[1013] | 1 | ! RATES WITH FORMAT A *(t/300)**B * exp(C/t), with t=temperature |
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| 2 | ! ch2: h + o2 + co2 --> ho2 + co2 |
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| 3 | ! JPL 2011 (low pressure limit)*2.5 |
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| 4 | 1.1d-31 -1.3 0. |
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| 5 | ! ch3: o + ho2 --> oh + o2 |
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| 6 | ! JPL 2011 |
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| 7 | 3.0d-11 0. 200. |
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| 8 | ! ch4: co + oh --> co2 + h |
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| 9 | ! JPL 2011 (low pressure limit) |
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| 10 | 1.5d-13 0.6 0. |
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| 11 | ! ch5: ho2 + ho2 --> h2o2 + o2 |
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| 12 | ! JPL 2011 |
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| 13 | 3.0d-13 0. 460. |
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| 14 | ! ch7: oh + ho2 --> h2o + o2 |
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| 15 | ! JPL 2011 |
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| 16 | 4.8d-11 0. 250. |
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| 17 | ! ch9: o(1d) + h2o --> 2oh |
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| 18 | ! JPL 2011 |
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| 19 | 1.63d-10 0. 60. |
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| 20 | ! ch10: o + o + co2 --> o2 + co2 |
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| 21 | ! Tsang and Hampson, 1986 |
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| 22 | 1.3d-34 0. 900. |
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| 23 | ! ch11: o + oh --> o2 + h |
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| 24 | ! JPL 2011 |
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| 25 | 1.8d-11 0. 180. |
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| 26 | ! ch13: h + ho2 --> h2 + o2 |
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| 27 | ! JPL 2011 |
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| 28 | 6.9d-12 0. 0. |
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| 29 | ! ch14: o(1d) + h2 --> h + oh |
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| 30 | ! JPL 2011 |
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| 31 | 1.2d-10 0. 0. |
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| 32 | ! ch15: oh + h2 --> h + h2o |
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| 33 | ! JPL 2011 |
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| 34 | 2.8d-12 0. -1800. |
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| 35 | ! ch18: oh + h2o2 --> h2o + ho2 |
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| 36 | ! JPL 2011 |
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| 37 | 1.8d-12 0. 0. |
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| 38 | ! ch19: o(1d) + co2 --> o + co2 |
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| 39 | ! JPL 2011 |
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| 40 | 7.5d-11 0. 115. |
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| 41 | ! ch20: o(1d) + o2 --> o + o2 |
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| 42 | ! JPL 2011 |
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| 43 | 3.3d-11 0. 55. |
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| 44 | ! ch21: o + o2 + co2 --> o3 + co2 |
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| 45 | ! JPL 2011 * 2.5 |
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| 46 | 1.5d-33 -2.4 0. |
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| 47 | ! ch22: o3 + h --> o2 + oh |
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| 48 | ! JPL 201 |
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| 49 | 1.4d-10 0. -470. |
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| 50 | ! ch23: o3 + oh --> ho2 + o2 |
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| 51 | ! JPL 2011 |
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| 52 | 1.7d-12 0. -940. |
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| 53 | ! ch24: o3 + ho2 --> oh + 2o2 |
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| 54 | ! JPL 2011: |
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| 55 | 1.0d-14 0. -490. |
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| 56 | ! ch30: n + no --> n2 + o |
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| 57 | ! JPL 2011 |
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| 58 | 2.1d-11 0. 100. |
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| 59 | ! ch31: n2 + o(1d) --> n2 + o |
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| 60 | ! JPL 2011 |
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| 61 | 2.15d-11 0. 110. |
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| 62 | ! ch32: n + o2 --> no + o |
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| 63 | ! JPL 2011 |
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| 64 | 1.5d-11 0. -3600. |
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| 65 | ! ch33: n + oh --> no + h |
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| 66 | ! Atkinson et al. 1989 (IUPAC) |
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| 67 | 3.8d-11 0. 85. |
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| 68 | ! ch34: n + o3 --> no + o2 |
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| 69 | ! JPL 2011 (upper limit) |
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| 70 | 1.0d-16 0. 0. |
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| 71 | ! ch35: n + ho2 --> no + oh |
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| 72 | ! Brune et al., J. Phys. Chem. 1983 |
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| 73 | 2.2d-11 0. 0. |
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| 74 | ! ch36: n(2d) + o --> n + o |
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| 75 | ! Herron, J. Phys. Chem. Ref. Data 1999 |
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| 76 | 3.3d-12 0. -260. |
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| 77 | ! ch37: n(2d) + n2 --> n + n2 |
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| 78 | ! Herron, J. Phys. Chem. Ref. Data 1999 |
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| 79 | 1.7d-14 0. 0. |
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| 80 | ! ch38: n(2d) + co2 --> no + co |
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| 81 | ! Herron, J. Phys. Chem. Ref. Data 1999 |
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| 82 | 3.6d-13 0. 0. |
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| 83 | ! ch39: no + ho2 --> no2+oh |
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| 84 | ! JPL 2011 |
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| 85 | 3.3d-12 0. 270. |
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| 86 | ! ch40: o + no + co2 --> no2 + co2 |
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| 87 | ! 2.5 * JPL 2011 (low pressure limit) |
