1 | ! Copyright (2013-2015,2017,2022-2023) Université de Reims Champagne-Ardenne |
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2 | ! Contributors : J. Burgalat (GSMA, URCA), B. de Batz de Trenquelléon (GSMA, URCA) |
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3 | ! email of the author : jeremie.burgalat@univ-reims.fr |
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4 | ! |
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5 | ! This software is a computer program whose purpose is to compute |
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6 | ! microphysics processes using a two-moments scheme. |
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7 | ! |
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8 | ! This library is governed by the CeCILL-B license under French law and |
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9 | ! abiding by the rules of distribution of free software. You can use, |
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10 | ! modify and/ or redistribute the software under the terms of the CeCILL-B |
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11 | ! license as circulated by CEA, CNRS and INRIA at the following URL |
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12 | ! "http://www.cecill.info". |
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13 | ! |
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14 | ! As a counterpart to the access to the source code and rights to copy, |
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15 | ! modify and redistribute granted by the license, users are provided only |
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16 | ! with a limited warranty and the software's author, the holder of the |
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17 | ! economic rights, and the successive licensors have only limited |
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18 | ! liability. |
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19 | ! |
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20 | ! In this respect, the user's attention is drawn to the risks associated |
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21 | ! with loading, using, modifying and/or developing or reproducing the |
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22 | ! software by the user in light of its specific status of free software, |
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23 | ! that may mean that it is complicated to manipulate, and that also |
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24 | ! therefore means that it is reserved for developers and experienced |
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25 | ! professionals having in-depth computer knowledge. Users are therefore |
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26 | ! encouraged to load and test the software's suitability as regards their |
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27 | ! requirements in conditions enabling the security of their systems and/or |
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28 | ! data to be ensured and, more generally, to use and operate it in the |
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29 | ! same conditions as regards security. |
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30 | ! |
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31 | ! The fact that you are presently reading this means that you have had |
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32 | ! knowledge of the CeCILL-B license and that you accept its terms. |
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33 | |
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34 | !! file: mm_methods.f90 |
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35 | !! summary: Model miscellaneous methods module. |
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36 | !! author: J. Burgalat |
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37 | !! date: 2013-2015,2017,2022-2023 |
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38 | !! modifications: B. de Batz de Trenquelléon |
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39 | |
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40 | MODULE MM_METHODS |
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41 | !! Model miscellaneous methods module. |
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42 | !! |
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43 | !! The module contains miscellaneous methods used either in the haze and clouds parts of the model. |
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44 | !! |
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45 | !! All thermodynamic functions related to cloud microphysics (i.e. [[mm_methods(module):mm_lHeatX(interface)]], |
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46 | !! [[mm_methods(module):mm_sigX(interface)]] and [[mm_methods(module):mm_psatX(interface)]]) compute related equations |
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47 | !! from \cite{reid1986}. A version of the book is freely available [here](http://f3.tiera.ru/3/Chemistry/References/Poling%20B.E.,%20Prausnitz%20J.M.,%20O'Connell%20J.P.%20The%20Properties%20of%20Gases%20and%20Liquids%20(5ed.,%20MGH,%202000)(ISBN%200070116822)(803s).pdf). |
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48 | !! |
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49 | !! The module defines the following functions/subroutines/interfaces: |
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50 | !! |
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51 | !! | name | description |
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52 | !! | :---------: | :------------------------------------------------------------------------------------- |
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53 | !! | mm_lheatx | Compute latent heat released |
