 = -1.256480521d-22 a11 = 1.329336168e-22 a12 = -4.403185142d-25 a13 = 6.098474897d-28 a14 = -3.256951018d-31 ionsec_nplus = a0 + a1*altaux + a2*altaux**2 + a3*altaux**3 + $ a4*altaux**4 + a5*altaux**5 + a6*altaux**6 + a7*altaux**7 $ + a8*altaux**8 + a9*altaux**9 + a10*altaux**10 + $ a11*altaux**11 + a12*altaux**12 + a13*altaux**13 + $ a14*altaux**14 ionsec_nplus = 10**(ionsec_nplus-2.) elseif(altaux.gt.80..and.altaux.le.108.4) then ! else b0 = 6.346190854d4 b1 = -2.623253212d3 b2 = 4.050319629d1 b3 = -2.767987276d-1 b4 = 7.064439029d-4 ionsec_nplus = b0 + b1*altaux + b2*altaux**2 + b3*altaux**3 + $ b4*altaux**4 ! ionsec_nplus = ionsec_nplus * 100. else ionsec_nplus=0.d0 endif if(ionsec_nplus.gt.100.d0.or.ionsec_nplus.lt.0.d0) ! if(ionsec_nplus.lt.0.d0) $ ionsec_nplus=0.d0 !Ionizacion secundaria a 0 ! ionsec_nplus=0.d0 return c END end c*********************************************************************** function ionsec_n2plus (zenit, alt) c Calcula la eficiencia de produccion de N+ por electrones secundarios c siguiendo Nicholson et al. 2009 c FGG sep 2010 first version c*********************************************************************** implicit none ! Arguments real*8 ionsec_n2plus real zenit real alt ! Local variables real*8 a0,a1,a2,a3,a4,a5,a6,a7,a8,a9 real*8 b0,b1,b2,b3,b4,b5 real*8 altaux real*8 zenit_rad !!!!!!! Program starts zenit_rad=dble(zenit*3.141592/180.) if(zenit.le.90.) then altaux=dble(alt)+ $ 15.*cos(zenit_rad)-40.*sqrt(cos(zenit_rad))+25. else altaux=dble(alt) endif if(altaux.gt.108.4) then a0 = 9.843804026d2 a1 = -3.978696855d1 a2 = 7.028448262d-1 a3 = -7.11195117d-3 a4 = 4.545683986d-5 a5 = -1.905046447d-7 a6 = 5.240068127d-10 a7 = -9.130399894d-13 a8 = 9.151792207d-16 a9 = -4.023230948d-19 ionsec_n2plus = a0 + a1*altaux + a2*altaux**2 + a3*altaux**3 + $ a4*altaux**4 + a5*altaux**5 + a6*altaux**6 + $ a7*altaux**7 + a8*altaux**8 + a9*altaux**9 ionsec_n2plus = 10**(ionsec_n2plus-2.) elseif(altaux.gt.80..and.altaux.le.108.4) then ! else b0 = 5.146111566d4 b1 = -1.771736158d3 b2 = 1.811156914d1 b3 = 3.583722498d-3 b4 = -9.891151731d-4 b5 = 3.994474097d-6 ionsec_n2plus = b0 + b1*altaux + b2*altaux**2 + b3*altaux**3 + $ b4*altaux**4 + b5*altaux**5 ! ionsec_n2plus = ionsec_n2plus * 100. else ionsec_n2plus = 0.d0 endif if(ionsec_n2plus.gt.100.d0.or.ionsec_n2plus.lt.0.d0) ! if(ionsec_n2plus.lt.0.d0) $ ionsec_n2plus=0.d0 !Ionizacion secundaria a 0 ! ionsec_n2plus=0.d0 return c END end c*********************************************************************** function ionsec_oplus (zenit, alt) c Calcula la eficiencia de produccion de N+ por electrones secundarios c siguiendo Nicholson et al. 2009 c FGG sep 2010 first version c*********************************************************************** implicit none ! Arguments real*8 ionsec_oplus real zenit real alt ! Local variables real*8 a0,a1,a2,a3,a4,a5,a6,a7,a8,a9,a10,a11,a12 real*8 b0,b1,b2,b3,b4,b5,b6 real*8 altaux real*8 zenit_rad !!!!!!! Program starts zenit_rad=dble(zenit*3.141592/180.) if(zenit.le.90.) then altaux=dble(alt)+ $ 15.*cos(zenit_rad)-40.*sqrt(cos(zenit_rad))+25. else altaux=dble(alt) endif if(altaux.gt.112.9) then a0 = 6.453740731d2 a1 = -2.547798991d1 a2 = 4.384613636d-1 a3 = -4.288387072d-3 a4 = 2.596437447d-5 a5 = -9.750300694d-8 a6 = 1.986722344d-10 a7 = -2.293667699d-14 a8 = -1.080547019d-15 a9 = 3.171787989d-18 a10 = -4.566493384d-21 a11 = 3.472393897d-24 a12 = -1.115699979d-27 ionsec_oplus = a0 + a1*altaux + a2*altaux**2 + a3*altaux**3 + $ a4*altaux**4 + a5*altaux**5 + a6*altaux**6 + a7*altaux**7 $ + a8*altaux**8 + a9*altaux**9 + a10*altaux**10 + $ a11*altaux**11 +a12*altaux**12 ionsec_oplus = 10**(ionsec_oplus-2.) elseif(altaux.gt.80..and.altaux.le.112.9) then ! else b0 = -5.934881676d5 b1 = 3.546095705d4 b2 = -8.806801303d2 b3 = 1.163735173d1 b4 = -8.62992438d-2 b5 = 3.40547333d-4 b6 = -5.587037506d-7 ionsec_oplus = b0 + b1*altaux + b2*altaux**2 + b3*altaux**3 + $ b4*altaux**4 + b5*altaux**5 + b6*altaux**6 ! ionsec_oplus = ionsec_oplus * 100. else ionsec_oplus=0.d0 endif if(ionsec_oplus.gt.100.d0.or.ionsec_oplus.lt.0.d0) ! if(ionsec_oplus.lt.0.d0) $ ionsec_oplus=0.d0 !Ionizacion secundaria a 0 ! ionsec_oplus=0.d0 return c END end c*********************************************************************** function ionsec_coplus (zenit, alt) c Calcula la eficiencia de produccion de N+ por electrones secundarios c siguiendo Nicholson et al. 2009 c FGG sep 2010 first version c*********************************************************************** implicit none ! Arguments real*8 ionsec_coplus real zenit real alt ! Local variables real*8 a0,a1,a2,a3,a4,a5,a6,a7,a8,a9 real*8 b0,b1,b2,b3,b4,b5,b6,b7,b8,b9,b10,b11,b12 real*8 altaux real*8 zenit_rad !!!!!!! Program starts zenit_rad=dble(zenit*3.141592/180.) if(zenit.le.90.) then altaux=dble(alt)+ $ 15.*cos(zenit_rad)-40.*sqrt(cos(zenit_rad))+25. else altaux=dble(alt) endif if(altaux.gt.110.6) then a0 = 7.33258229d2 a1 = -2.919984139d1 a2 = 5.079651482d-1 a3 = -5.057170037d-3 a4 = 3.178156709d-5 a5 = -1.309076957d-7 a6 = 3.53858799d-10 a7 = -6.060315762d-13 a8 = 5.973573923d-16 a9 = -2.584454326d-19 ionsec_coplus = a0 + a1*altaux + a2*altaux**2 + a3*altaux**3 + $ a4*altaux**4 + a5*altaux**5 + a6*altaux**6 + a7*altaux**7 $ + a8*altaux**8 + a9*altaux**9 ionsec_coplus = 10**(ionsec_coplus-2.) elseif(altaux.gt.80..and.altaux.le.110.6) then ! else b0 = -1.165107657d6 b1 = 4.315606169d4 b2 = -3.480483017d2 b3 = -3.831253024d0 b4 = 4.33316742d-2 b5 = 2.43075291d-4 b6 = -7.835732322d-8 b7 = -3.80859833d-8 b8 = -1.947628467d-10 b9 = 3.440753726d-12 b10 = 2.336227916d-14 b11 = -3.575877198d-16 b12 = 1.030801684d-18 ionsec_coplus = b0 + b1*altaux + b2*altaux**2 + b3*altaux**3 + $ b4*altaux**4 + b5*altaux**5 + b6*altaux**6 + $ b7*altaux**7 + b8*altaux**8 + b9*altaux**9 + $ b10*altaux**10 + b11*altaux**11 + b12*altaux**12 ! ionsec_coplus = ionsec_coplus * 100. else ionsec_coplus=0.d0 endif if(ionsec_coplus.gt.100..or.ionsec_coplus.lt.0.d0) ! if(ionsec_coplus.lt.0.d0) $ ionsec_coplus=0.d0 !Ionizacion secundaria a 0 ! ionsec_coplus=0.d0 return c END end c*********************************************************************** function ionsec_co2plus (zenit, alt) c Calcula la eficiencia de produccion de N+ por electrones secundarios c siguiendo Nicholson et al. 2009 c FGG sep 2010 first version c*********************************************************************** implicit none ! Arguments real*8 ionsec_co2plus real zenit real alt ! Local variables real*8 a0,a1,a2,a3,a4,a5,a6,a7,a8,a9 real*8 b0,b1,b2,b3,b4,b5,b6,b7,b8,b9,b10 real*8 altaux real*8 zenit_rad !!!!!!!Program starts zenit_rad=dble(zenit*3.141592/180.) if(zenit.le.90.) then altaux=dble(alt)+ $ 15.*cos(zenit_rad)-40.*sqrt(cos(zenit_rad))+25. else altaux=dble(alt) endif if(altaux.gt.112.9) then a0 = 8.64096192d2 a1 = -3.471713960d1 a2 = 6.072614479d-1 a3 = -6.050002721d-3 a4 = 3.779639483d-5 a5 = -1.533626303d-7 a6 = 4.032987841d-10 a7 = -6.602964344d-13 a8 = 6.067681784d-16 a9 = -2.356829271d-19 ionsec_co2plus = a0 + a1*altaux + a2*altaux**2 + a3*altaux**3 + $ a4*altaux**4 + a5*altaux**5 + a6*altaux**6 + $ a7*altaux**7 + a8*altaux**8 + a9*altaux**9 ionsec_co2plus = 10**(ionsec_co2plus-2.) elseif(altaux.ge.80..and.altaux.le.112.9) then ! else b0 = 1.159404818d6 b1 = -5.617523193d4 b2 = 8.535640078d2 b3 = -5.956128524d-1 b4 = -8.532255532d-2 b5 = 1.217829692d-4 b6 = 9.641535217d-6 b7 = -4.502450788d-8 b8 = -4.9684920146d-10 b9 = 4.830572346d-12 b10 = -1.168635127d-14 ionsec_co2plus = b0 + b1*altaux + b2*altaux**2 + b3*altaux**3 + $ b4*altaux**4 + b5*altaux**5 + b6*altaux**6 + $ b7*altaux**7 + b8*altaux**8 + b9*altaux**9 + $ b10*altaux**10 ! ionsec_co2plus = ionsec_co2plus * 100. else ionsec_co2plus = 0.d0 endif if(ionsec_co2plus.gt.100.d0.or.ionsec_co2plus.lt.0.d0) ! if(ionsec_co2plus.lt.0.d0) $ ionsec_co2plus=0.d0 !Ionizacion secundaria a 0 ! ionsec_co2plus=0.d0 return c END end c*********************************************************************** function ionsec_o2plus (zenit, alt) c Calcula la eficiencia de produccion de N+ por electrones secundarios c siguiendo Nicholson et al. 2009 c FGG sep 2010 first version c*********************************************************************** implicit none ! Arguments real*8 ionsec_o2plus real zenit real alt ! Local variables real*8 a0,a1,a2,a3,a4,a5,a6,a7 real*8 b0,b1,b2,b3,b4,b5,b6,b7,b8 real*8 altaux real*8 zenit_rad !!!!!!! Program starts zenit_rad=dble(zenit*3.141592/180.) if(zenit.le.90.) then altaux=dble(alt)+ $ 15.*cos(zenit_rad)-40.*sqrt(cos(zenit_rad))+25. else altaux=dble(alt) endif if(altaux.gt.112.9) then a0 = 7.265142765d2 a1 = -2.714716832d1 a2 = 4.315022800d-1 a3 = -3.774025573d-3 a4 = 1.962771814d-5 a5 = -6.076128732d-8 a6 = 1.037835637d-10 a7 = -7.552930040d-14 ionsec_o2plus = a0 + a1*altaux + a2*altaux**2 + a3*altaux**3 + $ a4*altaux**4 + a5*altaux**5 + a6*altaux**6 + a7*altaux**7 ionsec_o2plus = 10**(ionsec_o2plus-2.) elseif(altaux.gt.80..and.altaux.le.112.9) then ! else b0 = 3.622091694d6 b1 = -1.45914419d5 b2 = 1.764604914d3 b3 = 1.186141031d0 b4 = -1.331821089d-1 b5 = -3.661686584d-4 b6 = 1.934372959d-5 b7 = -1.307294421d-7 b8 = 2.846288872d-10 ionsec_o2plus = b0 + b1*altaux + b2*altaux**2 + b3*altaux**3 + $ b4*altaux**4 + b5*altaux**5 + b6*altaux**6 + b7*altaux**7 $ + b8*altaux**8 ! ionsec_o2plus = ionsec_o2plus * 100. else ionsec_o2plus = 0.d0 endif if(ionsec_o2plus.gt.100.d0.or.ionsec_o2plus.lt.0.d0) ! if(ionsec_o2plus.lt.0.d0) $ ionsec_o2plus=0.d0 !Ionizacion secundaria a 0 ! ionsec_o2plus=0.d0 return c END end c********************************************************************** c********************************************************************** subroutine phdisrate(ig,nlayer,chemthermod,zenit,i) c apr 2002 fgg first version c********************************************************************** use param_v4_h, only: ninter,nabs, . jfotsout,fluxtop, . jion,jdistot,jdistot_b, . efdisco2,efdiso2,efdish2o, . efdish2o2,efdish2,efdiso3, . efdiso,efdisn,efdish, . efdisno,efdisn2,efdisno2, . efdisco,efionco2,efionn2, . efionco,efiono3p,efionn, . efionno,efionh implicit none c arguments integer i !altitude integer ig,chemthermod,nlayer real zenit c local variables integer inter,iz,j real lambda real jdis(nabs,ninter,nlayer) character*1 dn c********************************************************************** c photodissociation and photoionization rates initialization jion(:,i,:) = 0.d0 jdistot(:,i) = 0.d0 jdistot_b(:,i) = 0.d0 ! jion(1,i,1) = 0.d0 ! CO2 channel 1 ( --> CO2+ + e- ) ! jion(1,i,2) = 0.d0 ! CO2 channel 2 ( --> O+ + CO + e- ) ! jion(1,i,3) = 0.d0 ! CO2 channel 3 ( --> CO+ + O + e- ) ! jion(1,i,4) = 0.d0 ! CO2 channel 4 ( --> C+ + O2 + e- ) ! jion(2,i,1) = 0.d0 ! O2 (only one ionization channel) ! jion(3,i,1) = 0.d0 ! O3P (only one ionization channel) ! jion(4,i,1) = 0.d0 ! H2O (no ionization) ! jion(5,i,1) = 0.d0 ! H2 (no ionization) ! jion(6,i,1) = 0.d0 ! H2O2 (no ionization) ! jion(7,i,1) = 0.d0 ! O3 (no ionization) ! jion(8,i,1) = 0.d0 ! N2 channel 1 ( --> n2+ + e- ) ! jion(8,i,2) = 0.d0 ! N2 channel 2 ( --> n+ + n + e- ) ! jion(9,i,1) = 0.d0 ! N ( --> N+ + e- ) ! jion(10,i,1)= 0.d0 ! We do not mind its ionization ! jion(11,i,1) = 0.d0 ! CO channel 1 ( --> co+ + e- ) ! jion(11,i,2) = 0.d0 ! CO channel 2 ( --> c+ + o + e- ) ! jion(11,i,3) = 0.d0 ! CO channel 3 ( --> o+ + c + e- ) ! jion(12,i,1) = 0.d0 ! H ( --> H+ + e- ) ! jion(13,i,1) = 0.d0 ! do j=1,nabs ! jdistot(j,i) = 0. ! jdistot_b(j,i) = 0. ! end do if(zenit.gt.140.) then dn='n' else dn='d' end if if(dn.eq.'n') return c photodissociation and photoionization rates for each species do inter=1,ninter c CO2 jdis(1,inter,i) = jfotsout(inter,1,i) * fluxtop(inter) $ * efdisco2(inter) if(inter.gt.29.and.inter.le.32) then jdistot(1,i) = jdistot(1,i) + jdis(1,inter,i) else if(inter.le.29) then jdistot_b(1,i) = jdistot_b(1,i) + jdis(1,inter,i) end if jion(1,i,1)=jion(1,i,1) + $ jfotsout(inter,1,i)*fluxtop(inter)*efionco2(inter,1) jion(1,i,2)=jion(1,i,2) + $ jfotsout(inter,1,i)*fluxtop(inter)*efionco2(inter,2) jion(1,i,3)=jion(1,i,3) + $ jfotsout(inter,1,i)*fluxtop(inter)*efionco2(inter,3) jion(1,i,4)=jion(1,i,4) + $ jfotsout(inter,1,i)*fluxtop(inter)*efionco2(inter,4) c O2 jdis(2,inter,i) = jfotsout(inter,2,i) * fluxtop(inter) $ * efdiso2(inter) if(inter.ge.31) then jdistot(2,i) = jdistot(2,i) + jdis(2,inter,i) else if(inter.eq.30) then jdistot(2,i)=jdistot(2,i)+0.02*jdis(2,inter,i) jdistot_b(2,i)=jdistot_b(2,i)+0.98*jdis(2,inter,i) else if(inter.lt.31) then jdistot_b(2,i) = jdistot_b(2,i) + jdis(2,inter,i) end if jion(2,i,1)=jion(2,i,1) + $ jfotsout(inter,2,i) * fluxtop(inter) * (1.-efdiso2(inter)) c O3P jion(3,i,1)=jion(3,i,1) + $ jfotsout(inter,3,i) * fluxtop(inter) * efiono3p(inter) c H2O jdis(4,inter,i) = jfotsout(inter,4,i) * fluxtop(inter) $ * efdish2o(inter) jdistot(4,i) = jdistot(4,i) + jdis(4,inter,i) c H2 jdis(5,inter,i) = jfotsout(inter,5,i) * fluxtop(inter) $ * efdish2(inter) jdistot(5,i) = jdistot(5,i) + jdis(5,inter,i) c H2O2 jdis(6,inter,i) = jfotsout(inter,6,i) * fluxtop(inter) $ * efdish2o2(inter) jdistot(6,i) = jdistot(6,i) + jdis(6,inter,i) !