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54 | !! | mm_sigx | Compute surface tension |
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55 | !! | mm_psatx | Compute saturation vapor pressure |
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56 | !! | mm_qsatx | Compute saturation mass mixing ratio |
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57 | !! | mm_fshape | Compute shape factor |
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58 | !! | mm_lambda_g | Compute air mean free path |
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59 | !! | mm_eta_g | Compute air viscosity |
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60 | !! | mm_get_kfm | Compute the thermodynamic pre-factor of coagulation kernel in free-molecular regime |
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61 | !! | mm_get_kco | Compute the thermodynamic pre-factor of coagulation kernel in continuous regime |
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62 | USE MM_MPREC |
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63 | USE MM_GLOBALS |
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64 | USE MM_INTERFACES |
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65 | IMPLICIT NONE |
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66 | |
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67 | PRIVATE |
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68 | |
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69 | PUBLIC :: mm_sigX, mm_LheatX, mm_psatX, mm_qsatx, mm_ysatX, mm_fshape, & |
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70 | mm_get_kco, mm_get_kfm, mm_eta_g, mm_lambda_g |
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71 | |
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72 | ! ---- INTERFACES |
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73 | |
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74 | !> Interface to surface tension computation functions. |
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75 | !! |
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76 | !! The method computes the surface tension of a given specie at given temperature(s). |
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77 | !! |
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78 | !! ```fortran |
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79 | !! FUNCTION mm_sigX(temp,xESP) |
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80 | !! ``` |
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81 | !! |
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82 | !! __xESP__ must always be given as a scalar. If __temp__ is given as a vector, then the method |
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83 | !! computes the result for all the temperatures and returns a vector of same size than __temp__. |
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84 | INTERFACE mm_sigX |
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85 | MODULE PROCEDURE sigx_sc,sigx_ve |
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86 | END INTERFACE mm_sigX |
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87 | |
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88 | !> Interface to Latent heat computation functions. |
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89 | !! |
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90 | !! The method computes the latent heat released of a given specie at given temperature(s). |
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91 | !! |
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92 | !! ```fortran |
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93 | !! FUNCTION mm_lheatX(temp,xESP) |
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94 | !! ``` |
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95 | !! |
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96 | !! __xESP__ must always be given as a scalar. If __temp__ is given as a vector, then the method |
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97 | !! computes the result for all the temperatures and returns a vector of same size than __temp__. |
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98 | INTERFACE mm_LheatX |
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99 | MODULE PROCEDURE lheatx_sc,lheatx_ve |
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100 | END INTERFACE mm_LheatX |
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101 | |
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102 | !> Interface to saturation vapor pressure computation functions. |
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103 | !! |
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104 | !! ```fortran |
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105 | !! FUNCTION mm_psatX(temp,xESP) |
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106 | !! ``` |
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107 | !! |
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108 | !! The method computes the saturation vapor pressure of a given specie at given temperature(s). |
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109 | !! |
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110 | !! __xESP__ must always be given as a scalar. If __temp__ is given as a vector, then the method |
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111 | !! computes the result for all the temperatures and returns a vector of same size than __temp__. |
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112 | INTERFACE mm_psatX |
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113 | MODULE PROCEDURE psatx_sc,psatx_ve |
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114 | END INTERFACE mm_psatX |
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115 | |
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116 | !> Interface to saturation mass mixing ratio computation functions. |
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117 | !! |
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118 | !! The method computes the mass mixing ratio at saturation of a given specie at given temperature(s) |
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119 | !! and pressure level(s). |
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120 | !! |
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121 | !! ```fortran |
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122 | !! FUNCTION mm_qsatX(temp,pres,xESP) |
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123 | !! ``` |
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124 | !! |
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125 | !! __xESP__ must always be given as a scalar. If __temp__ and __pres__ are given as a vector (of same |
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126 | !! size !), then the method computes the result for each couple of (temperature, pressure) and returns |
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127 | !! a vector of same size than __temp__. |
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128 | INTERFACE mm_qsatx |
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129 | MODULE PROCEDURE qsatx_sc,qsatx_ve |
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130 | END INTERFACE mm_qsatx |
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131 | |
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132 | !> Interface to saturation molar mixing ratio computation functions. |
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133 | !! |
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134 | !! The method computes the molar mixing ratio at saturation of a given specie at given temperature(s) |
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135 | !! and pressure level(s). |
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136 | !! |
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137 | !! ```fortran |
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138 | !! FUNCTION mm_ysatX(temp,pres,xESP) |
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139 | !! ``` |
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140 | !! |
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141 | !! __xESP__ must always be given as a scalar. If __temp__ and __pres__ are given as a vector (of same |
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142 | !! size !), then the method computes the result for each couple of (temperature, pressure) and returns |
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143 | !! a vector of same size than __temp__. |
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144 | INTERFACE mm_ysatX |
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145 | MODULE PROCEDURE ysatX_sc,ysatX_ve |
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146 | END INTERFACE mm_ysatX |
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147 | |
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148 | !> Interface to shape factor computation functions. |
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149 | !! |
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150 | !! The method computes the shape factor for the heterogeneous nucleation. |
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151 | !! |
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152 | !! ```fortran |
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153 | !! FUNCTION mm_fshape(m,x) |
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154 | !! ``` |
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155 | !! |
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156 | !! Where __m__ is cosine of the contact angle and __x__ the curvature radius. __m__ must always be |
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157 | !! given as a scalar. If __x__ is given as a vector, then the method compute the result for each |
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158 | !! value of __x__ and and returns a vector of same size than __x__. |
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159 | INTERFACE mm_fshape |
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160 | MODULE PROCEDURE fshape_sc,fshape_ve |
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161 | END INTERFACE mm_fshape |
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162 | |
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163 | CONTAINS |
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164 | |
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165 | FUNCTION fshape_sc(cost,rap) RESULT(res) |
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166 | !! Get the shape factor of a ccn (scalar). |
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167 | !! |
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168 | !! The method computes the shape factor for the heterogeneous nucleation on a fractal particle. |
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169 | !! Details about the shape factor can be found in \cite{prup1978}. |
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170 | REAL(kind=mm_wp), INTENT(in) :: cost !! Cosine of the contact angle. |
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171 | REAL(kind=mm_wp), INTENT(in) :: rap !! Curvature radius (\(r_{particle}/r^{*}\)). |
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172 | REAL(kind=mm_wp) :: res !! Shape factor value. |
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173 | REAL(kind=mm_wp) :: phi,a,b,c |
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174 | IF (rap > 3000._mm_wp) THEN |
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175 | res = ((2._mm_wp+cost)*(1._mm_wp-cost)**2)/4._mm_wp |
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176 | ELSE |