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) then c O3 jdis(7,inter,i) = jfotsout(inter,7,i) * fluxtop(inter) $ * efdiso3(inter) if(inter.eq.34) then jdistot(7,i) = jdistot(7,i) + jdis(7,inter,i) else if (inter.eq.35) then jdistot(7,i) = jdistot(7,i) + 0.997 * jdis(7,inter,i) jdistot_b(7,i) = jdistot_b(7,i) + 0.003 * jdis(7,inter,i) else if (inter.eq.36) then jdistot_b(7,i) = jdistot_b(7,i) + jdis(7,inter,i) endif endif !Of chemthermod.ge.1 !Only if N or ion chemistry requested if(chemthermod.ge.2) then c N2 jdis(8,inter,i) = jfotsout(inter,8,i) * fluxtop(inter) $ * efdisn2(inter) jdistot(8,i) = jdistot(8,i) + jdis(8,inter,i) jion(8,i,1) = jion(8,i,1) + jfotsout(inter,8,i) * $ fluxtop(inter) * efionn2(inter,1) jion(8,i,2) = jion(8,i,2) + jfotsout(inter,8,i) * $ fluxtop(inter) * efionn2(inter,2) c N jion(9,i,1) = jion(9,i,1) + jfotsout(inter,9,i) * $ fluxtop(inter) * efionn(inter) c NO jdis(10,inter,i) = jfotsout(inter,10,i) * fluxtop(inter) $ * efdisno(inter) jdistot(10,i) = jdistot(10,i) + jdis(10,inter,i) jion(10,i,1) = jion(10,i,1) + jfotsout(inter,10,i) * $ fluxtop(inter) * efionno(inter) c NO2 jdis(13,inter,i) = jfotsout(inter,13,i) * fluxtop(inter) $ * efdisno2(inter) jdistot(13,i) = jdistot(13,i) + jdis(13,inter,i) endif !Of chemthermod.ge.2 !Only if ion chemistry requested if(chemthermod.eq.3) then c CO jdis(11,inter,i) = jfotsout(inter,11,i) * fluxtop(inter) $ * efdisco(inter) jdistot(11,i) = jdistot(11,i) + jdis(11,inter,i) jion(11,i,1) = jion(11,i,1) + jfotsout(inter,11,i) * $ fluxtop(inter) * efionco(inter,1) jion(11,i,2) = jion(11,i,2) + jfotsout(inter,11,i) * $ fluxtop(inter) * efionco(inter,2) jion(11,i,3) = jion(11,i,3) + jfotsout(inter,11,i) * $ fluxtop(inter) * efionco(inter,3) c H jion(12,i,1) = jion(12,i,1) + jfotsout(inter,12,i) * $ fluxtop(inter) * efionh(inter) endif !Of chemthermod.eq.3 end do return end c********************************************************************** c*************************************************************************** subroutine getch (ig,chemthermod,tt,zkm) c NOV 98 MALV First Version. From the work: c Rodrigo et al, Atmosfera, 3, pp.31-43, 1990 c apr 02 FGG New reactions c Sep 07 fgg c*************************************************************************** use param_v4_h, only: rcoef, . ch2, ch3, ch4, ch5, ch7,ch9,ch10,ch11,ch13,ch14,ch15,ch18, . ch19,ch20,ch21,ch22,ch23,ch24,ch30,ch31,ch32,ch33,ch34, . ch35,ch36,ch37,ch38,ch39,ch40,ch41,ch42,ch43,ch45, . ch46,ch47,ch48,ch49,ch50,ch55,ch56,ch57,ch58,ch59,ch62, . ch63,ch64,ch65,ch66,ch67,ch68,ch69,ch70,ch71, . ch72,ch73,ch74,ch75,ch76,ch85,ch86,ch87 implicit none c Arguments integer ig,chemthermod real*8 tt ! Temperature real zkm ! Altitude in km c local variables: real*8 tcte real*8 t_elect ! electronic temperatures real*8 val ! valores de alturas corresp a t_elect real*8 zhanson(9),tehanson(9) real*8 incremento integer ii, i1, i2 c************************************************************************** tcte = tt !Electronic temperatures ! (Hanson et al. 1977) approx. from Mars p. 107 zhanson(1) = 120. zhanson(2) = 130. zhanson(3) = 150. zhanson(4) = 175. zhanson(5) = 200. zhanson(6) = 225. zhanson(7) = 250. zhanson(8) = 275. zhanson(9) = 300. tehanson(1) = tt tehanson(2) = 200. tehanson(3) = 300. tehanson(4) = 500. tehanson(5) = 1250. tehanson(6) = 2000. tehanson(7) = 2200. tehanson(8) = 2400. tehanson(9) = 2500. if ( zkm .le. 120. ) then t_elect = tt else if(zkm .ge.300.) then t_elect=tehanson(9) else do ii=9,2,-1 if ( zkm .lt. zhanson(ii) ) then i1 = ii - 1 i2 = ii endif enddo incremento = ( tehanson(i2)-tehanson(i1) ) / $ ( zhanson(i2)-zhanson(i1) ) t_elect = tehanson(i1) + (zkm-zhanson(i1)) * incremento endif !Initializations ch2 = 0.d0 ch3 = 0.0 ch4 = 0.d0 ch5 = 0.d0 ch7 = 0.d0 ch9 = 0.d0 ch10 = 0.d0 ch11 = 0.d0 ch13 = 0.d0 ch14 = 0.d0 ch15 = 0.d0 ch18 = 0.d0 ch19 = 0.d0 ch20 = 0.d0 ch21 = 0.d0 ch22 = 0.d0 ch23 = 0.d0 ch24 = 0.d0 ch30 = 0.d0 ch31 = 0.d0 ch32 = 0.d0 ch33 = 0.d0 ch34 = 0.d0 ch35 = 0.d0 ch36 = 0.d0 ch37 = 0.d0 ch38 = 0.d0 ch39 = 0.d0 ch40 = 0.d0 ch41 = 0.d0 ch42 = 0.d0 ch43 = 0.d0 ch45 = 0.d0 ch46 = 0.d0 ch47 = 0.d0 ch48 = 0.d0 ch49 = 0.d0 ch50 = 0.d0 ch55 = 0.d0 ch56 = 0.d0 ch57 = 0.d0 ch58 = 0.d0 ch59 = 0.d0 ch62 = 0.d0 ch63 = 0.d0 ch64 = 0.d0 ch65 = 0.d0 ch66 = 0.d0 ch67 = 0.d0 ch68 = 0.d0 ch69 = 0.d0 ch70 = 0.d0 ch71 = 0.d0 ch72 = 0.d0 ch73 = 0.d0 ch74 = 0.d0 ch75 = 0.d0 ch76 = 0.d0 ch85 = 0.d0 ch86 = 0.d0 !Reaction rates !ch2: h + o2 + co2 --> ho2 + co2 ! JPL 2003 (low pressure limit)*2.5 ! ch2 = 1.425d-31 * (tcte / 300.)**(-1.6d0) ! JPL 2011 (low pressure limit)*2.5 ! ch2 = 1.1e-31 * (tcte / 300.)**(-1.3) ch2=rcoef(1,1)*((tcte/300.)**rcoef(1,2))*exp(rcoef(1,3)/tcte) !ch3: o + ho2 --> oh + o2 ! JPL 2011: ! ch3 = 3.0d-11 * exp(200.d0 / tcte) ch3=rcoef(2,1)*((tcte/300.)**rcoef(2,2))*exp(rcoef(2,3)/tcte) ch4: co + oh --> co2 + h !Nair et al, 1994: !ch4 = 3.2d-13 * exp(-300.d0 / tcte) !mccabe et al., grl, 28, 3135, 2001 !ch4 = 1.57d-13 + 3.54d-33*concco2 !JPL 2011 (low pressure limit): ! ch4 = 1.5d-13 * (tcte/300.)**0.6 ch4=rcoef(3,1)*((tcte/300.)**rcoef(3,2))*exp(rcoef(3,3)/tcte) ch5: ho2 + ho2 --> h2o2 + o2 !JPL 2003: !ch5 = 2.3d-13 * exp(600.d0 / tcte) !JPL 2011: ! ch5 = 3.0d-13 * exp(460.d0 / tcte) ch5=rcoef(4,1)*((tcte/300.)**rcoef(4,2))*exp(rcoef(4,3)/tcte) ch7: oh + ho2 --> h2o + o2 !JPL 2011: ! ch7 = 4.8d-11 * exp(250.d0 / tcte) ch7=rcoef(5,1)*((tcte/300.)**rcoef(5,2))*exp(rcoef(5,3)/tcte) ch9: o(1d) + h2o --> 2oh !JPL 2003: !ch9 = 2.2d-10 !JPL 2011: ! ch9 = 1.63d-10 * exp(60.d0 / tcte) ch9=rcoef(6,1)*((tcte/300.)**rcoef(6,2))*exp(rcoef(6,3)/tcte) ch10: o + o + co2 --> o2 + co2 !JPL 1990: ! ch10 = 1.1d-27 * (tcte **(-2.0d0)) !Estandard en el 1-D !Tsang and Hampson, 1986: ! ch10 = 1.3d-34 * exp(900.d0/tcte) ch10=rcoef(7,1)*((tcte/300.)**rcoef(7,2))*exp(rcoef(7,3)/tcte) ch11: o + oh --> o2 + h !JPL 2003: !ch11 = 2.2d-11 * exp(120.d0 / tcte) !JPL 2011: ! ch11 = 1.8d-11 * exp(180.d0 /tcte) ch11=rcoef(8,1)*((tcte/300.)**rcoef(8,2))*exp(rcoef(8,3)/tcte) ch13: h + ho2 --> h2 + o2 !JPL 2003: !ch13 = 6.5d-12 !JPL 2011: ! ch13 = 6.9d-12 ch13=rcoef(9,1)*((tcte/300.)**rcoef(9,2))*exp(rcoef(9,3)/tcte) ch14: o(1d) + h2 --> h + oh !JPL 2003: !ch14 = 1.1d-10 !JPL 2011: ! ch14 = 1.2d-10 ch14=rcoef(10,1)*((tcte/300.)**rcoef(10,2))* $ exp(rcoef(10,3)/tcte) ch15: oh + h2 --> h + h2o !JPL 2003: !ch15 = 5.5d-12 * exp (-2000.d0 / tcte) !JPL 2011: ! ch15 = 2.8d-12 * exp (-1800.d0 / tcte) ch15=rcoef(11,1)*((tcte/300.)**rcoef(11,2))* $ exp(rcoef(11,3)/tcte) ch18: oh + h2o2 --> h2o + ho2 !JPL 2003: !ch18 = 2.9d-12 * exp (-160.d0 / tcte) !JPL 2011: ! ch18 = 1.8d-12 ch18=rcoef(12,1)*((tcte/300.)**rcoef(12,2))* $ exp(rcoef(12,3)/tcte) ch19: o(1d) + co2 --> o + co2 !JPL 2003: !ch19 = 7.4d-11 * exp(120.d0 / tcte) !JPL 2011: ! ch19 = 7.5d-11 * exp(115.d0 / tcte) ch19=rcoef(13,1)*((tcte/300.)**rcoef(13,2))* $ exp(rcoef(13,3)/tcte) ch20: o(1d) + o2 --> o + o2 !JPL 2003: !ch20 = 3.2d-11 * exp (70.d0 / tcte) !JPL 2011: ! ch20 = 3.3d-11 * exp(55.d0 / tcte) ch20=rcoef(14,1)*((tcte/300.)**rcoef(14,2))* $ exp(rcoef(14,3)/tcte) ch21: o + o2 + co2 --> o3 + co2 !JPL 2011 * 2.5: ! ch21 = 1.5d-33 * ((tcte / 300.d0) ** (-2.4d0)) ch21=rcoef(15,1)*((tcte/300.)**rcoef(15,2))* $ exp(rcoef(15,3)/tcte) !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) then ch22: o3 + h --> o2 + oh !JPL 2011: ! ch22 = 1.4d-10 * exp (-470.d0 / tcte) ch22=rcoef(16,1)*((tcte/300.)**rcoef(16,2))* $ exp(rcoef(16,3)/tcte) ch23: o3 + oh --> ho2 + o2 !JPL 2011: ! ch23 = 1.7d-12 * exp (-940.d0 / tcte) ch23=rcoef(17,1)*((tcte/300.)**rcoef(17,2))* $ exp(rcoef(17,3)/tcte) ch24: o3 + ho2 --> oh + 2o2 !JPL 2011: ! ch24 = 1.0d-14 * exp (-490.d0 / tcte) ch24=rcoef(18,1)*((tcte/300.)**rcoef(18,2))* $ exp(rcoef(18,3)/tcte) endif !Only if N or ion chemistry requested if(chemthermod.ge.2) then c<<<<<<<<<<<<<<<<<<<<<<<<<<<<<< c N chemistry ch30: n + no --> n2 + o !JPL 2011: ! ch30 = 2.1d-11 * exp (100.d0 / tcte) ch30=rcoef(19,1)*((tcte/300.)**rcoef(19,2))* $ exp(rcoef(19,3)/tcte) ch31: n2 + o(1d) --> n2 + o !JPL 2011: ! ch31 = 2.15d-11 * exp (110.d0 / tcte) ch31=rcoef(20,1)*((tcte/300.)**rcoef(20,2))* $ exp(rcoef(20,3)/tcte) ch32: n + o2 --> no + o !JPL 2011: ! ch32 = 1.5d-11 * exp (-3600.d0 / tcte) ch32=rcoef(21,1)*((tcte/300.)**rcoef(21,2))* $ exp(rcoef(21,3)/tcte) ch33: n + oh --> no + h !Atkinson et al., 1989 (usado en Nair et al., 1994) ! ch33 = 3.8d-11 * exp (85.d0 / tcte) ch33=rcoef(22,1)*((tcte/300.)**rcoef(22,2))* $ exp(rcoef(22,3)/tcte) ch34: n + o3 --> no + o2 !JPL 2011 (it is an upper limit): ! ch34 = 1.0d-16 ch34=rcoef(23,1)*((tcte/300.)**rcoef(23,2))* $ exp(rcoef(23,3)/tcte) ch35: n + ho2 --> no + oh !Brune et al., 1983 (from Nair et al., 1994) ! ch35 = 2.2d-11 ch35=rcoef(24,1)*((tcte/300.)**rcoef(24,2))* $ exp(rcoef(24,3)/tcte) ch36: n(2d) + o --> n + o !Fell et al., 1990 (from Nair et al., 1994) !ch36 = 6.9d-13 !Herron, 1999: ! ch36 = 3.3d-12 * exp(-260.d0 / tcte) ch36=rcoef(25,1)*((tcte/300.)**rcoef(25,2))* $ exp(rcoef(25,3)/tcte) ch37: n(2d) + n2 --> n + n2 !Herron, 1999: !Coincides with Nair et al., 1994: ! ch37 = 1.7d-14 ch37=rcoef(26,1)*((tcte/300.)**rcoef(26,2))* $ exp(rcoef(26,3)/tcte) ch38: n(2d) + co2 --> no + co !Pipper et al., 1989 (from Nair et al., 1994): !ch38 = 3.5d-13 !Herron, 1999: ! ch38 = 3.6d-13 ch38=rcoef(27,1)*((tcte/300.)**rcoef(27,2))* $ exp(rcoef(27,3)/tcte) ch39: no + ho2 --> no2+oh !JPL 2006: !ch39 = 3.5d-12 * exp (250.d0 / tcte) !JPL 2011: ! ch39 = 3.3d-12 * exp(270.d0 / tcte) ch39=rcoef(28,1)*((tcte/300.)**rcoef(28,2))* $ exp(rcoef(28,3)/tcte) ch40: o + no + co2 --> no2 + co2 !JPL 2011 * 2.5 (low pressure limit) ! ch40 = 2.5d0 * 9.0d-32 * ((tcte / 300.d0) ** (-1.5d0)) ch40=rcoef(29,1)*((tcte/300.)**rcoef(29,2))* $ exp(rcoef(29,3)/tcte) ch41: o + no2 --> no + o2 !JPL 2011: ! ch41 = 5.1d-12 * exp (210.d0 / tcte) ch41=rcoef(30,1)*((tcte/300.)**rcoef(30,2))* $ exp(rcoef(30,3)/tcte) ch42: no + o3 --> no2 + o2 !JPL 2011: ! ch42 = 3.0d-12 * exp (-1500.d0 / tcte) ch42=rcoef(31,1)*((tcte/300.)**rcoef(31,2))* $ exp(rcoef(31,3)/tcte) ch43: h + no2 --> no + oh !JPL 2011: ! ch43 = 4.0d-10 * exp (-340.d0 / tcte) ch43=rcoef(32,1)*((tcte/300.)**rcoef(32,2))* $ exp(rcoef(32,3)/tcte) ch45: n + o --> no !Du and Dalgarno, 1990 ! ch45 = 2.8d-17 * ((300.d0 / tcte) ** 0.5) ch45=rcoef(33,1)*((tcte/300.)**rcoef(33,2))* $ exp(rcoef(33,3)/tcte) endif !of if(chemthermod.ge.2) !Only if ion chemistry requested if(chemthermod.eq.3) then c c Ionosphere c ch46: co2+ + O2 --> O2+ + CO2 !Moffat et al., 2005 (given by GG): !ch46 = 5.0d-11 !Copp et al., 1982: !ch46 = 5.3d-11 !Aninich 1993 (from Fox and Sung 2001): ! ch46 = 5.5d-11 * (300.d0/t_elect)**0.82 ch46=rcoef(34,1)*((t_elect/300.)**rcoef(34,2))* $ exp(rcoef(34,3)/t_elect) ch47: CO2+ + O --> O+ + CO2 !Original (incorrect) value (corresponds to ch48): !ch47 = 1.64d-10 !Fehsenfeld et al., 1970 (from UMIST, !Fox and Sung 2001, Krasnopolsky 2002): ! ch47 = 9.6d-11 ch47=rcoef(35,1)*((t_elect/300.)**rcoef(35,2))* $ exp(rcoef(35,3)/t_elect) ch48: CO2+ + O --> O2+ + CO !Original (incorrect) value (corresponds to ch47): !ch48 = 9.6d-11 !Fehsenfeld et al., 1970 (from UMIST, !Fox and Sung 2001, Krasnopolsky 2002): ! ch48 = 1.64d-10 ch48=rcoef(36,1)*((t_elect/300.)**rcoef(36,2))* $ exp(rcoef(36,3)/t_elect) ch49: O2+ + elect --> O + O !Alge et al., 1983: !Here we do not divide into reaction producing different !O atomic states. O + O(1d) seems to be the dominant products !(see Fox and Sung 2002). We should consider dividing !into two different reactions ! ch49 = 2.0d-7*(300.d0/t_elect)**(0.7d0) ch49=rcoef(37,1)*((t_elect/300.)**rcoef(37,2))* $ exp(rcoef(37,3)/t_elect) ch50: O+ + CO2 --> O2+ + CO !Adams et al., 1980 (from UMIST): ! ch50 = 9.4d-10 !Anicich 1993 (from Fox and Sung 2001): !ch50 = 1.1d-9 ch50=rcoef(38,1)*((t_elect/300.)**rcoef(38,2))* $ exp(rcoef(38,3)/t_elect) ch55: CO2+ + e ----> CO + O !Mitchell, 1990 (from UMIST): ! ch55 = 3.8d-7*(300.d0/t_elect)**(0.5d0) !Gougousi et al., 1997 (from Fox and Sung 2001): !ch55 = 3.5d-7*(300.d0/t_elect)**0.5d0 ch55=rcoef(39,1)*((t_elect/300.)**rcoef(39,2))* $ exp(rcoef(39,3)/t_elect) ch56: O+ + CO2 ---> O2 + CO+ !Original, Kim et al., 1989: !ch56 = 9.4d-10 !It does not appear in any other paper. Its presence in !Kim et al., 1989 is probably a confusion with ch50. ! ch56 = 0.d0 ch56=rcoef(40,1)*((t_elect/300.)**rcoef(40,2))* $ exp(rcoef(40,3)/t_elect) ch57: CO+ + CO2 ---> CO2+ + CO !Adams et al., 1978 (from UMIST): ! ch57 = 1.0d-9 !Anicich 1993 (from Fox and Sung 2001): !ch57 = 1.1d-9 ch57=rcoef(41,1)*((t_elect/300.)**rcoef(41,2))* $ exp(rcoef(41,3)/t_elect) ch58: CO+ + O ---> O+ + CO !Fenhsenfeld et al. 1970 (from UMIST, F&S2001, K2002): ! ch58 = 1.4d-10 ch58=rcoef(42,1)*((t_elect/300.)**rcoef(42,2))* $ exp(rcoef(42,3)/t_elect) ch59: C+ + CO2 ---> CO+ + CO !!!! NEW !!! !Fahey et al., 1981 (from UMIST, F&S2001, K2002): ! ch59 = 1.1d-9 ch59=rcoef(43,1)*((t_elect/300.)**rcoef(43,2))* $ exp(rcoef(43,3)/t_elect) ch62: CO2+ + NO --> NO+ + CO2 !Copp et al., 1982 (from UMIST): ! ch62 = 1.2d-10 !Anicich 1993 (from Fox and Sung 2001): !ch62 = 1.23d-10 ch62=rcoef(44,1)*((t_elect/300.)**rcoef(44,2))* $ exp(rcoef(44,3)/t_elect) ch63: CO2+ + N --> NO + CO+ !Kim et al., 1989: !ch63 = 1.0d-11 !Scott et al., 1998 (from Fox and Sung 2001): ! ch63 = 3.4d-10 ch63=rcoef(45,1)*((t_elect/300.)**rcoef(45,2))* $ exp(rcoef(45,3)/t_elect) ch64: O2+ + NO --> NO+ + O2 !Middey and Vigiano 1999 (from Fox and Sung 2001): ! ch64 = 4.5d-10 !Aninich 1993 (from UMIST): !ch64 = 4.6d-10 ch64=rcoef(46,1)*((t_elect/300.)