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177 | phi = dsqrt(1._mm_wp-2._mm_wp*cost*rap+rap**2) |
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178 | a = 1._mm_wp + ( (1._mm_wp-cost*rap)/phi )**3 |
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179 | b = (rap**3) * (2._mm_wp - 3._mm_wp*(rap-cost)/phi + ((rap-cost)/phi)**3) |
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180 | c = 3._mm_wp * cost * (rap**2) * ((rap-cost)/phi-1._mm_wp) |
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181 | res = 0.5_mm_wp*(a+b+c) |
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182 | ENDIF |
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183 | RETURN |
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184 | END FUNCTION fshape_sc |
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185 | |
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186 | FUNCTION fshape_ve(cost,rap) RESULT(res) |
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187 | !! Get the shape factor of a ccn (vector). |
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188 | !! |
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189 | !! See [[mm_methods(module):fshape_sc(function)]]. |
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190 | REAL(kind=mm_wp), INTENT(in) :: cost !! Cosine of the contact angle. |
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191 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: rap !! Curvature radii (\(r_{particle}/r^{*}\)). |
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192 | REAL(kind=mm_wp), DIMENSION(SIZE(rap)) :: res !! Shape factor value. |
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193 | REAL(kind=mm_wp), DIMENSION(SIZE(rap)) :: phi,a,b,c |
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194 | WHERE(rap > 3000._mm_wp) |
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195 | res = ((2._mm_wp+cost)*(1._mm_wp-cost)**2)/4._mm_wp |
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196 | ELSEWHERE |
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197 | phi = dsqrt(1._mm_wp-2._mm_wp*cost*rap+rap**2) |
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198 | a = 1._mm_wp + ((1._mm_wp-cost*rap)/phi )**3 |
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199 | b = (rap**3)*(2._mm_wp-3._mm_wp*(rap-cost)/phi+((rap-cost)/phi)**3) |
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200 | c = 3._mm_wp*cost*(rap**2)*((rap-cost)/phi-1._mm_wp) |
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201 | res = 0.5_mm_wp*(a+b+c) |
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202 | ENDWHERE |
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203 | RETURN |
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204 | END FUNCTION fshape_ve |
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205 | |
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206 | FUNCTION LHeatX_sc(temp,xESP) RESULT(res) |
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207 | !! Compute latent heat of a given specie at given temperature (scalar). |
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208 | !! |
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209 | !! The method computes the latent heat equation as given in \cite{reid1986} p. 220 (eq. 7-9.4). |
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210 | IMPLICIT NONE |
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211 | ! - DUMMY |
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212 | REAL(kind=mm_wp), INTENT(in) :: temp !! temperature (K). |
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213 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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214 | REAL(kind=mm_wp) :: res !! Latent heat of given specie at given temperature (\(J.kg^{-1}\)). |
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215 | REAL(kind=mm_wp) :: ftm |
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216 | ftm=MAX(1._mm_wp-temp/xESP%tc,1.e-3_mm_wp) |
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217 | res = mm_rgas*xESP%tc*(7.08_mm_wp*ftm**0.354_mm_wp+10.95_mm_wp*xESP%w*ftm**0.456_mm_wp)/xESP%masmol |
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218 | END FUNCTION LHeatX_sc |
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219 | |
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220 | FUNCTION LHeatX_ve(temp,xESP) RESULT(res) |
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221 | !! Compute latent heat of a given specie at given temperature (vector). |
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222 | !! |
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223 | !! See [[mm_methods(module):lheatx_sc(function)]]. |
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224 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: temp !! temperatures (K). |
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225 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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226 | REAL(kind=mm_wp), DIMENSION(SIZE(temp)) :: res !! Latent heat of given specie at given temperatures (\(J.kg^{-1}\)). |
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227 | REAL(kind=mm_wp) :: ftm |
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228 | INTEGER :: i |
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229 | DO i=1,SIZE(temp) |
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230 | ftm=MAX(1._mm_wp-temp(i)/xESP%tc,1.e-3_mm_wp) |
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231 | res(i) = mm_rgas*xESP%tc*(7.08_mm_wp*ftm**0.354_mm_wp+10.95_mm_wp*xESP%w*ftm**0.456_mm_wp) / & |
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232 | xESP%masmol |
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233 | ENDDO |
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234 | END FUNCTION LHeatX_ve |
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235 | |
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236 | FUNCTION sigX_sc(temp,xESP) RESULT(res) |
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237 | !! Get the surface tension between a given specie and the air (scalar). |
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238 | !! |
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239 | !! The method computes the surface tension equation as given in \cite{reid1986} p. 637 (eq. 12-3.6). |
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240 | REAL(kind=mm_wp), INTENT(in) :: temp !! temperature (K). |
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241 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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242 | REAL(kind=mm_wp) :: res !! Surface tension (\(N.m^{-1}\)). |
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243 | REAL(kind=mm_wp) :: tr,tbr,sig |
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244 | tr=MIN(temp/xESP%tc,0.99_mm_wp) |
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245 | tbr=xESP%tb/xESP%tc |
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246 | sig = 0.1196_mm_wp*(1._mm_wp+(tbr*dlog(xESP%pc/1.01325_mm_wp))/(1._mm_wp-tbr))-0.279_mm_wp |
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247 | sig = xESP%pc**(2._mm_wp/3._mm_wp)*xESP%tc**(1._mm_wp/3._mm_wp)*sig*(1._mm_wp-tr)**(11._mm_wp/9._mm_wp) |
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248 | res = sig*1e-3_mm_wp ! dyn/cm -> N/m |
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249 | END FUNCTION sigX_sc |
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250 | |
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251 | FUNCTION sigX_ve(temp,xESP) RESULT(res) |
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252 | !! Get the surface tension between a given specie and the air (vector). |
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253 | !! |
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254 | !! See [[mm_methods(module):sigx_sc(function)]]. |
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255 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: temp !! temperatures (K). |
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256 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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257 | REAL(kind=mm_wp), DIMENSION(SIZE(temp)) :: res !! Surface tensions (\(N.m^{-1}\)). |
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258 | INTEGER :: i |
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259 | REAL(kind=mm_wp) :: tr,tbr,sig0,sig |
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260 | tbr = xESP%tb/xESP%tc |
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261 | sig0 = 0.1196_mm_wp*(1._mm_wp+(tbr*dlog(xESP%pc/1.01325_mm_wp))/(1._mm_wp-tbr))-0.279_mm_wp |
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262 | DO i=1,SIZE(temp) |
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263 | tr = MIN(temp(i)/xESP%tc,0.99_mm_wp) |
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264 | sig = xESP%pc**(2._mm_wp/3._mm_wp)*xESP%tc**(1._mm_wp/3._mm_wp)*sig0*(1._mm_wp-tr)**(11._mm_wp/9._mm_wp) |
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265 | res(i) = sig*1e-3_mm_wp ! dyn/cm -> N/m |
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266 | ENDDO |
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267 | END FUNCTION sigX_ve |
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268 | |
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269 | FUNCTION psatX_sc(temp,xESP) RESULT(res) |
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270 | !! Get saturation vapor pressure for a given specie at given temperature (scalar). |
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271 | !! |
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272 | !! The method computes the saturation vapor pressure equation given in \cite{reid1986} p. 657 (eq. 1). |
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273 | REAL(kind=mm_wp), INTENT(in) :: temp !! Temperature (K). |
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274 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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275 | REAL(kind=mm_wp) :: res !! Saturation vapor pressure (Pa). |
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276 | REAL(kind=mm_wp) :: x,qsat |
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277 | x = 1._mm_wp-temp/xESP%tc |
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278 | IF (x > 0._mm_wp) THEN |
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279 | qsat = (1._mm_wp-x)**(-1) * & |
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280 | (xESP%a_sat*x + xESP%b_sat*x**1.5_mm_wp + xESP%c_sat*x**2.5_mm_wp + xESP%d_sat*x**5_mm_wp) |
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281 | ELSE |
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282 | qsat = XESP%a_sat*x/abs(1._mm_wp-x) ! approx for t > tc |
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283 | ENDIF |
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284 | res = xESP%pc*exp(qsat) |
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285 | ! now convert bar to Pa |
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286 | res = res * 1e5_mm_wp |
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287 | END FUNCTION psatX_sc |
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288 | |
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289 | FUNCTION psatX_ve(temp,xESP) RESULT(res) |
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290 | !! Get saturation vapor pressure for a given specie at given temperature (vector). |
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291 | !! |
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292 | !! See [[mm_methods(module):psatX_sc(function)]]. |
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293 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: temp !! Temperatures (K). |