**rcoef(46,2))* $ exp(rcoef(46,3)/t_elect) ch65: O2+ + N2 --> NO+ + NO !Original from GG, Moffat 2005: !ch65 = 1.0d-16 !Ferguson 1973 (from Fox and Sung 2001): ! ch65 = 1.0d-15 ch65=rcoef(47,1)*((t_elect/300.)**rcoef(47,2))* $ exp(rcoef(47,3)/t_elect) ch66: O2+ + N --> NO+ + O !Kim et al., 1989: !ch66 = 1.2d-10 !Scott et al., 1998 (from Fox and Sung 2001): ! ch66 = 1.0d-10 !Goldan et al., 1966 (from UMIST): !ch66 = 1.8d-10 ch66=rcoef(48,1)*((t_elect/300.)**rcoef(48,2))* $ exp(rcoef(48,3)/t_elect) ch67: O+ + N2 --> NO+ + N !Moffat 2005: !ch67 = 1.2d-12 * (300.d0/t_elect)**(0.41d0) !Hierl et al. 1997 (from Fox and Sung 2001): ! ch67 = 1.2d-12 * (300.d0/t_elect)**0.45d0 !Adams et al., 1980 (from UMIST): !ch67=2.42d-12 * (300.d0/t_elec)**(-0.21)*exp(44./t_elec) ch67=rcoef(49,1)*((t_elect/300.)**rcoef(49,2))* $ exp(rcoef(49,3)/t_elect) ch68: N2+ + CO2 --> CO2+ + N2 !Adams et al. 1980 (from UMIST): !ch68 = 7.7d-10 !Dotan et al. 2000 (from F&S2001): ! ch68 = 9.0d-10 * (300./t_elect)**0.23 ch68=rcoef(50,1)*((t_elect/300.)**rcoef(50,2))* $ exp(rcoef(50,3)/t_elect) ch69: N2+ + O3p --> NO+ + N !McFarland et al., 1974 (from UMIST): !ch69 = 1.3d-10 !Scott et al. 1999 (from F&S2001): ! ch69 = 1.33d-10 * (300./t_elect)**0.44 ch69=rcoef(51,1)*((t_elect/300.)**rcoef(51,2))* $ exp(rcoef(51,3)/t_elect) ch70: N2+ + CO --> N2 + CO+ !Adams et al., 1980 (from UMIST): ! ch70 = 7.4d-11 !Frost et al., 1998 (from F&S2001): !ch70 = 7.6d-11 ch70=rcoef(52,1)*((t_elect/300.)**rcoef(52,2))* $ exp(rcoef(52,3)/t_elect) ch71: N2+ + e- --> N + N !Moffat 2005 !ch71 = 3.5d-7 * (300.d0/t_elect)**(0.5d0) !Peterson et al. 1998 (from UMIST): ! ch71 = 1.7d-7 * (300.d0/t_elect)**0.3 !Zipf 1980+Kella et al 1996 (from F&S2001): !ch71 = 2.2d-7 * (300.d0/t_elect)**0.39 ch71=rcoef(53,1)*((t_elect/300.)**rcoef(53,2))* $ exp(rcoef(53,3)/t_elect) ch72: N2+ + O3p --> O+ + N2 !Moffat 2005: !ch72 = 4.1d-10 !McFarland et al. 1974 (From UMIST): !ch72 = 1.1d-11 !Scott et al., 1999 (from F&S2001): ! ch72 = 7.0d-12 * (300.d0/t_elect)**0.23 ch72=rcoef(54,1)*((t_elect/300.)**rcoef(54,2))* $ exp(rcoef(54,3)/t_elect) ch73 CO+ + H --> H+ + CO !Scott et al., 1997 (from F&S2001): ! ch73 = 4.0d-10 !Federer et al. 1984 (from UMIST): !ch73 = 7.5d-10 ch73=rcoef(55,1)*((t_elect/300.)**rcoef(55,2))* $ exp(rcoef(55,3)/t_elect) ch74: O+ + H --> H+ + O !Krasnopolsky 2002: !ch74 = 5.7d-10 * (tt/300.d0)**(0.36d0) !Stancil et al. 1999 (from UMIST): ! ch74 = 5.66d-10*(tt/300.)**0.36*exp(8.6/tt) !Aninich 1993 (from F&S2001): !ch74 = 6.4e-10 ch74=rcoef(56,1)*((tcte/300.)**rcoef(56,2))* $ exp(rcoef(56,3)/tcte) ch75: NO+ + e- --> N + O !Mitchel 1990 (from UMIST): ! ch75 = 4.3d-7 * (300.d0/t_elect)**(0.37d0) !Vejby-Christensen et al. 1996 (from F&S2001): !ch75=4.0d-7 * (300.d0/t_elect)**0.5d0 ch75=rcoef(57,1)*((t_elect/300.)**rcoef(57,2))* $ exp(rcoef(57,3)/t_elect) ch76: H+ + O3p --> O+ + H !Krasnopolsky et al. 2002: !ch76 = 7.3d-10 * (tt/300.d0)**(0.23d0) * exp(-226./tt) !Stancil et al. 1999 (from UMIST): ! ch76 = 6.86e-10* (tt/300.)**0.26*exp(-224.3/tt) ch76=rcoef(58,1)*((tcte/300.)**rcoef(58,2))* $ exp(rcoef(58,3)/tcte) ch85: N+ + CO2 --> CO2+ + N !Krasnopolsky 2002: !ch85 = 1.d-9 !Adams et al. 1980 (from UMIST): ! ch85 = 7.5d-10 !Aninich et al. 1993 (from F&S2001): !ch85 = 9.2d-10 ch85=rcoef(59,1)*((t_elect/300.)**rcoef(59,2))* $ exp(rcoef(59,3)/t_elect) ch86: H2 + CO2+ --> H + HCO2+ !Scott et al. 1998 (from F&S2001 and K2002): !ch86 = 8.7d-10 !Copp et al. 1982 (from UMIST): ! ch86 = 9.5d-10 ch86=rcoef(60,1)*((t_elect/300.)**rcoef(60,2))* $ exp(rcoef(60,3)/t_elect) c h87: HCO2+ + e -> CO2 + H !Krasnopolsky 2002: ! ch87 = 3.4d-7 * (300.d0/t_elect)**(0.5d0) !UMIST 2012: the reactions has 3 different sets of products: CO2+H, !CO+O+H (dominante) y CO+OH. Habria que tener esto en cuenta ch87=rcoef(61,1)*((t_elect/300.)**rcoef(61,2))* $ exp(rcoef(61,3)/t_elect) endif !Of if(chemthermod.eq.3) return end c********************************************************************** c********************************************************************** subroutine lifetimes & ( ig,i,nlayer,chemthermod,zenit,zx,jdistot8, jdistot8_b, jion8, $ xtmin, xcompmin, xn_comp_en_EQ, $ co2xini,o2xini,o3pxini,coxini,hxini,ohxini,ho2xini,h2xini, $ h2oxini,h2o2xini,o1dxini,o3xini,n2xini,nxini,noxini,no2xini, $ n2dxini,co2plusxini,oplusxini,o2plusxini,coplusxini, $ cplusxini,nplusxini,noplusxini,n2plusxini,hplusxini, $ hco2plusxini,electxini) c Calculates the lifetime of each species at each time step (itime) c and each altitude (i), and the minimum of them (tmin) c It also computes the number of species in PE c c c jul 2008 MA Version en subrutina c 2009 FGG Adaptation to GCM c********************************************************************** use iono_h use param_v4_h implicit none include 'callkeys.h' c arguments c integer i,ig,nlayer ! I. Layer integer chemthermod real zenit real zx(nlayer) real*8 jdistot8(nabs,nlayer) ! I. real*8 jdistot8_b(nabs,nlayer) ! I. real*8 jion8(nabs,nlayer,4) ! I. real*8 xtmin ! O. integer xcompmin ! O. integer xn_comp_en_EQ ! O. real*8 co2xini,o2xini,o3pxini,coxini real*8 ho2xini,h2xini,hxini,ohxini real*8 h2o2xini,o1dxini,o3xini,h2oxini real*8 nxini,noxini,n2xini,n2dxini,no2xini real*8 co2plusxini,coplusxini,oplusxini,o2plusxini real*8 cplusxini,noplusxini,n2plusxini,hplusxini real*8 electxini,nplusxini,hco2plusxini c local variables c integer j external ionsec_nplus real*8 ionsec_nplus external ionsec_n2plus real*8 ionsec_n2plus external ionsec_oplus real*8 ionsec_oplus external ionsec_coplus real*8 ionsec_coplus external ionsec_co2plus real*8 ionsec_co2plus external ionsec_o2plus real*8 ionsec_o2plus ccccccccccccccc CODE STARTS !Initialization of lifetimes do j = 1, nreact tauco2(j,i) = 1.d30 tauo2(j,i) = 1.d30 tauo3p(j,i) = 1.d30 tauco(j,i) = 1.d30 tauh(j,i) = 1.d30 tauoh(j,i) = 1.d30 tauho2(j,i) = 1.d30 tauh2(j,i) = 1.d30 tauh2o(j,i) = 1.d30 tauo1d(j,i) = 1.d30 tauh2o2(j,i) = 1.d30 tauo3(j,i) = 1.d30 taun2(j,i) = 1.d30 taun(j,i) = 1.d30 tauno(j,i) = 1.d30 taun2d(j,i) = 1.d30 tauno2(j,i) = 1.d30 tauco2plus(j,i) = 1.d30 tauoplus(j,i) = 1.d30 tauo2plus(j,i) = 1.d30 taucoplus(j,i) = 1.d30 taucplus(j,i) = 1.d30 taunplus(j,i) = 1.d30 taun2plus(j,i) = 1.d30 taunoplus(j,i) = 1.d30 tauhplus(j,i) = 1.d30 tauhco2plus(j,i)= 1.d30 end do !Lifetime of each species in each reaction if(jdistot8(1,i).gt.1.d-30) tauco2(1,i) = 1.d0 / jdistot8(1,i) if(ch2*o2xini*co2xini.gt.1.d-30) $ tauh(2,i) = 1.d0 / (ch2 * o2xini * co2xini) if(ch2*hxini*co2xini.gt.1.d-30) $ tauo2(2,i) = 1.d0 / (ch2 * hxini * co2xini) if(ch3*o3pxini.gt.1.d-30) tauho2(3,i) = 1.d0 / $ (ch3 * o3pxini) if(ch3*ho2xini.gt.1.d-30) tauo3p(3,i) = 1.d0 / $ (ch3 * ho2xini) if(ch4*coxini.gt.1.d-30) tauoh(4,i) = 1.d0 / $ (ch4 * coxini) if(ch4*ohxini.gt.1.d-30) tauco(4,i) = 1.d0 / $ (ch4 * ohxini) if(ch5*ho2xini.gt.1.d-30)tauho2(5,i)=1.d0 / $ (2.d0*ch5*ho2xini) if(jdistot8(6,i).gt.1.d-30) tauh2o2(6,i) = 1.d0 / jdistot8(6,i) if(ch7*ohxini.gt.1.d-30) tauho2(7,i) = 1.d0 / $ (ch7 * ohxini) if(ch7*ho2xini.gt.1.d-30) tauoh(7,i) = 1.d0 / $ (ch7 * ho2xini) if(jdistot8(4,i).gt.1.d-30) tauh2o(8,i) = 1.d0 / jdistot8(4,i) if(ch9*o1dxini.gt.1.d-30) tauh2o(9,i) = 1.d0 / $ (ch9 * o1dxini) if(ch9*h2oxini.gt.1.d-30) tauo1d(9,i) = 1.d0 / $ (ch9 * h2oxini) if(ch10*o3pxini*co2xini.gt.1.d-30) $ tauo3p(10,i) = 1.d0 / $ (2.d0 * ch10 * o3pxini * co2xini) if(ch11*o3pxini.gt.1.d-30) tauoh(11,i)=1.d0 / $ (ch11 * o3pxini) if(ch11*ohxini.gt.1.d-30) tauo3p(11,i) = 1.d0 / $ (ch11 * ohxini) if(jdistot8(2,i).gt.1.d-30) tauo2(12,i) = 1.d0 / jdistot8(2,i) if(ch13*hxini.gt.1.d-30) tauho2(13,i) = 1.d0 / $ (ch13 * hxini) if(ch13*ho2xini.gt.1.d-30) tauh(13,i) = 1.d0 / $ (ch13 * ho2xini) if(ch14*o1dxini.gt.1.d-30) tauh2(14,i) = 1.d0 / $ (ch14 * o1dxini) if(ch14*h2xini.gt.1.d-30) tauo1d(14,i) = 1.d0 / $ (ch14 * h2xini) if(ch15*ohxini.gt.1.d-30) tauh2(15,i) = 1.d0 / $ (ch15 * ohxini) if(ch15*h2xini.gt.1.d-30) tauoh(15,i) = 1.d0 / $ (ch15 * h2xini) if(jdistot8_b(1,i).gt.1.d-30) tauco2(16,i)=1.d0/jdistot8_b(1,i) if(jdistot8_b(2,i).gt.1.d-30) tauo2(17,i)=1.d0/jdistot8_b(2,i) if(ch18*ohxini.gt.1.d-30) tauh2o2(18,i)=1.d0 / $ (ch18 * ohxini) if(ch18*h2o2xini.gt.1.d-30) tauoh(18,i)=1.d0 / $ (ch18 * h2o2xini) if(ch19*co2xini.gt.1.d-30)tauo1d(19,i)=1.d0 / $ (ch19 * co2xini) if(ch20*o2xini.gt.1.d-30)tauo1d(20,i)= 1.d0 / $ (ch20 * o2xini) if(ch21*o2xini*co2xini.gt.1.d-30)tauo3p(21,i)= 1.d0 / $ (ch21 * o2xini * co2xini) if(ch21*o3pxini*co2xini.gt.1.d-30) tauo2(21,i) = 1.d0 / $ (ch21 * o3pxini * co2xini) !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) then if(ch22*hxini.gt.1.d-30) tauo3(22,i) = 1.d0 / $ (ch22 * hxini) if(ch22*o3xini.gt.1.d-30) tauh(22,i) = 1.d0 / $ (ch22 * o3xini) if(ch23*ohxini.gt.1.d-30) tauo3(23,i) = 1.d0 / $ (ch23 * ohxini) if(ch23*o3xini.gt.1.d-30) tauoh(23,i) = 1.d0 / $ (ch23 * o3xini) if(ch24 * ho2xini.gt.1.d-30)tauo3(24,i)= 1.d0 / $ (ch24 * ho2xini) if(ch24 * o3xini.gt.1.d-30)tauho2(24,i)= 1.d0 / $ (ch24 * o3xini) if(jdistot8(7,i).gt.1.d-30) tauo3(25,i)=1.d0 / $ jdistot8(7,i) if(jdistot8_b(7,i).gt.1.d-30) tauo3(26,i)= 1.d0 / $ jdistot8_b(7,i) endif !Of chemthermod.ge.1 if(jdistot8(5,i).gt.1.d-30) tauh2(27,i)= 1.d0/jdistot8(5,i) ! if(ch28 * h2oxini.gt.1.d-30) tauo3(i,28) = 1.d0/(ch28*h2oxini) ! if(ch28 * o3xini.gt.1.d-30) tauh2o(i,28) = 1.d0/(ch28*o3xini) !Only if N or ion chemistry requested if(chemthermod.ge.2) then if(jdistot8(8,i).gt.1.d-30) taun2(28,i) = 1.d0 / $ jdistot8(8,i) if(jdistot8(10,i).gt.1.d-30) tauno(29,i) = 1.d0 / $ jdistot8(10,i) if(ch30 * noxini.gt.1.d-30) taun(30,i) = 1.d0 / $ (ch30 * noxini) if(ch30 * nxini.gt.1.d-30) tauno(30,i) = 1.d0 / $ (ch30 * nxini) if(ch31 * o1dxini.gt.1.d-30) taun2(31,i) = 1.d0 / $ (ch31 * o1dxini) if(ch31 * n2xini.gt.1.d-30) tauo1d(31,i) = 1.d0 / $ (ch31 * n2xini) if(ch32 * o2xini.gt.1.d-30) taun(32,i) = 1.d0 / $ (ch32 * o2xini) if(ch32 * nxini.gt.1.d-30) tauo2(32,i) = 1.d0 / $ (ch32 * nxini) if(ch33 * ohxini.gt.1.d-30) taun(33,i) = 1.d0 / $ (ch33 * ohxini) if(ch33 * nxini.gt.1.d-30) tauoh(33,i) = 1.d0 / $ (ch33 * nxini) if(ch34 * o3xini.gt.1.d-30) taun(34,i) = 1.d0 / $ (ch34 * o3xini) if(ch34 * nxini.gt.1.d-30) tauo3(34,i) = 1.d0 / $ (ch34 * nxini) if(ch35 * ho2xini.gt.1.d-30) taun(35,i) = 1.d0 / $ (ch35 * ho2xini) if(ch35 * nxini.gt.1.d-30) tauho2(35,i) = 1.d0 / $ (ch35 * nxini) if(ch36 * o3pxini.gt.1.d-30) taun2d(36,i) = 1.d0 / $ (ch36 * o3pxini) if(ch36 * n2dxini.gt.1.d-30) tauo3p(36,i) = 1.d0 / $ (ch36 * n2dxini) if(ch37 * n2xini.gt.1.d-30) taun2d(37,i) = 1.d0 / $ (ch37 * n2xini) if(ch37 * n2dxini.gt.1.d-30) taun2(37,i) = 1.d0 / $ (ch37 * n2dxini) if(ch38 * co2xini.gt.1.d-30) taun2d(38,i) = 1.d0 / $ (ch38 * co2xini) if(ch38 * n2dxini.gt.1.d-30) tauco2(38,i) = 1.d0 / $ (ch38 * n2dxini) if(ch39 * ho2xini.gt.1.d-30) tauno(39,i) = 1.d0 / $ (ch39 * ho2xini) if(ch39 * noxini.gt.1.d-30) tauho2(39,i) = 1.d0 / $ (ch39 * noxini) if(ch40 * noxini * co2xini.gt.1.d-30) tauo3p(40,i) = 1.d0 / $ (ch40 * noxini * co2xini) if(ch40 * o3pxini * co2xini.gt.1.d-30) tauno(40,i) = 1.d0 / $ (ch40 * o3pxini * co2xini) if(ch41 * no2xini.gt.1.d-30) tauo3p(41,i) = 1.d0 / $ (ch41 * no2xini) if(ch41 * o3pxini.gt.1.d-30) tauno2(41,i) = 1.d0 / $ (ch41 * o3pxini) if(ch42 * noxini.gt.1.d-30) tauo3(42,i) = 1.d0 / $ (ch42 * noxini) if(ch42 * o3xini.gt.1.d-30) tauno(42,i) = 1.d0 / $ (ch42 * o3xini) if(ch43 * no2xini.gt.1.d-30) tauh(43,i) = 1.d0 / $ (ch43 * no2xini) if(ch43 * hxini.gt.1.d-30) tauno2(43,i) = 1.d0 / $ (ch43 * hxini) if(jdistot8(13,i).gt.1.d-30) tauno2(44,i) = 1.d0 / $ jdistot8(13,i) if(ch45 * nxini.gt.1.d-30) tauo3p(45,i) = 1.d0 / $ (ch45 * nxini) if(ch45 * o3pxini.gt.1.d-30) taun(45,i) = 1.d0 / $ (ch45 * o3pxini) endif !Of chemthermod.ge.2 c>>>>>>>>>>>>>>>>>>>>>>>> IONOSPHERE >>>>>>>>>>>>>>>> !Only if ion chemistry requested if(chemthermod.eq.3) then if(ch46 * co2plusxini .gt.1.d-30) tauo2(46,i) = @ 1.d0/(ch46*co2plusxini) if(ch46 * o2xini .gt.1.d-30) tauco2plus(46,i) = @ 1.d0/(ch46*o2xini) if ( ch47*o3pxini .gt. 1.d-30 ) tauco2plus(47,i) = @ 1.d0/( ch47*o3pxini ) if ( ch47*co2plusxini .gt. 1.d-30 ) tauo3p(47,i) = @ 1.d0/( ch47*co2plusxini ) if ( ch48*o3pxini .gt. 1.d-30 ) tauco2plus(48,i) = @ 1.d0/(ch48*o3pxini) if ( ch48*co2plusxini .gt. 1.d-30 ) tauo3p(48,i) = @ 1.d0/(ch48*co2plusxini) if ( ch49*electxini .gt. 1.d-30 ) tauo2plus(49,i) = @ 1.d0/(ch49*electxini) if ( ch50*co2xini .gt. 1.d-30 ) tauoplus(50,i) = @ 1.d0/(ch50*co2xini) if ( ch50*oplusxini .gt. 1.d-30 ) tauco2(50,i) = @ 1.d0/(ch50*oplusxini) if ( jion8(1,i,1).gt.1.d-30 ) tauco2(51,i) = $ 1.d0 / jion8(1,i,1) if ( jion8(1,i,2).gt.1.d-30 ) tauco2(52,i) = $ 1.d0 / jion8(1,i,2) if ( jion8(1,i,3).gt.1.d-30 ) tauco2(53,i) = $ 1.d0 / jion8(1,i,3) if ( jion8(1,i,4).gt.1.d-30 ) tauco2(54,i) = $ 1.d0 / jion8(1,i,4) if ( ch55*electxini .gt. 1.d-30 ) tauco2plus(55,i) = @ 1.d0/(ch55*electxini) if ( ch56*oplusxini .gt. 1.d-30 ) tauco2(56,i) = @ 1.d0/(ch56*oplusxini) if ( ch56*co2xini .gt. 1.d-30 ) tauoplus(56,i) = @ 1.d0/(ch56*co2xini) if ( ch57*coplusxini .gt. 1.d-30 ) tauco2(57,i) = @ 1.d0/(ch57*coplusxini) if ( ch57*co2xini .gt. 1.d-30 ) taucoplus(57,i) = @ 1.d0/(ch57*co2xini) if ( ch58*coplusxini .gt. 1.d-30 ) tauo3p(58,i) = @ 1.d0/(ch58*coplusxini) if ( ch58*o3pxini .gt. 1.d-30 ) taucoplus(58,i) = @ 1.d0/(ch58*o3pxini) if ( ch59*cplusxini .gt. 