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294 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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295 | REAL(kind=mm_wp), DIMENSION(SIZE(temp)) :: res !! Saturation vapor pressures (Pa). |
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296 | INTEGER :: i |
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297 | REAL(kind=mm_wp) :: x,qsat |
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298 | DO i=1, SIZE(temp) |
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299 | x = 1._mm_wp-temp(i)/xESP%tc |
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300 | IF (x > 0._mm_wp) THEN |
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301 | qsat = (1._mm_wp-x)**(-1) * & |
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302 | (xESP%a_sat*x + xESP%b_sat*x**1.5_mm_wp + xESP%c_sat*x**2.5_mm_wp + xESP%d_sat*x**5_mm_wp) |
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303 | ELSE |
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304 | qsat = XESP%a_sat*x/abs(1._mm_wp-x) ! approx for t > tc |
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305 | ENDIF |
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306 | res(i) = xESP%pc*exp(qsat) |
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307 | ENDDO |
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308 | ! now convert bar to Pa |
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309 | res = res * 1e5_mm_wp |
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310 | END FUNCTION psatX_ve |
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311 | |
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312 | FUNCTION qsatX_sc(temp,pres,xESP) RESULT(res) |
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313 | !! Get the mass mixing ratio of a given specie at saturation (scalar). |
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314 | !! |
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315 | !! @warning |
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316 | !! The method applies a multiplicative factor of 0.80 if the specie is CH4 : |
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317 | !! this is done to account for dissolution in N2 and is somehow specific to Titan atmosphere. |
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318 | REAL(kind=mm_wp), INTENT(in) :: temp !! Temperature (K). |
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319 | REAL(kind=mm_wp), INTENT(in) :: pres !! Pressure level (Pa). |
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320 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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321 | REAL(kind=mm_wp) :: res !! Mass mixing ratio of the specie. |
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322 | REAL(kind=mm_wp) :: psat |
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323 | psat = mm_psatX(temp,xESP) |
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324 | res = (psat / pres) * xESP%fmol2fmas |
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325 | ! Peculiar case of CH4 : x0.80 (dissolution in N2) |
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326 | IF (xESP%name == "CH4") THEN |
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327 | res = res * 0.80_mm_wp |
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328 | IF (mm_debug) WRITE(*,'(a)') "[DEBUG] mm_qsat: applying .85 factor to qsat for CH4 specie (N2 dissolution)" |
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329 | ENDIF |
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330 | END FUNCTION qsatX_sc |
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331 | |
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332 | FUNCTION qsatX_ve(temp,pres,xESP) RESULT(res) |
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333 | !! Get the mass mixing ratio of a given specie at saturation (vector). |
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334 | !! |
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335 | !! @warning |
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336 | !! The method applies a multiplicative factor of 0.85 if the specie is CH4 : |
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337 | !! this is done to account for dissolution in N2 and is somehow specific to Titan atmosphere. |
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338 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: temp !! Temperatures (K). |
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339 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: pres !! Pressure levels (Pa). |
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340 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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341 | REAL(kind=mm_wp), DIMENSION(SIZE(temp)) :: res !! Mass mixing ratios of the specie. |
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342 | REAL(kind=mm_wp), DIMENSION(SIZE(temp)) :: psat |
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343 | psat = mm_psatX(temp,xESP) |
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344 | res = (psat / pres) * xESP%fmol2fmas |
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345 | ! Peculiar case of CH4 : x0.80 (dissolution in N2) |
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346 | IF (xESP%name == "CH4") THEN |
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347 | res = res * 0.80_mm_wp |
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348 | IF (mm_debug) WRITE(*,'(a)') "[DEBUG] mm_qsat: applying .85 factor to qsat for CH4 specie (N2 dissolution)" |
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349 | ENDIF |
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350 | END FUNCTION qsatX_ve |
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351 | |
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352 | FUNCTION ysatX_sc(temp,pres,xESP) RESULT(res) |
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353 | !! Get the molar mixing ratio of a given specie at saturation (scalar). |
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354 | !! Compute saturation profiles (mol/mol) for condensable tracers |
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355 | !! |
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356 | !! @warning |
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357 | !! The method applies a multiplicative factor of 0.80 if the specie is CH4 : |
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358 | !! this is done to account for dissolution in N2 and is somehow specific to Titan atmosphere. |
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359 | REAL(kind=mm_wp), INTENT(in) :: temp !! Temperature (K). |
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360 | REAL(kind=mm_wp), INTENT(in) :: pres !! Pressure level (Pa). |
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361 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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362 | REAL(kind=mm_wp) :: res !! Molar mixing ratio of the specie. |
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363 | |
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364 | IF(xESP%name == "C2H2") THEN |
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365 | ! Fray and Schmidt (2009) |
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366 | res = (1.0e5 / pres) * exp(1.340e1 - 2.536e3/temp) |
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367 | |
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368 | ELSE IF(xESP%name == "C2H6") THEN |
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369 | ! Fray and Schmidt (2009) |
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370 | res = (1.0e5 / pres) * exp(1.511e1 - 2.207e3/temp - 2.411e4/temp**2 + 7.744e5/temp**3 - 1.161e7/temp**4 + 6.763e7/temp**5) |
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371 | |
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372 | ELSE IF(xESP%name == "HCN") THEN |
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373 | ! Fray and Schmidt (2009) |
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374 | res = (1.0e5 / pres) * exp(1.393e1 - 3.624e3/temp - 1.325e5/temp**2 + 6.314e6/temp**3 - 1.128e8/temp**4) |
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375 | |
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376 | ELSE IF (xESP%name == "CH4") THEN |
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377 | ! Fray and Schmidt (2009) |
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378 | res = (1.0e5 / pres) * exp(1.051e1 - 1.110e3/temp - 4.341e3/temp**2 + 1.035e5/temp**3 - 7.910e5/temp**4) |
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379 | ! Peculiar case of CH4 : x0.80 (dissolution in N2) |
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380 | res = res * 0.80_mm_wp |
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381 | ! Forcing CH4 to 1.4% minimum |
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382 | IF (res < 0.014) THEN |
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383 | res = 0.014 |
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384 | ENDIF |
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385 | ENDIF |
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386 | END FUNCTION ysatX_sc |
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387 | |
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388 | FUNCTION ysatX_ve(temp,pres,xESP) RESULT(res) |
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389 | !! Get the molar mixing ratio of a given specie at saturation (vector). |
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390 | !! Compute saturation profiles (mol/mol) for condensable tracers |
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391 | !! |
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392 | !! @warning |
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393 | !! The method applies a multiplicative factor of 0.80 if the specie is CH4 : |
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394 | !! this is done to account for dissolution in N2 and is somehow specific to Titan atmosphere. |
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395 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: temp !! Temperatures (K). |
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396 | REAL(kind=mm_wp), INTENT(in), DIMENSION(:) :: pres !! Pressure levels (Pa). |
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397 | TYPE(mm_esp), INTENT(in) :: xESP !! Specie properties. |
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398 | REAL(kind=mm_wp), DIMENSION(SIZE(temp)) :: res !! Molar mixing ratios of the specie. |
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399 | |
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400 | IF(xESP%name == "C2H2") THEN |
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401 | ! Fray and Schmidt (2009) |
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402 | res = (1.0e5 / pres) * exp(1.340e1 - 2.536e3/temp) |
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403 | |
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404 | ELSE IF(xESP%name == "C2H6") THEN |
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405 | ! Fray and Schmidt (2009) |
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406 | res = (1.0e5 / pres) * exp(1.511e1 - 2.207e3/temp - 2.411e4/temp**2 + 7.744e5/temp**3 - 1.161e7/temp**4 + 6.763e7/temp**5) |
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407 | |
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408 | ELSE IF(xESP%name == "HCN") THEN |
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409 | ! Fray and Schmidt (2009) |