1.d-30 ) tauco2(59,i) = @ 1.d0/(ch59*cplusxini) if ( ch59*co2xini .gt. 1.d-30 ) taucplus(59,i) = @ 1.d0/(ch59*co2xini) if ( jion8(2,i,1).gt.1.d-30 ) tauo2(60,i) = $ 1.d0 / jion8(2,i,1) if ( jion8(3,i,1).gt.1.d-30 ) tauo3p(61,i) = $ 1.d0 / jion8(3,i,1) if ( ch62*co2plusxini .gt. 1.d-30 ) tauno(62,i) = @ 1.d0/(ch62*co2plusxini) if ( ch62*noxini .gt. 1.d-30 ) tauco2plus(62,i) = @ 1.d0/(ch62*noxini) if ( ch63*co2plusxini .gt. 1.d-30 ) taun(63,i) = @ 1.d0/(ch63*cplusxini) if ( ch63*nxini .gt. 1.d-30 ) tauco2plus(63,i) = @ 1.d0/(ch63*nxini) if ( ch64*o2plusxini .gt. 1.d-30 ) tauno(64,i) = @ 1.d0/(ch64*o2plusxini) if ( ch64*noxini .gt. 1.d-30 ) tauo2plus(64,i) = @ 1.d0/(ch64*noxini) if ( ch65*o2plusxini .gt. 1.d-30 ) taun2(65,i) = @ 1.d0/(ch65*o2plusxini) if ( ch65*n2xini .gt. 1.d-30 ) tauo2plus(65,i) = @ 1.d0/(ch65*n2xini) if ( ch66*o2plusxini .gt. 1.d-30 ) taun(66,i) = @ 1.d0/(ch66*o2plusxini) if ( ch66*nxini .gt. 1.d-30 ) tauo2plus(66,i) = @ 1.d0/(ch66*nxini) if ( ch67*oplusxini .gt. 1.d-30 ) taun2(67,i) = @ 1.d0/(ch67*oplusxini) if ( ch67*n2xini .gt. 1.d-30 ) tauoplus(67,i) = @ 1.d0/(ch67*n2xini) if ( ch68*n2plusxini .gt. 1.d-30 ) tauco2(68,i) = @ 1.d0/(ch68*n2plusxini) if ( ch68*co2xini .gt. 1.d-30 ) taun2plus(68,i) = @ 1.d0/(ch68*co2xini) if ( ch69*cplusxini .gt. 1.d-30 ) tauco2(69,i) = @ 1.d0/(ch69*cplusxini) if ( ch69*co2xini .gt. 1.d-30 ) taucplus(69,i) = @ 1.d0/(ch69*co2xini) if ( ch70*n2plusxini .gt. 1.d-30 ) tauco(70,i) = @ 1.d0/(ch70*n2plusxini) if ( ch70*coxini .gt. 1.d-30 ) taun2plus(70,i) = @ 1.d0/(ch70*coxini) if ( ch71*electxini .gt. 1.d-30 ) taun2plus(71,i) = @ 1.d0/(ch71*electxini) if ( ch72*n2plusxini .gt. 1.d-30 ) tauo3p(72,i) = @ 1.d0/(ch72*n2plusxini) if ( ch72*o3pxini .gt. 1.d-30 ) taun2plus(72,i) = @ 1.d0/(ch72*o3pxini) if ( ch73*coplusxini .gt. 1.d-30 ) tauh(73,i) = @ 1.d0/(ch73*coplusxini) if ( ch73*hxini .gt. 1.d-30 ) taucoplus(73,i) = @ 1.d0/(ch73*hxini) if ( ch74*oplusxini .gt. 1.d-30 ) tauh(74,i) = @ 1.d0/(ch74*oplusxini) if ( ch74*hxini .gt. 1.d-30 ) tauoplus(74,i) = @ 1.d0/(ch74*hxini) if ( ch75*electxini .gt. 1.d-30 ) taunoplus(75,i) = @ 1.d0/(ch75*electxini) if ( ch76*hplusxini .gt. 1.d-30 ) tauo3p(76,i) = @ 1.d0/(ch76*hplusxini) if ( ch76*o3pxini .gt. 1.d-30 ) tauhplus(76,i) = @ 1.d0/(ch76*o3pxini) if( jion8(11,i,1).gt.1.d-30 ) tauco(77,i) = $ 1.d0 / jion8(11,i,1) if( jion8(11,i,2).gt.1.d-30 ) tauco(78,i) = $ 1.d0 / jion8(11,i,2) !if( jion8(11,i,3).gt.1.d-30 ) tauco(79,i) = ! $ 1.d0 / jion8(11,i,3) if( jion8(10,i,1).gt.1.d-30 ) tauno(80,i) = $ 1.d0 / jion8(10,i,1) if( jion8(8,i,1).gt.1.d-30 ) taun2(81,i) = $ 1.d0 / jion8(8,i,1) if( jion8(8,i,2).gt.1.d-30 ) taun2(82,i) = $ 1.d0 / jion8(8,i,2) if( jion8(12,i,1).gt.1.d-30 ) tauh(83,i) = $ 1.d0 / jion8(12,i,1) if( jion8(9,i,1).gt.1.d-30 ) taun(84,i) = $ 1.d0 / jion8(9,i,1) if ( ch85*nplusxini .gt. 1.d-30 ) tauco2(85,i) = @ 1.d0/(ch85*nplusxini) if ( ch85*co2xini .gt. 1.d-30 ) taunplus(85,i) = @ 1.d0/(ch85*co2xini) if ( ch86*co2plusxini .gt. 1.d-30) tauh2(86,i) = $ 1.d0/(ch86*co2plusxini) if ( ch86*h2xini .gt. 1.d-30) tauco2plus(86,i) = $ 1.d0/(ch86*h2xini) if ( ch87*electxini .gt. 1.d-30) tauhco2plus(87,i) = $ 1.d0/(ch87*electxini) if ( jion8(9,i,1)*ionsec_nplus(zenit,zx(i)).gt.1.d-30) $ taun(88,i) = 1.d0 / $ (jion8(9,i,1)*ionsec_nplus(zenit,zx(i))) if ( jion8(8,i,1)*ionsec_n2plus(zenit,zx(i)).gt.1.d-30) $ taun2(89,i) = 1.d0 / $ (jion8(8,i,1)*ionsec_n2plus(zenit,zx(i))) if ( jion8(3,i,1)*ionsec_oplus(zenit,zx(i)).gt.1.d-30) $ tauo3p(90,i) = 1.d0 / $ (jion8(3,i,1)*ionsec_oplus(zenit,zx(i))) if (jion8(11,i,1)*ionsec_coplus(zenit,zx(i)).gt.1.d-30) $ tauco(91,i) = 1.d0 / $ (jion8(11,i,1)*ionsec_coplus(zenit,zx(i))) if (jion8(1,i,1)*ionsec_co2plus(zenit,zx(i)).gt.1.d-30) $ tauco2(92,i) = 1.d0 / $ (jion8(1,i,1)*ionsec_co2plus(zenit,zx(i))) if ( jion8(2,i,1)*ionsec_o2plus(zenit,zx(i)).gt.1.d-30) $ tauo2(93,i) = 1.d0 / $ (jion8(2,i,1)*ionsec_o2plus(zenit,zx(i))) endif !Of chemthermod.eq.3 c>>>>>>>>>>>>>>>>>>>>>>>> !Minimum lifetime for each species tminco2(i) = 1.d30 tmino2(i) = 1.d30 tmino3p(i) = 1.d30 tminco(i) = 1.d30 tminh(i) = 1.d30 tminoh(i) = 1.d30 tminho2(i) = 1.d30 tminh2(i) = 1.d30 tminh2o(i) = 1.d30 tmino1d(i) = 1.d30 tminh2o2(i) = 1.d30 tmino3(i) = 1.d30 tminn(i) = 1.d30 tminno(i) = 1.d30 tminn2(i) = 1.d30 tminn2d(i) = 1.d30 tminno2(i) = 1.d30 tminco2plus(i) = 1.d30 tminoplus(i) = 1.d30 tmino2plus(i) = 1.d30 tmincoplus(i) = 1.d30 tmincplus(i) = 1.d30 tminnplus(i) = 1.d30 tminn2plus(i) = 1.d30 tminnoplus(i) = 1.d30 tminhplus(i) = 1.d30 tminhco2plus(i)=1.d30 do j=1,nreact tminco2(i) = min(tminco2(i),tauco2(j,i)) tmino2(i) = min(tmino2(i),tauo2(j,i)) tmino3p(i) = min(tmino3p(i),tauo3p(j,i)) tminco(i) = min(tminco(i),tauco(j,i)) tminh(i) = min(tminh(i),tauh(j,i)) tminoh(i) = min(tminoh(i),tauoh(j,i)) tminho2(i) = min(tminho2(i),tauho2(j,i)) tminh2(i) = min(tminh2(i),tauh2(j,i)) tminh2o(i) = min(tminh2o(i),tauh2o(j,i)) tmino1d(i) = min(tmino1d(i),tauo1d(j,i)) tminh2o2(i) = min(tminh2o2(i),tauh2o2(j,i)) tmino3(i) = min(tmino3(i),tauo3(j,i)) tminn(i) = min(tminn(i),taun(j,i)) tminno(i) = min(tminno(i),tauno(j,i)) tminn2(i) = min(tminn2(i),taun2(j,i)) tminn2d(i) = min(tminn2d(i),taun2d(j,i)) tminno2(i) = min(tminno2(i),tauno2(j,i)) ! tminco2plus(i) = min(tminco2plus(i),tauco2plus(j,i)) tminoplus(i) = min(tminoplus(i),tauoplus(j,i)) tmino2plus(i) = min(tmino2plus(i),tauo2plus(j,i)) tmincoplus(i) = min(tmincoplus(i),taucoplus(j,i)) tmincplus(i) = min(tmincplus(i),taucplus(j,i)) tminnplus(i) = min(tminnplus(i),taunplus(j,i)) tminn2plus(i) = min(tminn2plus(i),taun2plus(j,i)) tminnoplus(i) = min(tminnoplus(i),taunoplus(j,i)) tminhplus(i) = min(tminhplus(i),tauhplus(j,i)) tminhco2plus(i)= min(tminhco2plus(i),tauhco2plus(j,i)) end do !!! Minimum lifetime for all species xtmin = 1.d30 ! Neutrals that can not be in PE xtmin = min(xtmin,tminco2(i)) if(xtmin.eq.tminco2(i)) xcompmin=1 xtmin = min(xtmin,tmino2(i)) if(xtmin.eq.tmino2(i)) xcompmin=2 xtmin = min(xtmin,tmino3p(i)) if(xtmin.eq.tmino3p(i)) xcompmin=3 xtmin = min(xtmin,tminco(i)) if(xtmin.eq.tminco(i)) xcompmin=4 xtmin = min(xtmin,tminh2(i)) if(xtmin.eq.tminh2(i)) xcompmin=8 xtmin = min(xtmin,tminh2o(i)) if(xtmin.eq.tminh2o(i)) xcompmin=9 xtmin = min(xtmin,tminh2o2(i)) if(xtmin.eq.tminh2o2(i)) xcompmin=11 xtmin = min(xtmin,tmino3(i)) if(xtmin.eq.tmino3(i)) xcompmin=12 xtmin = min(xtmin,tminn(i)) if(xtmin.eq.tminn(i)) xcompmin=13 xtmin = min(xtmin,tminno(i)) if(xtmin.eq.tminno(i)) xcompmin=14 xtmin = min(xtmin,tminn2(i)) if(xtmin.eq.tminn2(i)) xcompmin=15 ! Neutrals that can be in PE ! [ O1D , OH , HO2 , H , N2D , NO2 ] xn_comp_en_EQ = 0 ! H h_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! OH oh_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! HO2 ho2_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! O1D o1d_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! O3 o3_eq(i)='N' ! o3_eq(i)='Y' ! xn_comp_en_EQ = xn_comp_en_EQ + 1 !Only if N or ion chemistry requested if(chemthermod.ge.2) then ! N2D n2d_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! NO2 no2_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! NO no_eq(i)='N' ! no_eq(i)='Y' ! xn_comp_en_EQ = xn_comp_en_EQ + 1 endif !Of chemthermod.ge.2 ! Ions !Only if ion chemistry requested if(chemthermod.eq.3) then ! C+ cplus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! CO+ coplus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! O+ ! oplus_eq(i)='N' oplus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! N2+ n2plus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! H+ ! hplus_eq(i)='N' hplus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! CO2+ co2plus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! O2+ o2plus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! NO+ noplus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! N+ nplus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 ! HCO2+ hco2plus_eq(i)='Y' xn_comp_en_EQ = xn_comp_en_EQ + 1 endif !Of chemthermod.eq.3 return c END end c********************************************************************** c********************************************************************** subroutine timemarching( ig,i,nlayer,chemthermod,n_comp_en_EQ, $ compmin,tmin,timefrac_sec, deltat,fmargin1 ) c Calculates the timestep of the model, deltat, and verifies if the species c that can be in PE actually verify or not the PE condition c c jul 2008 MA Version en subrutina c 2009 FGG Adaptation to GCM c********************************************************************** use iono_h use param_v4_h, only: tminco2,tmino2,tmino3p,tminco,tminh,tminoh, . tminho2,tminh2,tminh2o,tmino1d,tminh2o2,tmino3,tminn,tminno, . tminno2,tminn2,tminn2d,tminco2plus,tminoplus,tmino2plus, . tmincoplus,tmincplus,tminnplus,tminnoplus,tminn2plus, . tminhplus,tminhco2plus implicit none c arguments c integer i,ig,nlayer ! I. Layer integer chemthermod integer n_comp_en_EQ(nlayer) ! Number of species in PE integer compmin(nlayer) ! Species with minimum lifetime real*8 tmin(nlayer) ! Minimum lifetime real*8 timefrac_sec ! I. real*8 deltat ! O. TimeMarching step c local variables c integer j real*8 tminaux real*8 fmargin1, fmargin2 ccccccccccccccc CODE STARTS ! fmargin1=1. fmargin2=5. !Internal timestep as the minimum of the external (GCM) timestep !and the minimum lifetime of the species not in PE divided by a !given factor tminaux = min( timefrac_sec, tmin(i)/fmargin1 ) !Given the internal timestep, we verify if the species that can be !in PE verify or not the PE condition (lifetime < deltat/fmargin2) ! 6 neutral species that can be in PE ! [ O1D , OH , HO2 , H , N2D , NO2 ] ! O1D if ( (o1d_eq(i).eq.'Y') .and. & (tmino1d(i).gt.tminaux/fmargin2) ) then o1d_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! OH if ( (oh_eq(i).eq.'Y') .and. & (tminoh(i).gt.tminaux/fmargin2) ) then oh_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! HO2 if ( (ho2_eq(i).eq.'Y') .and. & (tminho2(i).gt.tminaux/fmargin2) ) then ho2_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! H if ( (h_eq(i).eq.'Y') .and. & (tminh(i).gt.tminaux/fmargin2) ) then h_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif !Only if N or ion chemistry requested if(chemthermod.ge.2) then ! N2D if ( (n2d_eq(i).eq.'Y') .and. & (tminn2d(i).gt.tminaux/fmargin2) ) then n2d_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! NO2 if ( (no2_eq(i).eq.'Y') .and. & (tminno2(i).gt.tminaux/fmargin2) ) then no2_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif endif !Of chemthermod.ge.2 ! ! 9 ions ! !Only if ion chemistry requested if(chemthermod.eq.3) then ! C+ if ( (cplus_eq(i).eq.'Y') .and. & (tmincplus(i).gt.tminaux/fmargin2) ) then cplus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! CO+ if ( (coplus_eq(i).eq.'Y') .and. & (tmincoplus(i).gt.tminaux/fmargin2) ) then coplus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! O+ if ( (oplus_eq(i).eq.'Y') .and. & (tminoplus(i).gt.tminaux/fmargin2) ) then oplus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! N2+ if ( (n2plus_eq(i).eq.'Y') .and. & (tminn2plus(i).gt.tminaux/fmargin2) ) then n2plus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! H+ if ( (hplus_eq(i).eq.'Y') .and. & (tminhplus(i).gt.tminaux/fmargin2) ) then hplus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! CO2+ if ( (co2plus_eq(i).eq.'Y') .and. & (tminco2plus(i).gt.tminaux/fmargin2) ) then co2plus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! O2+ if ( (o2plus_eq(i).eq.'Y') .and. & (tmino2plus(i).gt.tminaux/fmargin2) ) then o2plus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! NO+ if ( (noplus_eq(i).eq.'Y') .and. & (tminnoplus(i).gt.tminaux/fmargin2) ) then noplus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! N+ if ( (nplus_eq(i).eq.'Y') .and. & (tminnplus(i).gt.tminaux/fmargin2) ) then nplus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif ! HCO2+ if ( (hco2plus_eq(i).eq.'Y') .and. & (tminhco2plus(i).gt.tminaux/fmargin2) ) then hco2plus_eq(i)='N' n_comp_en_EQ(i) = n_comp_en_EQ(i) - 1 endif endif !Of chemthermod.eq.3 ! And we set the internal timestep ! deltat = tminaux return c END end c********************************************************************** c********************************************************************** subroutine prodsandlosses ( ig,i,nlayer,chemthermod,zenit,zx, & jdistot8, jdistot8_b, jion8, & co2xinput, o2xinput, o3pxinput, & coxinput, h2xinput, o3xinput, & h2oxinput, nxinput, noxinput, & h2o2xinput, n2xinput, & o1dxinput, ohxinput, ho2xinput, & hxinput, n2dxinput, no2xinput, & co2plusxinput, o2plusxinput, coplusxinput, & oplusxinput, cplusxinput, noplusxinput, & n2plusxinput, hplusxinput, nplusxinput, & hco2plusxinput,electxinput ) c Calculates the productions and losses of each species in each reaction c and each altitude c c jul 2008 MA Version en subrutina c apr 2009 FGG Compact version to save CPU time, adaptation c to GCM c********************************************************************** use param_v4_h implicit none c arguments c integer ig,nlayer integer i ! I. Layer integer chemthermod real zx(nlayer) real zenit real*8 jdistot8(nabs,nlayer) real*8 jdistot8_b(nabs,nlayer) real*8 jion8(nabs,nlayer,4) real*8 co2xinput,o2xinput,o3pxinput,coxinput real*8 ho2xinput,h2xinput,hxinput,ohxinput real*8 h2o2xinput,o1dxinput,o3xinput,h2oxinput real*8 nxinput,noxinput,n2xinput,n2dxinput,no2xinput real*8 co2plusxinput,coplusxinput,oplusxinput,o2plusxinput real*8 cplusxinput,noplusxinput,n2plusxinput,hplusxinput real*8 electxinput,nplusxinput,hco2plusxinput c local variables c integer j external ionsec_nplus real*8 ionsec_nplus external ionsec_n2plus real*8 ionsec_n2plus external ionsec_oplus real*8 ionsec_oplus external ionsec_coplus real*8 ionsec_coplus external ionsec_co2plus real*8 ionsec_co2plus external ionsec_o2plus real*8 ionsec_o2plus logical firstcall save firstcall data firstcall /.true./ ccccccccccccccc CODE STARTS !Initialization' ! if (firstcall) then ! firstcall= .false. do j=1,nreact Lco2(i,j) = 0.d0 Pco2(i,j) = 0.d0 Lo2(i,j) = 0.d0 Po2(i,j) = 0.d0 Lo3p(i,j) = 0.d0 Po3p(i,j) = 0.d0 Lco(i,j) = 0.d0 Pco(i,j) = 0.d0 Ph(i,j) = 0.d0 Lh(i,j) = 0.d0 Poh(i,j) = 0.d0 Loh(i,j) = 0.d0 Pho2(i,j) = 0.d0 Lho2(i,j) = 0.d0 Ph2(i,j) = 0.d0 Lh2(i,j) = 0.d0 Ph2o(i,j) = 0.d0 Lh2o(i,j) = 0.d0 Po1d(i,j) = 0.d0 Lo1d(i,j) = 0.d0 Ph2o2(i,j) = 0.d0 Lh2o2(i,j) = 0.d0 Po3(i,j) = 0.d0 Lo3(i,j) = 0.d0 Pn(i,j) = 0.d0 Ln(i,j) = 0.d0 Pno(i,j) = 0.d0 Lno(i,j) = 0.d0 Pn2(i,j) = 0.d0 Ln2(i,j) = 0.d0 Pn2d(i,j) = 0.d0 Ln2d(i,j) = 0.d0 Pno2(i,j) = 0.d0 Lno2(i,j) = 0.d0 Lco2plus(i,j) = 0.d0 Pco2plus(i,j) = 0.d0 Loplus(i,j) = 0.d0 Poplus(i,j) = 0.d0 Lo2plus(i,j) = 0.d0 Po2plus(i,j) = 0.d0 Pcoplus(i,j) = 0.d0 Lcoplus(i,j) = 0.d0 Pcplus(i,j) = 0.d0 Lcplus(i,j) = 0.d0 Pnplus(i,j) = 0.d0 Lnplus(i,j) = 0.d0 Pnoplus(i,j) = 0.d0 Lnoplus(i,j) = 0.d0 Pn2plus(i,j) = 0.d0 Ln2plus(i,j) = 0.d0 Phplus(i,j) = 0.d0 Lhplus(i,j) = 0.d0 Phco2plus(i,j) = 0.d0 Lhco2plus(i,j) = 0.d0 Pelect(i,j) = 0.d0 Lelect(i,j) = 0.d0 end do Pco2tot(i) = 0.d0 Lco2tot(i) = 0.d0 Po2tot(i) = 0.d0 Lo2tot(i) = 0.d0 Po3ptot(i) = 0.d0 Lo3ptot(i) = 0.d0 Pcotot(i) = 0.d0 Lcotot(i) = 0.d0 Phtot(i) = 0.d0 Lhtot(i) = 0.d0 Pohtot(i) = 0.d0 Lohtot(i) = 0.d0 Pho2tot(i) = 0.d0 Lho2tot(i) = 0.d0 Ph2tot(i) = 0.d0 Lh2tot(i) = 0.d0 Ph2otot(i) = 0.d0 Lh2otot(i) = 0.d0 Po1dtot(i) = 0.d0 Lo1dtot(i) = 0.d0 Ph2o2tot(i) = 0.d0 Lh2o2tot(i) = 0.d0 Po3tot(i) = 0.d0 Lo3tot(i) = 0.d0 Pntot(i) = 0.d0 Lntot(i) = 0.d0 Pnotot(i) = 0.d0 Lnotot(i) = 0.d0 Pn2tot(i) = 0.d0 Ln2tot(i) = 0.d0 Pn2dtot(i) = 0.d0 Ln2dtot(i) = 0.d0 Pno2tot(i) = 0.d0 Lno2tot(i) = 0.d0 ! Pco2plustot(i) = 0.d0 Lco2plustot(i) = 0.d0 Loplustot(i) = 0.d0 Poplustot(i) = 0.d0 Lo2plustot(i) = 0.d0 Po2plustot(i) = 0.d0 Lcoplustot(i) = 0.d0 Pcoplustot(i) = 0.d0 Lcplustot(i) = 0.d0 Pcplustot(i) = 0.d0 Lnplustot(i) = 0.d0 Pnplustot(i) = 0.d0 Lnoplustot(i) = 0.d0 Pnoplustot(i) = 0.d0 Ln2plustot(i) = 0.d0 Pn2plustot(i) = 0.d0 Lhplustot(i) = 0.d0 Phplustot(i) = 0.d0 Lhco2plustot(i) = 0.d0 Phco2plustot(i) = 0.d0 Pelecttot(i) = 0.0d0 Lelecttot(i) = 0.0d0 ! endif !!! Productions and losses reaction by reaction c R1: CO2 + hv -> CO + O Lco2(i,1) = jdistot8(1,i) Pco(i,1) = co2xinput * jdistot8(1,i) Po3p(i,1) = Pco(i,1)!co2xinput * jdistot8(1,i) c R16(1b): CO2 + hv -> CO + O1D Lco2(i,16) = jdistot8_b(1,i) Pco(i,16) = co2xinput * jdistot8_b(1,i) Po1d(i,16) = Pco(i,16)!co2xinput * jdistot8_b(1,i) c R2: H + O2 + CO2 -> HO2 + CO2 Lh(i,2) = ch2 * o2xinput * co2xinput Lo2(i,2) = ch2 * hxinput * co2xinput Pho2(i,2) = ch2 * hxinput * o2xinput * co2xinput c R3: O + HO2 -> OH + O2 Lo3p(i,3) = ch3 * ho2xinput Lho2(i,3) = ch3 * o3pxinput Poh(i,3) = ch3 * o3pxinput * ho2xinput Po2(i,3) = Poh(i,3)!ch3 * o3pxinput * ho2xinput c R4: CO + OH -> CO2 + H Lco(i,4) = ch4 * ohxinput Loh(i,4) = ch4 * coxinput Pco2(i,4) = ch4 * coxinput * ohxinput Ph(i,4) = Pco2(i,4)!ch4 * coxinput * ohxinput c R5: 2HO2 -> H2O2 + O2 Lho2(i,5) = 2.d0 * ch5 * ho2xinput Po2(i,5) = ch5 * ho2xinput * ho2xinput Ph2o2(i,5) = Po2(i,5)!ch5 * ho2xinput * ho2xinput c R6: H2O2 + hv -> 2OH Lh2o2(i,6) = jdistot8(6,i) Poh(i,6) = 2.d0 * jdistot8(6,i) * h2o2xinput c R7: OH + HO2 -> H2O + O2 Loh(i,7) = ch7 * ho2xinput Lho2(i,7) = ch7 * ohxinput Po2(i,7) = ch7 * ohxinput * ho2xinput Ph2o(i,7) = Po2(i,7)!ch7 * ohxinput * ho2xinput c R8: H20 + hv -> H + OH Lh2o(i,8) = jdistot8(4,i) Ph(i,8) = jdistot8(4,i) * h2oxinput Poh(i,8) = Ph(i,8)!jdistot8(4,i) * h2oxinput c R9: O(1D) + H2O -> 2OH Lo1d(i,9) = ch9 * h2oxinput Lh2o(i,9) = ch9 * o1dxinput Poh(i,9) = 2.d0 * ch9 * o1dxinput * h2oxinput c R10: 2O + CO2 -> O2 + CO2 Lo3p(i,10) = 2.d0 * ch10 * o3pxinput * co2xinput Po2(i,10) = ch10 * o3pxinput * o3pxinput * co2xinput c R11: O + OH -> O2 + H Lo3p(i,11) = ch11 * ohxinput Loh(i,11) = ch11 * o3pxinput Po2(i,11) = ch11 * o3pxinput * ohxinput Ph(i,11) = Po2(i,11)!ch11 * o3pxinput * ohxinput c R12: O2 + hv -> 2O Lo2(i,12) = jdistot8(2,i) Po3p(i,12) = 2.d0 * jdistot8(2,i) * o2xinput c R17(12b): O2 + hv -> O + O1D Lo2(i,17) = jdistot8_b(2,i) Po3p(i,17) = jdistot8_b(2,i) * o2xinput Po1d(i,17) = Po3p(i,17)!jdistot8_b(2,i) * o2xinput c R13: H + HO2 -> H2 + O2 Lh(i,13) = ch13 * ho2xinput Lho2(i,13) = ch13 * hxinput Ph2(i,13) = ch13 * hxinput * ho2xinput Po2(i,13) = Ph2(i,13)!ch13 * hxinput * ho2xinput c R14: O(1D) + H2 -> H + OH Lo1d(i,14) = ch14 * h2xinput Lh2(i,14) = ch14 * o1dxinput Ph(i,14) = ch14 * o1dxinput * h2xinput Poh(i,14) = Ph(i,14)!ch14 * o1dxinput * h2xinput c R15: OH + H2 -> H + H20 Loh(i,15) = ch15 * h2xinput Lh2(i,15) = ch15 * ohxinput Ph(i,15) = ch15 * ohxinput * h2xinput Ph2o(i,15) = Ph(i,15)!ch15 * ohxinput * h2xinput c R18: OH + H2O2 -> H2O + HO2 Loh(i,18) = ch18 * h2o2xinput Lh2o2(i,18) = ch18 * ohxinput Ph2o(i,18) = ch18 * ohxinput * h2o2xinput Pho2(i,18) = Ph2o(i,18)!ch18 * ohxinput * h2o2xinput c R19: O(1D) + CO2 -> O + CO2 Lo1d(i,19) = ch19 * co2xinput Po3p(i,19) = ch19 * o1dxinput * co2xinput c R20: O(1D) + O2 -> O + O2 Lo1d(i,20) = ch20 * o2xinput Po3p(i,20) = ch20 * o1dxinput * o2xinput c R21: O + O2 + CO2 -> O3 + CO2 Lo3p(i,21) = ch21 * o2xinput * co2xinput Lo2(i,21) = ch21 * o3pxinput * co2xinput Po3(i,21) = ch21 * o3pxinput * o2xinput * co2xinput !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) then c R22: O3 + H -> OH + O2 Lo3(i,22) = ch22 * hxinput Lh(i,22) = ch22 * o3xinput Poh(i,22) = ch22 * o3xinput * hxinput Po2(i,22) = Poh(i,22) !ch22 * o3xinput * hxinput c R23: O3 + OH -> HO2 + O2 Lo3(i,23) = ch23 * ohxinput Loh(i,23) = ch23 * o3xinput Pho2(i,23) = ch23 * ohxinput * o3xinput Po2(i,23) = Pho2(i,23) !ch23 * ohxinput * o3xinput c R24: O3 + HO2 -> OH + 2O2 Lo3(i,24) = ch24 * ho2xinput Lho2(i,24) = ch24 * o3xinput Poh(i,24) = ch24 * o3xinput * ho2xinput Po2(i,24) = Poh(i,24) !2.d0 * ch24 * o3xinput * ho2xinput c R25: O3 + hv -> O2 + O3P Lo3(i,25) = jdistot8(7,i) Po2(i,25) = jdistot8(7,i) * o3xinput Po3p(i,25) = Po2(i,25) !jdistot8(7,i) * o3xinput c R26 (R25_b): O3 + hv -> O2 + O1D Lo3(i,26) = jdistot8_b(7,i) Po2(i,26) = jdistot8_b(7,i) * o3xinput Po1d(i,26) = Po2(i,26) !jdistot8_b(7,i) * o3xinput endif !Of chemthermod.ge.1 c R27: H2 + hv -> 2H Lh2(i,27) = jdistot8(5,i) Ph(i,27) = 2.d0 * jdistot8(5,i) * h2xinput !Only if N or ion chemistry requested if(chemthermod.ge.2) then c R28: N2 + hv -> N + N2D Ln2(i,28) = jdistot8(8,i) Pn(i,28) = jdistot8(8,i) * n2xinput Pn2d(i,28) = Pn(i,28) !jdistot8(8,i) * n2xinput c R29: NO + hv -> N + O Lno(i,29) = jdistot8(10,i) Pn(i,29) = jdistot8(10,i) * noxinput Po3p(i,29) = Pn(i,29) !jdistot8(10,i) * noxinput c R30: N + NO -> N2 + O Ln(i,30) = ch30 * noxinput Lno(i,30) = ch30 * nxinput Pn2(i,30) = ch30 * nxinput * noxinput Po3p(i,30) = Pn2(i,30) !ch30 * nxinput * noxinput c R31: N2 + O1D -> N2 + O Lo1d(i,31) = ch31 * n2xinput Po3p(i,31) = ch31 * n2xinput * o1dxinput c R32: N + O2 -> NO + O Ln(i,32) = ch32 * o2xinput Lo2(i,32) = ch32 * nxinput Pno(i,32) = ch32 * o2xinput * nxinput Po3p(i,32) = Pno(i,32) !ch32 * o2xinput * nxinput c R33: N + OH -> NO + H Ln(i,33) = ch33 * ohxinput Loh(i,33) = ch33 * nxinput Pno(i,33) = ch33 * nxinput * ohxinput Ph(i,33) = Pno(i,33) !Pch33 * nxinput * ohxinput c R34: N + O3 -> NO + O2 Ln(i,34) = ch34 * o3xinput Lo3(i,34) = ch34 * nxinput Pno(i,34) = ch34 * nxinput * o3xinput Po2(i,34) = Pno(i,34) !ch34 * nxinput * o3xinput c R35: N + HO2 -> NO + OH Ln(i,35) = ch35 * ho2xinput Lho2(i,35) = ch35 * nxinput Pno(i,35) = ch35 * nxinput * ho2xinput Poh(i,35) = Pno(i,35) !ch35 * nxinput * ho2xinput c R36: N2D + O -> N + O Ln2d(i,36) = ch36 * o3pxinput Pn(i,36) = ch36 * n2dxinput * o3pxinput c R37: N2D + N2 -> N + N2 Ln2d(i,37) = ch37 * n2xinput Pn(i,37) = ch37 * n2dxinput * n2xinput c R38: N2D + CO2 -> NO + CO Ln2d(i,38) = ch38 * co2xinput Lco2(i,38) = ch38 * n2dxinput Pno(i,38) = ch38 * n2dxinput * co2xinput Pco(i,38) = Pno(i,38) !ch38 * n2dxinput * co2xinput c R39: NO + HO2 -> NO2 + OH Lno(i,39) = ch39 * ho2xinput Lho2(i,39) = ch39 * noxinput Pno2(i,39) = ch39 * noxinput * ho2xinput Poh(i,39) = Pno2(i,39) !ch39 * noxinput * ho2xinput c R40: O + NO + CO2 -> NO2 + CO2 Lo3p(i,40) = ch40 * noxinput * co2xinput Lno(i,40) = ch40 * o3pxinput * co2xinput Pno2(i,40) = ch40 * o3pxinput * noxinput * co2xinput c R41: O + NO2 -> NO + O2 Lo3p(i,41) = ch41 * no2xinput Lno2(i,41) = ch41 * o3pxinput Pno(i,41) = ch41 * o3pxinput * no2xinput Po2(i,41) = Pno(i,41) !ch41 * o3pxinput * no2xinput c R42: NO + O3 -> NO2 + O2 Lno(i,42) = ch42 * o3xinput Lo3(i,42) = ch42 * noxinput Pno2(i,42) = ch42 * noxinput * o3xinput Po2(i,42) = Pno2(i,42) !ch42 * noxinput * o3xinput c R43: H + NO2 -> NO + OH Lh(i,43) = ch43 * no2xinput Lno2(i,43) = ch43 * hxinput Pno(i,43) = ch43 * no2xinput * hxinput Poh(i,43) = Pno(i,43) !ch43 * no2xinput * hxinput c R44: NO2 + hv -> NO + O Lno2(i,44) = jdistot8(13,i) Pno(i,44) = jdistot8(13,i) * no2xinput Po3p(i,44) = Pno(i,44) !jdistot8(13,i) * no2xinput c R45: N + O -> NO Ln(i,45) = ch45 * o3pxinput Lo3p(i,45) = ch45 * nxinput Pno(i,45) = ch45 * o3pxinput * nxinput endif !Of chemthermod.ge.2 ! >>>> IONOSFERA !Only if ion chemistry requested if(chemthermod.eq.3) then c R46: CO2+ + O2 -> CO2 + O2+ Lco2plus(i,46) = ch46 * o2xinput Lo2(i,46) = ch46 * co2plusxinput Pco2(i,46) = ch46 * co2plusxinput * o2xinput Po2plus(i,46) = Pco2(i,46) !ch46 * co2plusxinput * o2xinput c R47: CO2+ + O -> O+ + CO2 Lco2plus(i,47) = ch47 * o3pxinput Lo3p(i,47) = ch47 * co2plusxinput Pco2(i,47) = ch47 * co2plusxinput * o3pxinput Poplus(i,47) = Pco2(i,47) !ch47 * co2plusxinput * o3pxinput c R48: CO2+ O -> O2+ + CO Lco2plus(i,48) = ch48 * o3pxinput Lo3p(i,48) = ch48 * co2plusxinput Po2plus(i,48) = ch48 * co2plusxinput * o3pxinput Pco(i,48) = Po2plus(i,48) !ch48 * co2plusxinput * o3pxinput c R49: O2+ + e -> O + O Lo2plus(i,49) = ch49 * electxinput Lelect(i,49) = ch49 * o2plusxinput Po3p(i,49) = ch49 * o2plusxinput * electxinput *2.d0 c R50: O+ + CO2 -> O2+ + CO Loplus(i,50) = ch50 * co2xinput Lco2(i,50) = ch50 * oplusxinput Po2plus(i,50)= ch50 * oplusxinput * co2xinput Pco(i,50) = Po2plus(i,50) !ch50 * oplusxinput * co2xinput c R51: CO2 + hv -> CO2+ + e Lco2(i,51) = jion8(1,i,1) Pco2plus(i,51) = co2xinput * jion8(1,i,1) Pelect(i,51) = Pco2plus(i,51) !co2xinput * jion8(1,i,1) c R52: CO2 + hv --> O+ + CO + e Lco2(i,52) = jion8(1,i,2) Pco(i,52) = co2xinput * jion8(1,i,2) Poplus(i,52) = Pco(i,52) !co2xinput * jion8(1,i,2) Pelect(i,52) = Pco(i,52) !co2xinput * jion8(1,i,2) c R53: CO2 + hv --> CO+ + O + e Lco2(i,53) = jion8(1,i,3) Pcoplus(i,53) = co2xinput * jion8(1,i,3) Po3p(i,53) = Pcoplus(i,53) !co2xinput * jion8(1,i,3) Pelect(i,53) = Pcoplus(i,53) !co2xinput * jion8(1,i,3) c R54: CO2 + hv --> C+ + O2 + e Lco2(i,54) = jion8(1,i,4) Pcplus(i,54) = co2xinput * jion8(1,i,4) Po2(i,54) = Pcplus(i,54) !co2xinput * jion8(1,i,4) Pelect(i,54) = Pcplus(i,54) !co2xinput * jion8(1,i,4) c R55: CO2+ + e --> CO + O Lco2plus(i,55) = ch55 * electxinput Lelect(i,55) = ch55 * co2plusxinput Pco(i,55) = ch55 * co2plusxinput * electxinput Po3p(i,55) = Pco(i,55) !ch55 * co2plusxinput * electxinput c R56: O+ + CO2 --> O2 + CO+ Probablemente no se dá Lco2(i,56) = ch56 * oplusxinput Loplus(i,56) = ch56 * co2xinput Po2(i,56) = ch56 * co2xinput * oplusxinput Pcoplus(i,56)= Po2(i,56) !ch56 * co2xinput * oplusxinput c R57: CO+ + CO2 --> CO2+ + CO Lco2(i,57) = ch57 * coplusxinput Lcoplus(i,57) = ch57 * co2xinput Pco2plus(i,57)= ch57 * coplusxinput * co2xinput Pco(i,57) = Pco2plus(i,57) !ch57 * coplusxinput * co2xinput c R58: CO+ + O --> O+ + CO Lo3p(i,58) = ch58 * coplusxinput Lcoplus(i,58) = ch58 * o3pxinput Poplus(i,58) = ch58 * coplusxinput * o3pxinput Pco(i,58) = Poplus(i,58) !ch58 * coplusxinput * o3pxinput c R59: C+ + CO2 --> CO+ + CO Lco2(i,59) = ch59 * cplusxinput Lcplus(i,59) = ch59 * co2xinput Pcoplus(i,59)= ch59 * cplusxinput * co2xinput Pco(i,59) = Pcoplus(i,59) !ch59 * cplusxinput * co2xinput c R60: O2 + hv --> O2+ + e Lo2(i,60) = jion8(2,i,1) Po2plus(i,60) = o2xinput * jion8(2,i,1) Pelect(i,60) = Po2plus(i,60) !o2xinput * jion8(2,i,1) c R61: O + hv --> O+ + e Lo3p(i,61) = jion8(3,i,1) Poplus(i,61) = o3pxinput * jion8(3,i,1) Pelect(i,61) = Poplus(i,61) !o3pxinput * jion8(3,i,1) c R62 : CO2+ + NO --> NO+ + CO2 Lco2plus(i,62) = ch62 * noxinput Lno(i,62) = ch62 * co2plusxinput Pnoplus(i,62) = ch62 * co2plusxinput * noxinput Pco2(i,62) = Pnoplus(i,62) !ch62 * co2plusxinput * noxinput c R63 : CO2+ + N --> NO + CO+ Lco2plus(i,63) = ch63 * nxinput Ln(i,63) = ch63 * co2plusxinput Pcoplus(i,63) = ch63 * co2plusxinput * nxinput Pno(i,63) = Pcoplus(i,63) !ch63 * co2plusxinput * nxinput c R64 : O2+ + NO --> NO+ + O2 Lo2plus(i,64) = ch64 * noxinput Lno(i,64) = ch64 * o2plusxinput Pnoplus(i,64) = ch64 * o2plusxinput * noxinput Po2(i,64) = Pnoplus(i,64) !ch64 * o2plusxinput * noxinput c R65 : O2+ + N2 --> NO+ + NO Lo2plus(i,65) = ch65 * n2xinput Ln2(i,65) = ch65 * o2plusxinput Pnoplus(i,65) = ch65 * o2plusxinput * n2xinput Pno(i,65) = Pnoplus(i,65) !ch65 * o2plusxinput * n2xinput c R66: O2+ + N --> NO+ + O Lo2plus(i,66) = ch66 * nxinput Ln(i,66) = ch66 * o2plusxinput Pnoplus(i,66) = ch66 * o2plusxinput * nxinput Po3p(i,66) = Pnoplus(i,66) !ch66 * o2plusxinput * nxinput c R67 : O+ + N2 --> NO+ + N Loplus(i,67) = ch67 * n2xinput Ln2(i,67) = ch67 * oplusxinput Pnoplus(i,67) = ch67 * oplusxinput * n2xinput Pn(i,67) = Pnoplus(i,67) !ch67 * oplusxinput * n2xinput c R68 : N2+ + CO2 --> CO2+ + N2 Ln2plus(i,68) = ch68 * co2xinput Lco2(i,68) = ch68 * n2plusxinput Pco2plus(i,68) = ch68 * n2plusxinput * co2xinput Pn2(i,68) = Pco2plus(i,68) !ch68 * n2plusxinput * co2xinput c R69 : N2+ + O3p --> NO+ + N Ln2plus(i,69) = ch69 * o3pxinput Lo3p(i,69) = ch69 * n2plusxinput Pnoplus(i,69) = ch69 * n2plusxinput * o3pxinput Pn(i,69) = Pnoplus(i,69) !ch69 * n2plusxinput * o3pxinput c R70 : N2+ + CO --> N2 + CO+ Ln2plus(i,70) = ch70 * coxinput Lco(i,70) = ch70 * n2plusxinput Pcoplus(i,70) = ch70 * n2plusxinput * coxinput Pn2(i,70) = Pcoplus(i,70) !ch70 * n2plusxinput * coxinput c R71 : N2+ + e- --> N + N Ln2plus(i,71) = ch71 * electxinput Lelect(i,71) = ch71 * n2plusxinput Pn(i,71) = 2. * ch71 * n2plusxinput * electxinput c R72 : N2+ + O3p --> O+ + N2 Ln2plus(i,72) = ch72 * o3pxinput Lo3p(i,72) = ch72 * n2plusxinput Poplus(i,72) = ch72 * n2plusxinput * o3pxinput Pn2(i,72) = Poplus(i,72) !ch72 * n2plusxinput * o3pxinput c R73 : CO+ + H --> H+ + CO Lcoplus(i,73) = ch73 * hxinput Lh(i,73) = ch73 * coplusxinput Phplus(i,73) = ch73 * coplusxinput * hxinput Pco(i,73) = Phplus(i,73) !ch73 * coplusxinput * hxinput c R74 : O+ + H --> H+ + O Loplus(i,74) = ch74 * hxinput Lh(i,74) = ch74 * oplusxinput Phplus(i,74) = ch74* oplusxinput * hxinput Po3p(i,74) = Phplus(i,74) !ch74 * oplusxinput * hxinput c R75: NO+ + e- --> N + O Lnoplus(i,75) = ch75 * electxinput Lelect(i,75) = ch75 * noplusxinput Pn(i,75)= ch75 * noplusxinput * electxinput Po3p(i,75)= Pn(i,75) !ch75 * noplusxinput * electxinput c R76: H+ + O3p --> O+ + H Lhplus(i,76) = ch76 * o3pxinput Lo3p(i,76) = ch76 * hplusxinput Poplus(i,76) = ch76 * hplusxinput * o3pxinput Ph(i,76) = Poplus(i,76) !ch76 * hplusxinput * o3pxinput c R77: CO + hv --> CO+ + e- Lco(i,77) = jion8(11,i,1) Pcoplus(i,77) = coxinput * jion8(11,i,1) Pelect(i,77) = Pcoplus(i,77) !coxinput * jion8(11,i,1) c R78: CO + hv --> C+ + O + e- Lco(i,78) = jion8(11,i,2) Pcplus(i,78) = coxinput * jion8(11,i,2) Po3p(i,78) = Pcplus(i,78) !coxinput * jion8(11,i,2) Pelect(i,78) = Pcplus(i,78) !coxinput * jion8(11,i,2) c R79: CO + hv --> C + O+ + e- ! Lco(i,79) = jion8(11,i,3) ! Pc(i,79) = coxinput * jion8(11,i,3) ! Poplus(i,79) = Pc(i,79)!Pc(i,79)coxinput * jion8(11,i,3) ! Pelect(i,79) = Pc(i,79)!coxinput * jion8(11,i,3) c R80: NO + hv --> NO+ + e- Lno(i,80) = jion8(10,i,1) Pnoplus(i,80) = noxinput * jion8(10,i,1) Pelect(i,80) = Pnoplus(i,80) !noxinput * jion8(10,i,1) c R81: N2 + hv --> N2+ + e- Ln2(i,81) = jion8(8,i,1) Pn2plus(i,81) = n2xinput * jion8(8,i,1) Pelect(i,81) = Pn2plus(i,81) !n2xinput * jion8(8,i,1) c R82: N2 + hv --> N+ + N + e- Ln2(i,82) = jion8(8,i,2) Pnplus(i,82) = n2xinput * jion8(8,i,2) Pn(i,82) = Pnplus(i,82) !n2xinput * jion8(8,i,2) Pelect(i,82) = Pnplus(i,82) !n2xinput * jion8(8,i,2) c R83: H + hv --> H+ + e Lh(i,83) = jion8(12,i,1) Phplus(i,83) = hxinput * jion8(12,i,1) Pelect(i,83) = Phplus(i,83) !hxinput * jion8(12,i,1) c R84: N + hv --> N+ + e Ln(i,84) = jion8(9,i,1) Pnplus(i,84) = nxinput * jion8(9,i,1) Pelect(i,84) = Pnplus(i,84) !nxinput * jion8(9,i,1) c R85: N+ + CO2 --> CO2+ + N Pn(i,85) = ch85 * co2xinput * nplusxinput Pco2plus(i,85) = Pn(i,85) !ch85 * co2xinput * nplusxinput Lnplus(i,85) = ch85 * co2xinput Lco2(i,85) = ch85 * nplusxinput c R86: H2 + CO2+ --> H + HCO2+ Ph(i,86) = ch86 * co2plusxinput * h2xinput Lco2plus(i,86) = ch86 * h2xinput Lh2(i,86) = ch86 * co2plusxinput !!! c R87: HCO2+ + e --> H + CO2 Ph(i,87) = ch87 * hco2plusxinput * electxinput Pco2(i,87) = Ph(i,87) Lhco2plus(i,87) = ch87 * electxinput Lelect(i,87) = ch87 * hco2plusxinput c R88: N + e --> N+ + e + e Pnplus(i,88) = ionsec_nplus(zenit,zx(i))*Pnplus(i,84) Pelect(i,88) = Pnplus(i,88) if(nxinput.ge.1.d-20) then Ln(i,88) = Pnplus(i,88)/nxinput else Ln(i,88) = 1.d-30 endif c R89: N2 + e --> N2+ + e + e Pn2plus(i,89) = ionsec_n2plus(zenit,zx(i))*Pn2plus(i,81) Pelect(i,89) = Pn2plus(i,89) if(n2xinput.ge.1.d-20) then Ln2(i,89) = Pn2plus(i,89)/n2xinput else Ln2(i,89) = 1.d-30 endif c R90: O + e --> O+ + e + e Poplus(i,90) = ionsec_oplus(zenit,zx(i))*Poplus(i,61) Pelect(i,90) = Poplus(i,90) if(o3pxinput.ge.1.d-20) then Lo3p(i,90) = Poplus(i,90)/o3pxinput else Lo3p(i,90) = 1.d-30 endif c R91: CO + e --> CO+ + e + e Pcoplus(i,91) = ionsec_coplus(zenit,zx(i))*Pcoplus(i,77) Pelect(i,91) = Pcoplus(i,91) if(coxinput.ge.1.d-20) then Lco(i,91) = Pcoplus(i,91)/coxinput else Lco(i,91) = 1.d-30 endif c R92: CO2 + e --> CO2+ + e + e Pco2plus(i,92) = ionsec_co2plus(zenit,zx(i))* $ Pco2plus(i,51) Pelect(i,92) = Pco2plus(i,92) if(co2xinput.ge. 1.d-20) then Lco2(i,92) = Pco2plus(i,92)/co2xinput else Lco2(i,92) = 1.d-30 endif c R93: O2 + e --> O2+ + e Po2plus(i,93) = ionsec_o2plus(zenit,zx(i))*Po2plus(i,60) Pelect(i,93) = Po2plus(i,93) if(o2xinput.ge.1.d-20) then Lo2(i,93) = Po2plus(i,93)/o2xinput else Lo2(i,93) = 1.d-30 endif endif !Of chemthermod.eq.3 c Total production and loss for each species. To save CPU time, we c do not sum over all reactions, but only over those where the species c participates c CO2: c Prod: R4, R46, R47, R62, R87 c Loss: R1, R16, R38, R50, R51, R52, R53, R54, R57, R59, R68, R85, R92 Pco2tot(i) = Pco2(i,4) + Pco2(i,46) + Pco2(i,47) + Pco2(i,62) $ + Pco2(i,87) Lco2tot(i) = Lco2(i,1) + Lco2(i,16) + Lco2(i,38) + Lco2(i,50) + $ Lco2(i,51) + Lco2(i,52) + Lco2(i,53) + Lco2(i,54) + $ Lco2(i,56) + Lco2(i,57) + Lco2(i,59) + Lco2(i,68) + $ Lco2(i,85) + Lco2(i,92) c O2 c Prod: R3, R5, R7, R10, R11, R13, R22, R23, R24, R25, R26, R34, R41, R42, c R54, R64 c Loss: R2, R12, R17, R21, R32, R46, R60, R93 Po2tot(i) = Po2(i,3) + Po2(i,5) + Po2(i,7) + Po2(i,10) + $ Po2(i,11) + Po2(i,13) + Po2(i,22) + Po2(i,23) + Po2(i,24) + $ Po2(i,25) + Po2(i,26) + Po2(i,34) + Po2(i,41) + Po2(i,42) + $ Po2(i,54) + Po2(i,56) + Po2(i,64) Lo2tot(i) = Lo2(i,2) + Lo2(i,12) + Lo2(i,17) + Lo2(i,21) + $ Lo2(i,32) + Lo2(i,46) + Lo2(i,60) + Lo2(i,93) c O(3p) c Prod: R1, R12, R17, R19, R20, R25, R29, R30, R31, R32, R44, R49, R53, c R55, R66, R74, R75, R78 c Loss: R3, R10, R11, R21, R40, R41, R45, R47, R48, R58, R61, R69, R72, c R76, R90 Po3ptot(i) = Po3p(i,1) + Po3p(i,12) + Po3p(i,17) + Po3p(i,19) + $ Po3p(i,20) + Po3p(i,25) + Po3p(i,29) + Po3p(i,30) + $ Po3p(i,31) + Po3p(i,32) + Po3p(i,44) + Po3p(i,49) + $ Po3p(i,53) + Po3p(i,55) + Po3p(i,66) + Po3p(i,74) + $ Po3p(i,75) + Po3p(i,78) Lo3ptot(i) = Lo3p(i,3) + Lo3p(i,10) + Lo3p(i,11) + Lo3p(i,21) + $ Lo3p(i,40) + Lo3p(i,41) + Lo3p(i,45) + Lo3p(i,47) + $ Lo3p(i,48) + Lo3p(i,58) + Lo3p(i,61) + Lo3p(i,69) + $ Lo3p(i,72) + Lo3p(i,76) + Lo3p(i,90) c CO c Prod: R1, R16, R38, R48, R50, R52, R55, R57, R58, R59, R73 c Loss: R4, R70, R77, R78, R91 Pcotot(i) = Pco(i,1) + Pco(i,16) + Pco(i,38) + Pco(i,48) + $ Pco(i,50) + Pco(i,52) + Pco(i,55) + Pco(i,57) + Pco(i,58) + $ Pco(i,59) + Pco(i,73) Lcotot(i) = Lco(i,4) + Lco(i,70) + Lco(i,77) + Lco(i,78) + $ Lco(i,90) c H c Prod: R4, R8, R11, R14, R15, R27, R33, R76, R86, R87 c Loss: R2, R13, R22, R43, R73, R74, R83 Phtot(i) = Ph(i,4) + Ph(i,8) + Ph(i,11) + Ph(i,14) + Ph(i,15) + $ Ph(i,27) + Ph(i,33) + Ph(i,76) + Ph(i,86) + Ph(i,87) Lhtot(i) = Lh(i,2) + Lh(i,13) + Lh(i,22) + Lh(i,43) + Lh(i,73) + $ Lh(i,74) + Lh(i,83) c OH c Prod: R3, R6, R8, R9, R14, R22, R24, R35, R39, R43 c Loss: R4, R7, R11, R15, R18, R23, R33 Pohtot(i) = Poh(i,3) + Poh(i,6) + Poh(i,8) + Poh(i,9) + $ Poh(i,14) + Poh(i,22) + Poh(i,24) + Poh(i,35) + Poh(i,39) + $ Poh(i,43) Lohtot(i) = Loh(i,4) + Loh(i,7) + Loh(i,11) + Loh(i,15) + $ Loh(i,18) + Loh(i,23) + Loh(i,33) c HO2 c Prod: R2, R18, R23 c Loss: R3, R5, R7, R13, R24, R35, R39 Pho2tot(i) = Pho2(i,2) + Pho2(i,18) + Pho2(i,23) Lho2tot(i) = Lho2(i,3) + Lho2(i,5) + Lho2(i,7) + Lho2(i,13) + $ Lho2(i,24) + Lho2(i,35) + Lho2(i,39) c H2 c Prod: R13 c Loss: R14, R15, R27, R86 Ph2tot(i) = Ph2(i,13) Lh2tot(i) = Lh2(i,14) + Lh2(i,15) + Lh2(i,27) + Lh2(i,86) c H2O c Prod: R7, R15, R18 c Loss: R8, R9 Ph2otot(i) = Ph2o(i,7) + Ph2o(i,15) + Ph2o(i,18) Lh2otot(i) = Lh2o(i,8) + Lh2o(i,9) c O(1d) c Prod: R16, R17, R26 c Loss: R9, R14, R19, R20, R31 Po1dtot(i) = Po1d(i,16) + Po1d(i,17) + Po1d(i,26) Lo1dtot(i) = Lo1d(i,9) + Lo1d(i,14) + Lo1d(i,19) + Lo1d(i,20) + $ Lo1d(i,31) c H2O2 c Prod: R5 c Loss: R6, R18 Ph2o2tot(i) = Ph2o2(i,5) Lh2o2tot(i) = Lh2o2(i,6) + Lh2o2(i,18) !Only if O3, N or ion chemistry requested if(chemthermod.ge.1) then c O3 c Prod: R21 c Loss: R22, R23, R24, R25, R26, R34, R42 Po3tot(i) = Po3(i,21) Lo3tot(i) = Lo3(i,22) + Lo3(i,23) + Lo3(i,24) + Lo3(i,25) + $ Lo3(i,26) + Lo3(i,34) + Lo3(i,42) endif !Only if N or ion chemistry requested if(chemthermod.ge.2) then c N c Prod: R28, R29, R36, R37, R67, R69, R71, R75, R82, R85 c Loss: R30, R32, R33, R34, R35, R45, R63, R66, R84, R88 Pntot(i) = Pn(i,28) + Pn(i,29) + Pn(i,36) + Pn(i,37) +Pn(i,67)+ $ Pn(i,69) + Pn(i,71) + Pn(i,75) + Pn(i,82) + Pn(i,85) Lntot(i) = Ln(i,30) + Ln(i,32) + Ln(i,33) + Ln(i,34) +Ln(i,35)+ $ Ln(i,45) + Ln(i,63) + Ln(i,66) + Ln(i,84) + Ln(i,88) c NO c Prod: R32, R33, R34, R35, R38, R41, R43, R44, R45, R63, R65 c Loss: R29, R30, R39, R40, R42, R62, R64, R80 Pnotot(i) = Pno(i,32) + Pno(i,33) + Pno(i,34) + Pno(i,35) + $ Pno(i,38) + Pno(i,41) + Pno(i,43) + Pno(i,44) + Pno(i,45)+ $ Pno(i,63) + Pno(i,65) Lnotot(i) = Lno(i,29) + Lno(i,30) + Lno(i,39) + Lno(i,40) + $ Lno(i,42) + Lno(i,62) + Lno(i,64) + Lno(i,80) c N2 c Prod: R30, R68, R70, R72 c Loss: R28, R65, R67, R81, R82, R89 Pn2tot(i) = Pn2(i,30) + Pn2(i,68) + Pn2(i,70) + Pn2(i,72) Ln2tot(i) = Ln2(i,28) + Ln2(i,65) + Ln2(i,67) + Ln2(i,81) + $ Ln2(i,82) + Ln2(i,89) c N(2d) c Prod: R28 c Loss: R36, R37, R38 Pn2dtot(i) = Pn2d(i,28) Ln2dtot(i) = Ln2d(i,36) + Ln2d(i,37) + Ln2d(i,38) c NO2 c Prod: R39, R40, R42 c Loss: R41, R43, R44 Pno2tot(i) = Pno2(i,39) + Pno2(i,40) + Pno2(i,42) Lno2tot(i) = Lno2(i,41) + Lno2(i,43) + Lno2(i,44) endif !Of chemthermod.ge.2 ! !Only if ion chemistry requested if(chemthermod.eq.3) then c CO2+ c Prod: R51,R57, R68, R85, R92 c Loss: R46, R47, R48, R55, R62, R63, R86 Pco2plustot(i) = Pco2plus(i,51) + Pco2plus(i,57) + $ Pco2plus(i,68) + Pco2plus(i,85) + Pco2plus(i,92) Lco2plustot(i) = Lco2plus(i,46) + Lco2plus(i,47) + $ Lco2plus(i,48) + Lco2plus(i,55) + Lco2plus(i,62) + $ Lco2plus(i,63) + Lco2plus(i,86) c O+ c Prod: R47, R52, R58, R61, R72, R76, R90 c Loss: 50,67,74 Poplustot(i) = Poplus(i,47) + Poplus(i,52) + Poplus(i,58) + $ Poplus(i,61) + Poplus(i,72) + Poplus(i,76) + Poplus(i,90) Loplustot(i) = Loplus(i,50) + Loplus(i,56) + Loplus(i,67) + $ Loplus(i,74) c O2+ c Prod: R46, R48, R50, R60, R93 c Loss: R49, R64, R65, R66 Po2plustot(i) = Po2plus(i,46) + Po2plus(i,48) + Po2plus(i,50) + $ Po2plus(i,60) + Po2plus(i,93) Lo2plustot(i) = Lo2plus(i,49) + Lo2plus(i,64) + Lo2plus(i,65) + $ Lo2plus(i,66) c CO+ c Prod: R53, R59, R63, R70, R77, R91 c Loss: R57, R58, R73 Pcoplustot(i) = Pcoplus(i,53) + Pcoplus(i,56) + Pcoplus(i,59) + $ Pcoplus(i,63) + Pcoplus(i,70) + Pcoplus(i,77) + $ Pcoplus(i,91) Lcoplustot(i) = Lcoplus(i,57) + Lcoplus(i,58) + Lcoplus(i,73) c C+ c Prod: R54, R78 c Loss: R59 Pcplustot(i) = Pcplus(i,54) + Pcplus(i,78) Lcplustot(i) = Lcplus(i,59) c N+ c Prod: R82, R84, R88 c Loss: R85 Pnplustot(i) = Pnplus(i,82) + Pnplus(i,84) + Pnplus(i,88) Lnplustot(i) = Lnplus(i,85) c N2+ c Prod: R81, R89 c Loss: R68, R69, R70, R71, R72 Pn2plustot(i) = Pn2plus(i,81) + Pn2plus(i,89) Ln2plustot(i) = Ln2plus(i,68) + Ln2plus(i,69) + Ln2plus(i,70) + $ Ln2plus(i,71) + Ln2plus(i,72) c NO+ c Prod: R62, R64, R65, R66, R67, R69, R80 c Loss: R75 Pnoplustot(i) = Pnoplus(i,62) + Pnoplus(i,64) + Pnoplus(i,65) + $ Pnoplus(i,66) + Pnoplus(i,67) + Pnoplus(i,69) + $ Pnoplus(i,80) Lnoplustot(i) = Lnoplus(i,75) c H+ c Prod: R73, R74, R83 c Loss: R76 Phplustot(i) = Phplus(i,73) + Phplus(i,74) + Phplus(i,83) Lhplustot(i) = Lhplus(i,76) c HCO2+ c Prod: R86 c Loss: R87 Phco2plustot(i) = Phco2plus(i,86) Lhco2plustot(i) = Lhco2plus(i,87) c e- c Prod: R51, R52, R53, R54, R60, R61, R77, R78, R80, R81, R82, R83, R84, c R88, R89, R90, R91, R92, R93 c Loss: R49, R55, R71, R75, R87 Pelecttot(i) = Pelect(i,51) + Pelect(i,52) + Pelect(i,53) + $ Pelect(i,54) + Pelect(i,60) + Pelect(i,61) + Pelect(i,77)+ $ Pelect(i,78) + Pelect(i,80) + Pelect(i,81) + Pelect(i,82)+ $ Pelect(i,83) + Pelect(i,84) + Pelect(i,88) + Pelect(i,89)+ $ Pelect(i,90) + Pelect(i,91) + Pelect(i,92) + Pelect(i,93) Lelecttot(i) = Lelect(i,49) + Lelect(i,55) + Lelect(i,71) + $ Lelect(i,75) + Lelect(i,87) endif !Of chemthermod.eq.3 return c END end c********************************************************************** c********************************************************************** subroutine EF_oscilacion & (ig,i,nlayer,paso,chemthermod,zenit, zx, & jdistot8, jdistot8_b,jion8, & tminaux, & co2xoutput, co2xinput, $ o2xoutput, o2xinput, $ o3pxoutput, o3pxinput, $ coxoutput, coxinput, $ h2xoutput, h2xinput, $ h2oxoutput, h2oxinput, $ h2o2xoutput, h2o2xinput, $ o3xoutput, o3xinput, $ nxoutput, nxinput, $ noxoutput, noxinput, $ n2xoutput, n2xinput, & o1dxoutput, o1dxinput, & ohxoutput, ohxinput, & ho2xoutput, ho2xinput, & hxoutput, hxinput, & n2dxoutput, n2dxinput, & no2xoutput, no2xinput, & co2plusxoutput, co2plusxinput, & o2plusxoutput, o2plusxinput, & coplusxoutput, coplusxinput, & oplusxoutput, oplusxinput, & cplusxoutput, cplusxinput, & noplusxoutput, noplusxinput, & n2plusxoutput, n2plusxinput, & hplusxoutput, hplusxinput, & nplusxoutput, nplusxinput, $ hco2plusxoutput,hco2plusxinput, & electxoutput, electxinput, & electxoutput_timemarching ) c Calculates the concentrations of the fast species in PE c c 2009 FGG Adaptation to GCM c jul 2008 MA Version en subrutina c nov 2007 MA Original. Evita oscilacion en EF c********************************************************************** use iono_h use param_v4_h, only: nabs, . ch2, ch3, ch4, ch5, ch7,ch9,ch10,ch11,ch13,ch14,ch15,ch18, . ch19,ch20,ch21,ch22,ch23,ch24,ch30,ch31,ch32,ch33,ch34, . ch35,ch36,ch37,ch38,ch39,ch40,ch41,ch42,ch43,ch45, . ch46,ch47,ch48,ch49,ch50,ch55,ch56,ch57,ch58,ch59,ch62, . ch63,ch64,ch65,ch66,ch67,ch68,ch69,ch70,ch71, . ch72,ch73,ch74,ch75,ch76,ch85,ch86,ch87 implicit none c arguments integer ig,nlayer integer i ! I. Layer integer paso ! I. paso temporal del timemarching, 1,numpasos integer chemthermod real*8 tminaux ! I. real zx(nlayer) real zenit real*8 jdistot8(nabs,nlayer) ! I. real*8 jdistot8_b(nabs,nlayer) ! I. real*8 jion8(nabs,nlayer,4) real*8 co2xoutput,o2xoutput,o3pxoutput,coxoutput,h2xoutput real*8 h2o2xoutput,o3xoutput,h2oxoutput real*8 nxoutput,noxoutput,n2xoutput real*8 ho2xoutput, hxoutput, ohxoutput ! O. real*8 o1dxoutput, n2dxoutput, no2xoutput ! O. real*8 co2xinput,o2xinput,o3pxinput,coxinput,h2xinput real*8 h2o2xinput,o3xinput,h2oxinput real*8 nxinput,noxinput,n2xinput real*8 ho2xinput, hxinput, ohxinput ! I. real*8 o1dxinput, n2dxinput, no2xinput ! I. real*8 co2plusxoutput, coplusxoutput, oplusxoutput ! O. real*8 o2plusxoutput, cplusxoutput, noplusxoutput ! O. real*8 n2plusxoutput, hplusxoutput ! O. real*8 electxoutput, nplusxoutput, hco2plusxoutput ! O. real*8 co2plusxinput, coplusxinput, oplusxinput ! I. real*8 o2plusxinput, cplusxinput, noplusxinput ! I. real*8 n2plusxinput, hplusxinput ! I. real*8 electxinput, nplusxinput, hco2plusxinput ! I. real*8 electxoutput_timemarching ! I. c local variables integer npasitos parameter (npasitos=20) real*8 electxoutput_neutr real*8 ho2xoutput2, hxoutput2, ohxoutput2 real*8 o1dxoutput2, n2dxoutput2, no2xoutput2 real*8 co2plusxoutput2, coplusxoutput2, oplusxoutput2 real*8 o2plusxoutput2, hplusxoutput2, nplusxoutput2 real*8 cplusxoutput2, noplusxoutput2, n2plusxoutput2 real*8 hco2plusxoutput2 !real*8 electxoutput2 integer correc_oscil, ip real*8 avg_pares, avg_impar, dispersion real*8 dif_impar, dif_pares , dif_pares_impar real*8 ho2xpares(3), hxpares(3), ohxpares(3) real*8 o1dxpares(3), n2dxpares(3), no2xpares(3) real*8 co2plusxpares(3), coplusxpares(3), oplusxpares(3) real*8 o2plusxpares(3), hplusxpares(3), nplusxpares(3) real*8 cplusxpares(3), noplusxpares(3), n2plusxpares(3) real*8 hco2plusxpares(3) real*8 ho2ximpar(3), hximpar(3), ohximpar(3) real*8 o1dximpar(3), n2dximpar(3), no2ximpar(3) real*8 co2plusximpar(3), coplusximpar(3), oplusximpar(3) real*8 o2plusximpar(3), hplusximpar(3), nplusximpar(3) real*8 cplusximpar(3), noplusximpar(3), n2plusximpar(3) real*8 hco2plusximpar(3) real*8 auxp,auxl,ca, cb,cc, cd1,cd2,ce real*8 IonMostAbundant real*8 cocimin parameter (cocimin=1.d-30) integer cociopt parameter (cociopt=1) c external functions c external cociente real*8 cociente external ionsec_nplus real*8 ionsec_nplus external ionsec_n2plus real*8 ionsec_n2plus external ionsec_oplus real*8 ionsec_oplus external ionsec_coplus real*8 ionsec_coplus external ionsec_co2plus real*8 ionsec_co2plus external ionsec_o2plus real*8 ionsec_o2plus external avg real*8 avg external dif real*8 dif real*8 log1 real*8 log2 real*8 log3 ccccccccccccccc CODE STARTS !!! Starts iteration to avoid oscilations correc_oscil=0 do ip = 1, npasitos if (ip.eq.1) then if (o1d_eq(i).eq.'Y') o1dxoutput = o1dxinput if (oh_eq(i).eq.'Y') ohxoutput = ohxinput if (ho2_eq(i).eq.'Y') ho2xoutput = ho2xinput if (h_eq(i).eq.'Y') hxoutput = hxinput !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dxoutput = n2dxinput if (no2_eq(i).eq.'Y') no2xoutput = no2xinput endif ! !Only if ion chemistry requested if(chemthermod.ge.3) then if (n2plus_eq(i).eq.'Y') n2plusxoutput=n2plusxinput if (cplus_eq(i).eq.'Y') cplusxoutput=cplusxinput if (coplus_eq(i).eq.'Y') coplusxoutput=coplusxinput if (oplus_eq(i).eq.'Y') oplusxoutput=oplusxinput if (hplus_eq(i).eq.'Y') hplusxoutput=hplusxinput if (co2plus_eq(i).eq.'Y') co2plusxoutput=co2plusxinput if (noplus_eq(i).eq.'Y') noplusxoutput=noplusxinput if (o2plus_eq(i).eq.'Y') o2plusxoutput=o2plusxinput if (nplus_eq(i).eq.'Y') nplusxoutput=nplusxinput if (hco2plus_eq(i).eq.'Y') hco2plusxoutput=hco2plusxinput electxoutput = electxinput endif endif ! 6 neutral , O1D, OH, HO2, H, N2D, NO2 !O1D if (o1d_eq(i).eq.'Y') then auxp = jdistot8_b(1,i) * co2xoutput & + jdistot8_b(2,i) * o2xoutput & + jdistot8_b(7,i) * o3xoutput auxl = ch9 * h2oxoutput & + ch14 * h2xoutput & + ch19 * co2xoutput & + ch20 * o2xoutput & + ch31 * n2xoutput o1dxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if !OH if (oh_eq(i).eq.'Y') then auxp = ch3 * o3pxoutput * ho2xoutput & + 2.d0 * jdistot8(6,i) * h2o2xoutput & + jdistot8(4,i) * h2oxoutput & + 2.d0 * ch9 * o1dxoutput * h2oxoutput & + ch14 * o1dxoutput * h2xoutput & + ch22 * o3xoutput * hxoutput & + ch24 * o3xoutput * ho2xoutput & + ch35 * nxoutput * ho2xoutput & + ch39 * noxoutput * ho2xoutput & + ch43 * no2xoutput * hxoutput auxl = ch4 * coxoutput & + ch7 * ho2xoutput & + ch11 * o3pxoutput & + ch15 * h2xoutput & + ch18 * h2o2xoutput & + ch23 * o3xoutput & + ch33 * nxoutput ohxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if !HO2 if (ho2_eq(i).eq.'Y') then auxp = ch2 * hxoutput * o2xoutput * co2xoutput & + ch18 * ohxoutput * h2o2xoutput & + ch23 * ohxoutput * o3xoutput auxl = ch3 * o3pxoutput & + 2.d0 * ch5 * ho2xoutput & + ch7 * ohxoutput & + ch13 * hxoutput & + ch24 * o3xoutput & + ch35 * nxoutput & + ch39 * noxoutput ho2xoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if !H if (h_eq(i).eq.'Y') then auxp = ch4 * coxoutput * ohxoutput & + jdistot8(4,i) * h2oxoutput & + ch11 * o3pxoutput * ohxoutput & + ch14 * o1dxoutput * h2xoutput & + ch15 * ohxoutput * h2xoutput & + 2.d0 * jdistot8(5,i) * h2xoutput & + ch33 * nxoutput * ohxoutput & + ch76 * hplusxoutput * o3pxoutput & + hxoutput * jion8(12,i,1) $ + ch86 * h2xoutput * co2plusxoutput $ + ch87 * hco2plusxoutput * electxoutput auxl = ch2 * o2xoutput * co2xoutput & + ch13 * ho2xoutput & + ch22 * o3xoutput & + ch43 * no2xoutput & + ch73 * coplusxoutput & + ch74 * oplusxoutput & + jion8(12,i,1) hxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if !Only if N or ion chemistry requested if(chemthermod.ge.2) then !N2D if (n2d_eq(i).eq.'Y') then auxp = jdistot8(8,i) * n2xoutput auxl = ch36 * o3pxoutput & + ch37 * n2xoutput & + ch38 * co2xoutput n2dxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if !NO2 if (no2_eq(i).eq.'Y') then auxp = ch39 * noxoutput * ho2xoutput & + ch40 * o3pxoutput * noxoutput * co2xoutput & + ch42 * noxoutput * o3xoutput auxl = ch41 * o3pxoutput & + ch43 * hxoutput & + jdistot8(13,i) no2xoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if endif !Of chemthermod.ge.2 ! 9 ions !Only if ion chemistry requested if(chemthermod.eq.3) then ! N2+ if (n2plus_eq(i).eq.'Y') then auxp = jion8(8,i,1)*n2xoutput* $ (1.d0+ionsec_n2plus(zenit,zx(i))) auxl = ch68*co2xoutput & + ch69*o3pxoutput & + ch70*coxoutput $ + ch71*electxoutput & + ch72*o3pxoutput n2plusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) endif ! C+ if (cplus_eq(i).eq.'Y') then auxp = jion8(1,i,4)*co2xoutput & + jion8(11,i,2)*coxoutput auxl = ch59*co2xoutput cplusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if ! CO+ if (coplus_eq(i).eq.'Y') then auxp = jion8(1,i,3)*co2xoutput $ + ch59*cplusxoutput *co2xoutput $ + ch63*co2plusxoutput*nxoutput $ + ch70*n2plusxoutput*coxoutput $ + jion8(11,i,1)*coxoutput* $ (1.d0+ionsec_coplus(zenit,zx(i))) auxl = ch57*co2xoutput & + ch58*o3pxoutput & + ch73*hxoutput coplusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if ! CO2+ if (co2plus_eq(i).eq.'Y') then auxp = jion8(1,i,1)*co2xoutput* $ (1.d0+ionsec_co2plus(zenit,zx(i))) & + ch57*coplusxoutput*co2xoutput $ + ch68*n2plusxoutput*co2xoutput & + ch85*nplusxoutput*co2xoutput auxl = ch46*o2xoutput & + ch47*o3pxoutput & + ch55*electxoutput $ + ch62*noxoutput & + ch63*nxoutput & + ch48*o3pxoutput $ + ch86*h2xoutput co2plusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if ! ! [O+] [H+] are linked: 2 equations with 2 unknowns ! ! [H+] = (ca + cb [O+])/cd1 ! [O+] = (cc + ce [H+])/cd2 ! ca = ch73 * coplusxoutput * hxoutput & + jion8(12,i,1)*hxoutput cb = ch74 * hxoutput cd1 = ch76 * o3pxoutput cc = ch47*co2plusxoutput*o3pxoutput & + jion8(1,i,2)*co2xoutput $ + jion8(3,i,1)*o3pxoutput* $ (1.d0+ionsec_oplus(zenit,zx(i))) & + ch58*coplusxoutput*o3pxoutput $ + ch72*n2plusxoutput*o3pxoutput ce = ch76 * o3pxoutput cd2 = ch50*co2xoutput + ch67*n2xoutput + ch74*hxoutput ! O+ if (oplus_eq(i).eq.'Y') then auxp = cc*cd1 + ce*ca auxl = cd1*cd2 -ce*cb oplusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) end if ! H+ if (hplus_eq(i).eq.'Y') then auxp = ca + cb * oplusxoutput auxl = cd1 hplusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) endif ! O2+ if (o2plus_eq(i).eq.'Y') then auxp = ch46*co2plusxoutput*o2xoutput $ + ch48*co2plusxoutput*o3pxoutput $ + ch50*oplusxoutput*co2xoutput $ + jion8(2,i,1)*o2xoutput* $ (1.d0+ionsec_o2plus(zenit,zx(i))) auxl = ch49*electxoutput + ch64*noxoutput $ + ch65*n2xoutput + ch66*nxoutput o2plusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) endif ! NO+ if(noplus_eq(i).eq.'Y') then auxp = ch62*coplusxoutput*noxoutput $ + ch64*o2plusxoutput*noxoutput $ + ch65*o2plusxoutput*n2xoutput $ + ch66*o2plusxoutput*nxoutput $ + ch67*oplusxoutput*n2xoutput $ + ch69*n2plusxoutput*o3pxoutput $ + jion8(10,i,1)*noxoutput auxl = ch75*electxoutput noplusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) endif ! N+ if(nplus_eq(i).eq.'Y') then auxp = jion8(8,i,2)*n2xoutput & + jion8(9,i,1)*nxoutput* $ (1.d0+ionsec_nplus(zenit,zx(i))) auxl = ch85*co2xoutput nplusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) endif ! HCO2+ if(hco2plus_eq(i).eq.'Y') then auxp = ch86*h2xoutput*co2plusxoutput auxl = ch87*electxoutput hco2plusxoutput2 = cociente(auxp,auxl,cocimin,cociopt) endif endif !Of chemthermod.eq.3 ! Detection of oscilations and elimination if (ip.eq.4 .or. ip.eq.14) then ! ***pares(1) if (o1d_eq(i).eq.'Y') o1dxpares(1)=o1dxoutput2 if (oh_eq(i).eq.'Y') ohxpares(1)=ohxoutput2 if (ho2_eq(i).eq.'Y') ho2xpares(1)=ho2xoutput2 if (h_eq(i).eq.'Y') hxpares(1)=hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dxpares(1)=n2dxoutput2 if (no2_eq(i).eq.'Y') no2xpares(1)=no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusxpares(1)=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusxpares(1)=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusxpares(1)=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusxpares(1)=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusxpares(1)=hplusxoutput2 if (co2plus_eq(i).eq.'Y')co2plusxpares(1)=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusxpares(1)=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusxpares(1)=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusxpares(1)=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') $ hco2plusxpares(1)=hco2plusxoutput2 endif elseif (ip.eq.6 .or. ip.eq.16) then ! ***pares(2) if (o1d_eq(i).eq.'Y') o1dxpares(2)=o1dxoutput2 if (oh_eq(i).eq.'Y') ohxpares(2)=ohxoutput2 if (ho2_eq(i).eq.'Y') ho2xpares(2)=ho2xoutput2 if (h_eq(i).eq.'Y') hxpares(2)=hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dxpares(2)=n2dxoutput2 if (no2_eq(i).eq.'Y') no2xpares(2)=no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusxpares(2)=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusxpares(2)=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusxpares(2)=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusxpares(2)=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusxpares(2)=hplusxoutput2 if (co2plus_eq(i).eq.'Y')co2plusxpares(2)=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusxpares(2)=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusxpares(2)=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusxpares(2)=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') $ hco2plusxpares(2)=hco2plusxoutput2 endif elseif (ip.eq.8 .or. ip.eq.18) then ! ***pares(3) if (o1d_eq(i).eq.'Y') o1dxpares(3)=o1dxoutput2 if (oh_eq(i).eq.'Y') ohxpares(3)=ohxoutput2 if (ho2_eq(i).eq.'Y') ho2xpares(3)=ho2xoutput2 if (h_eq(i).eq.'Y') hxpares(3)=hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dxpares(3)=n2dxoutput2 if (no2_eq(i).eq.'Y') no2xpares(3)=no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusxpares(3)=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusxpares(3)=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusxpares(3)=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusxpares(3)=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusxpares(3)=hplusxoutput2 if (co2plus_eq(i).eq.'Y')co2plusxpares(3)=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusxpares(3)=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusxpares(3)=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusxpares(3)=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') $ hco2plusxpares(3)=hco2plusxoutput2 endif elseif (ip.eq.5 .or. ip.eq.15) then ! ***impar(1) if (o1d_eq(i).eq.'Y') o1dximpar(1)=o1dxoutput2 if (oh_eq(i).eq.'Y') ohximpar(1)=ohxoutput2 if (ho2_eq(i).eq.'Y') ho2ximpar(1)=ho2xoutput2 if (h_eq(i).eq.'Y') hximpar(1)=hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dximpar(1)=n2dxoutput2 if (no2_eq(i).eq.'Y') no2ximpar(1)=no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusximpar(1)=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusximpar(1)=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusximpar(1)=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusximpar(1)=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusximpar(1)=hplusxoutput2 if (co2plus_eq(i).eq.'Y')co2plusximpar(1)=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusximpar(1)=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusximpar(1)=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusximpar(1)=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') $ hco2plusximpar(1)=hco2plusxoutput2 endif elseif (ip.eq.7 .or. ip.eq.17) then ! ***impar(2) if (o1d_eq(i).eq.'Y') o1dximpar(2)=o1dxoutput2 if (oh_eq(i).eq.'Y') ohximpar(2)=ohxoutput2 if (ho2_eq(i).eq.'Y') ho2ximpar(2)=ho2xoutput2 if (h_eq(i).eq.'Y') hximpar(2)=hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dximpar(2)=n2dxoutput2 if (no2_eq(i).eq.'Y') no2ximpar(2)=no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusximpar(2)=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusximpar(2)=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusximpar(2)=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusximpar(2)=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusximpar(2)=hplusxoutput2 if (co2plus_eq(i).eq.'Y')co2plusximpar(2)=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusximpar(2)=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusximpar(2)=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusximpar(2)=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') $ hco2plusximpar(2)=hco2plusxoutput2 endif elseif (ip.eq.9 .or. ip.eq.19) then ! ***impar(3) if (o1d_eq(i).eq.'Y') o1dximpar(3)=o1dxoutput2 if (oh_eq(i).eq.'Y') ohximpar(3)=ohxoutput2 if (ho2_eq(i).eq.'Y') ho2ximpar(3)=ho2xoutput2 if (h_eq(i).eq.'Y') hximpar(3)=hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dximpar(3)=n2dxoutput2 if (no2_eq(i).eq.'Y') no2ximpar(3)=no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusximpar(3)=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusximpar(3)=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusximpar(3)=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusximpar(3)=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusximpar(3)=hplusxoutput2 if (co2plus_eq(i).eq.'Y')co2plusximpar(3)=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusximpar(3)=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusximpar(3)=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusximpar(3)=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') $ hco2plusximpar(3)=hco2plusxoutput2 endif if (o1d_eq(i).eq.'Y') then log1 = dlog10(o1dxpares(1)) log2 = dlog10(o1dxpares(2)) log3 = dlog10(o1dxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(o1dximpar(1)) log2 = dlog10(o1dximpar(2)) log3 = dlog10(o1dximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.d0*dispersion) then correc_oscil=correc_oscil+1 o1dxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (oh_eq(i).eq.'Y') then log1 = dlog10(ohxpares(1)) log2 = dlog10(ohxpares(2)) log3 = dlog10(ohxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(ohximpar(1)) log2 = dlog10(ohximpar(2)) log3 = dlog10(ohximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 ohxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (ho2_eq(i).eq.'Y') then log1 = dlog10(ho2xpares(1)) log2 = dlog10(ho2xpares(2)) log3 = dlog10(ho2xpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(ho2ximpar(1)) log2 = dlog10(ho2ximpar(2)) log3 = dlog10(ho2ximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 ho2xoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (h_eq(i).eq.'Y') then log1 = dlog10(hxpares(1)) log2 = dlog10(hxpares(2)) log3 = dlog10(hxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(hximpar(1)) log2 = dlog10(hximpar(2)) log3 = dlog10(hximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 hxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') then log1 = dlog10(n2dxpares(1)) log2 = dlog10(n2dxpares(2)) log3 = dlog10(n2dxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(n2dximpar(1)) log2 = dlog10(n2dximpar(2)) log3 = dlog10(n2dximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 n2dxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (no2_eq(i).eq.'Y') then log1 = dlog10(no2xpares(1)) log2 = dlog10(no2xpares(2)) log3 = dlog10(no2xpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(no2ximpar(1)) log2 = dlog10(no2ximpar(2)) log3 = dlog10(no2ximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 no2xoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif endif !Of chemthermod.ge.2 ! IONS !Only if ion chemistry requested if(chemthermod.eq.3) then if (cplus_eq(i).eq.'Y') then log1 = dlog10(cplusxpares(1)) log2 = dlog10(cplusxpares(2)) log3 = dlog10(cplusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(cplusximpar(1)) log2 = dlog10(cplusximpar(2)) log3 = dlog10(cplusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 cplusxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (coplus_eq(i).eq.'Y') then log1 = dlog10(coplusxpares(1)) log2 = dlog10(coplusxpares(2)) log3 = dlog10(coplusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(coplusximpar(1)) log2 = dlog10(coplusximpar(2)) log3 = dlog10(coplusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 coplusxoutput2=10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (oplus_eq(i).eq.'Y') then log1 = dlog10(oplusxpares(1)) log2 = dlog10(oplusxpares(2)) log3 = dlog10(oplusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(oplusximpar(1)) log2 = dlog10(oplusximpar(2)) log3 = dlog10(oplusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 oplusxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (n2plus_eq(i).eq.'Y') then log1 = dlog10(n2plusxpares(1)) log2 = dlog10(n2plusxpares(2)) log3 = dlog10(n2plusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(n2plusximpar(1)) log2 = dlog10(n2plusximpar(2)) log3 = dlog10(n2plusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 n2plusxoutput2 =10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (hplus_eq(i).eq.'Y') then log1 = dlog10(hplusxpares(1)) log2 = dlog10(hplusxpares(2)) log3 = dlog10(hplusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(hplusximpar(1)) log2 = dlog10(hplusximpar(2)) log3 = dlog10(hplusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 hplusxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (co2plus_eq(i).eq.'Y') then log1 = dlog10(co2plusxpares(1)) log2 = dlog10(co2plusxpares(2)) log3 = dlog10(co2plusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(co2plusximpar(1)) log2 = dlog10(co2plusximpar(2)) log3 = dlog10(co2plusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 co2plusxoutput2=10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (o2plus_eq(i).eq.'Y') then log1 = dlog10(o2plusxpares(1)) log2 = dlog10(o2plusxpares(2)) log3 = dlog10(o2plusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(o2plusximpar(1)) log2 = dlog10(o2plusximpar(2)) log3 = dlog10(o2plusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 o2plusxoutput2 =10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (noplus_eq(i).eq.'Y') then log1 = dlog10(noplusxpares(1)) log2 = dlog10(noplusxpares(2)) log3 = dlog10(noplusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(noplusximpar(1)) log2 = dlog10(noplusximpar(2)) log3 = dlog10(noplusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 noplusxoutput2 =10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (nplus_eq(i).eq.'Y') then log1 = dlog10(nplusxpares(1)) log2 = dlog10(nplusxpares(2)) log3 = dlog10(nplusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(nplusximpar(1)) log2 = dlog10(nplusximpar(2)) log3 = dlog10(nplusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 nplusxoutput2 = 10.d0**(0.5*(avg_pares+avg_impar)) endif endif if (hco2plus_eq(i).eq.'Y') then log1 = dlog10(hco2plusxpares(1)) log2 = dlog10(hco2plusxpares(2)) log3 = dlog10(hco2plusxpares(3)) avg_pares = avg(log1,log2,log3) dif_pares = dif(log1,log2,log3,avg_pares) log1 = dlog10(hco2plusximpar(1)) log2 = dlog10(hco2plusximpar(2)) log3 = dlog10(hco2plusximpar(3)) avg_impar = avg(log1,log2,log3) dif_impar = dif(log1,log2,log3,avg_impar) dispersion = dif_pares + dif_impar dif_pares_impar = abs(avg_pares-avg_impar) if (dif_pares_impar .gt. 5.*dispersion) then correc_oscil=correc_oscil+1 hco2plusxoutput2=10.d0**(0.5*(avg_pares+avg_impar)) endif endif endif !Of chemthermod.eq.3 endif ! Preparation of next step if (o1d_eq(i).eq.'Y') o1dxoutput = o1dxoutput2 if (oh_eq(i).eq.'Y') ohxoutput = ohxoutput2 if (ho2_eq(i).eq.'Y') ho2xoutput = ho2xoutput2 if (h_eq(i).eq.'Y') hxoutput = hxoutput2 !Only if N or ion chemistry requested if(chemthermod.ge.2) then if (n2d_eq(i).eq.'Y') n2dxoutput = n2dxoutput2 if (no2_eq(i).eq.'Y') no2xoutput = no2xoutput2 endif ! !Only if ion chemistry requested if(chemthermod.eq.3) then if (n2plus_eq(i).eq.'Y') n2plusxoutput=n2plusxoutput2 if (cplus_eq(i).eq.'Y') cplusxoutput=cplusxoutput2 if (coplus_eq(i).eq.'Y') coplusxoutput=coplusxoutput2 if (oplus_eq(i).eq.'Y') oplusxoutput=oplusxoutput2 if (hplus_eq(i).eq.'Y') hplusxoutput=hplusxoutput2 if (co2plus_eq(i).eq.'Y') co2plusxoutput=co2plusxoutput2 if (noplus_eq(i).eq.'Y') noplusxoutput=noplusxoutput2 if (o2plus_eq(i).eq.'Y') o2plusxoutput=o2plusxoutput2 if (nplus_eq(i).eq.'Y') nplusxoutput=nplusxoutput2 if (hco2plus_eq(i).eq.'Y') hco2plusxoutput=hco2plusxoutput2 electxoutput = o2plusxoutput + @ co2plusxoutput + @ coplusxoutput + @ oplusxoutput + @ cplusxoutput + @ n2plusxoutput + @ nplusxoutput + @ noplusxoutput + @ hplusxoutput + $ hco2plusxoutput electxoutput_neutr = electxoutput IonMostAbundant = o2plusxoutput IonMostAbundant = max( co2plusxoutput, IonMostAbundant) IonMostAbundant = max( coplusxoutput, IonMostAbundant) IonMostAbundant = max( oplusxoutput, IonMostAbundant) IonMostAbundant = max( cplusxoutput, IonMostAbundant) IonMostAbundant = max( n2plusxoutput, IonMostAbundant) IonMostAbundant = max( noplusxoutput, IonMostAbundant) IonMostAbundant = max( nplusxoutput, IonMostAbundant) IonMostAbundant = max( hplusxoutput, IonMostAbundant) IonMostAbundant = max( hco2plusxoutput, IonMostAbundant) IonMostAbundant = IonMostAbundant / electxoutput endif !Of chemthermod.eq.3 enddo !!! End of iteration return end !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! function avg(log1,log2,log3) implicit none real*8 avg real*8 log1,log2,log3 avg = (log1+log2+log3)*0.333 return end !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! function dif(log1,log2,log3,avg) implicit none real*8 dif real*8 avg real*8 log1,log2,log3 dif = (abs(log1-avg) + & abs(log2-avg) + & abs(log3-avg) ) * 0.333 return end !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! c********************************************************************** c*********************************************************************** function cociente (xnum, xdenom, minimo, option) c Returns the ratio between XNUM and XDENOM avoiding null values c according to the action given by OPTION. Checks that the are not c negative values c If XNUM = 0 -> cociente=0 c If XDENOM < minimo, increases XDENOM in a factor=1e20 to avoid c overflow, and after the ratio XNUM/XDENOM the value is back to normal c if cociente < minimo -> cociente=minimo c If XDENOM = 0 then : c option = 0 .... warning message and stop c option = 1 .... " " and cociente=minimo c MALV Jul-08 Original c*********************************************************************** implicit none ! Arguments real*8 cociente real*8 xnum real*8 xdenom real*8 minimo integer option ! Local variables real*8 factor !!!!!!! Program starts if (xnum .lt. 0.d0) then write (*,*) log10( xnum ) STOP ' ERROR. Negative productions. XNUM=0.' elseif (xdenom .lt. 0.d0) then STOP ' ERROR. Negative losses. XDENOM=0.' endif if (xnum .eq. 0.d0) then cociente = minimo return endif if (xdenom .eq. 0.d0) then if (option .eq. 0) then STOP ' ERROR. xdenom=0. ' elseif (option .eq. 1) then ! write (*,*) 'WARNING !! xdenom=0 ' ! write (*,*) 'WARNING !! option=2 => cociente=minimo', ! $ xdenom cociente = minimo return else STOP ' ERROR. option undefined in call to cociente' endif endif if (xdenom .lt. minimo) then factor = xdenom * 1.d20 cociente = xnum / factor * 1.d20 else cociente = xnum / xdenom endif if (cociente .lt. minimo) cociente = minimo return c END end