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410 | res = (1.0e5 / pres) * exp(1.393e1 - 3.624e3/temp - 1.325e5/temp**2 + 6.314e6/temp**3 - 1.128e8/temp**4) |
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411 | |
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412 | ! Peculiar case : CH4 : x0.85 (dissolution in N2) |
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413 | ELSE IF (xESP%name == "CH4") THEN |
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414 | res = (1.0e5 / pres) * exp(1.051e1 - 1.110e3/temp - 4.341e3/temp**2 + 1.035e5/temp**3 - 7.910e5/temp**4) |
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415 | ! Peculiar case of CH4 : x0.80 (dissolution in N2) |
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416 | res = res * 0.80_mm_wp |
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417 | ! Forcing CH4 to 1.4% minimum |
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418 | WHERE (res(:) < 0.014) res(:) = 0.014 |
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419 | ENDIF |
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420 | END FUNCTION ysatX_ve |
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421 | |
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422 | ELEMENTAL FUNCTION mm_get_kco(t) RESULT(res) |
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423 | !! Get the Continuous regime thermodynamics pre-factor of the coagulation kernel. |
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424 | REAL(kind=mm_wp), INTENT(in) :: t !! Temperature (K). |
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425 | REAL(kind=mm_wp) :: res !! Continuous regime thermodynamics pre-factor (\(m^{3}.s^{-1}\)). |
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426 | res = 2._mm_wp*mm_kboltz*t / (3._mm_wp*mm_eta_g(t)) |
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427 | RETURN |
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428 | END FUNCTION mm_get_kco |
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429 | |
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430 | ELEMENTAL FUNCTION mm_get_kfm(t) RESULT(res) |
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431 | !! Get the Free Molecular regime thermodynamics pre-factor of the coagulation kernel. |
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432 | REAL(kind=mm_wp), INTENT(in) :: t !! Temperature (K). |
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433 | REAL(kind=mm_wp) :: res !! Free Molecular regime thermodynamics pre-factor (\(m^{5/2}.s^{-1}\)). |
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434 | res = (6._mm_wp*mm_kboltz*t/mm_rhoaer)**(0.5_mm_wp) |
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435 | RETURN |
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436 | END FUNCTION mm_get_kfm |
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437 | |
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438 | ! ELEMENTAL FUNCTION mm_eta_g(t) RESULT (res) |
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439 | ! !! Get the air viscosity at a given temperature. |
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440 | ! !! |
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441 | ! !! The function computes the air viscosity at temperature __t__ using Sutherland method. |
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442 | ! REAL(kind=mm_wp), INTENT(in) :: t !! Temperature (K). |
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443 | ! REAL(kind=mm_wp) :: res !! Air viscosity at given temperature (\(Pa.s^{-1}\)). |
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444 | ! REAL (kind=mm_wp), PARAMETER :: eta0 = 1.75e-5_mm_wp, & |
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445 | ! tsut = 109._mm_wp, & |
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446 | ! tref = 293._mm_wp |
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447 | ! res = eta0 *dsqrt(t/tref)*(1._mm_wp+tsut/tref)/(1._mm_wp+tsut/t) |
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448 | ! RETURN |
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449 | ! END FUNCTION mm_eta_g |
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450 | ! |
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451 | ! ELEMENTAL FUNCTION mm_lambda_g(t,p) RESULT(res) |
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452 | ! !! Get the air mean free path at given temperature and pressure. |
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453 | ! !! |
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454 | ! !! The method computes the air mean free path: |
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455 | ! !! |
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456 | ! !! $$ \lambda_{g} = \dfrac{k_{b}T}{4\sqrt{2}\pi r_{a}^2 P} $$ |
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457 | ! !! |
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458 | ! !! Where \(\lambda_{g}\), is the air mean free path, \(k_{b}\) the Boltzmann constant, T the |
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459 | ! !! temperature, P the pressure level and \(r_{a}\) the radius of an _air molecule_. |
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460 | ! REAL(kind=mm_wp), INTENT(in) :: t !! Temperature (K). |
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461 | ! REAL(kind=mm_wp), INTENT(in) :: p !! Pressure level (Pa). |
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462 | ! REAL(kind=mm_wp) :: res !! Air mean free path (m). |
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463 | ! res = mm_kboltz*t/(4._mm_wp*dsqrt(2._mm_wp)*mm_pi*(mm_air_rad**2)*p) |
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464 | ! RETURN |
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465 | ! END FUNCTION mm_lambda_g |
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466 | |
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467 | END MODULE MM_METHODS |
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