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| 88 | 2.25d-31 -1.5 0. |
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| 89 | ! ch41: o + no2 --> no + o2 |
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| 90 | ! JPL 2011 |
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| 91 | 5.1d-12 0. 210. |
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| 92 | ! ch42: no + o3 --> no2 + o2 |
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| 93 | ! JPL 2011 |
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| 94 | 3.0d-12 0. -1500. |
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| 95 | ! ch43: h + no2 --> no + oh |
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| 96 | ! JPL 2011 |
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| 97 | 4.0d-10 0. -340. |
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| 98 | ! ch45: n + o --> no |
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| 99 | ! Du and Dalgarno, JGR 1990 |
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| 100 | 2.8d-17 -0.5 0. |
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| 101 | ! ch46: co2+ + O2 --> O2+ + CO2 |
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| 102 | ! Aninich, J. Phys. Chem. Ref. Data 1993 |
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| 103 | 5.5d-11 -0.82 0. |
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| 104 | ! ch47: CO2+ + O --> O+ + CO2 |
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| 105 | ! UMIST database |
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| 106 | 9.6d-11 0. 0. |
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| 107 | ! ch48: CO2+ + O --> O2+ + CO |
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| 108 | ! UMIST database |
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| 109 | 1.64d-10 0. 0. |
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| 110 | ! ch49: O2+ + elect --> O + O |
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| 111 | ! Alge et al., J. Phys. B, At. Mol. Phys. 1983 |
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| 112 | 2.0d-7 -0.7 0. |
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| 113 | ! ch50: O+ + CO2 --> O2+ + CO |
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| 114 | ! UMIST database |
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| 115 | 9.4d-10 0. 0. |
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| 116 | ! ch55: CO2+ + e ----> CO + O |
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| 117 | ! UMIST database |
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| 118 | 3.8d-7 -0.5 0. |
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| 119 | ! ch56: O+ + CO2 ---> O2 + CO+ |
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| 120 | ! Error in Kim et al., 1989?? |
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| 121 | 0. 0. 0. |
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| 122 | ! ch57: CO+ + CO2 ---> CO2+ + CO |
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| 123 | ! UMIST database |
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| 124 | 1.0d-9 0. 0. |
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| 125 | ! ch58: CO+ + O ---> O+ + CO |
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| 126 | ! UMIST database |
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| 127 | 1.4d-10 0. 0. |
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| 128 | ! ch59: C+ + CO2 ---> CO+ + CO |
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| 129 | ! UMIST database |
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| 130 | 1.1d-9 0. 0. 0. 0. |
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| 131 | ! ch62: CO2+ + NO --> NO+ + CO2 |
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| 132 | ! UMIST database |
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| 133 | 1.2d-10 0. 0. |
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| 134 | ! ch63: CO2+ + N --> NO + CO+ |
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| 135 | ! Scott et al., J. Chem. Phys. 1998 |
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| 136 | 3.4d-10 0. 0. |
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| 137 | ! ch64: O2+ + NO --> NO+ + O2 |
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| 138 | ! Middey and Viggiano. J. Chem. Phys. 1999 |
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| 139 | 4.5d-10 0. 0. |
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| 140 | ! ch65: O2+ + N2 --> NO+ + NO |
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| 141 | ! Ferguson, At. Data Necl. Data Tables, 1973 (Fox and Sung 2001) |
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| 142 | 1.0d-15 0. 0. |
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| 143 | ! ch66: O2+ + N --> NO+ + O |
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| 144 | ! Scott et al., J. Chem. Phys. 1998 (Fox and Sung 2001) |
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| 145 | 1.0d-10 0. 0. |
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| 146 | ! ch67: O+ + N2 --> NO+ + N |
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| 147 | ! UMIST database |
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| 148 | 1.2d-12 -0.45 0. |
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| 149 | ! ch68: N2+ + CO2 --> CO2+ + N2 |
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| 150 | ! Dotan et al., J. Chem. Phys. 2000 (Fox and Sung 2001) |
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| 151 | 9.d-10 -0.23 0. |
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| 152 | ! ch69: N2+ + O3p --> NO+ + N |
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| 153 | ! Scott et al., J. Phys. Chem. A 1999 (Fox and Sung 2001) |
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| 154 | 1.33d-10 -0.44 0. |
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| 155 | ! ch70: N2+ + CO --> N2 + CO+ |
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| 156 | ! UMIST database |
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| 157 | 7.4d-11 0. 0. |
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| 158 | ! ch71: N2+ + e- --> N + N |
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| 159 | ! UMIST database |
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| 160 | 1.7d-7 -0.3 0. |
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| 161 | ! ch72: N2+ + O3p --> O+ + N2 |
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| 162 | ! Scott et al., J. Phys. Chem. A 1999 (Fox and Sung 2001) |
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| 163 | 7.0d-12 -0.23 0. |
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| 164 | ! ch73: CO+ + H --> H+ + CO |
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| 165 | ! Scott et al., J. Chem. Phys. 1997 (Fox and Sung 2001) |
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| 166 | 4.0d-10 0. 0. |
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| 167 | ! ch74: O+ + H --> H+ + O |
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| 168 | ! UMIST database |
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| 169 | 5.66d-10 0.36 8.6 |
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| 170 | ! ch75: NO+ + e- --> N + O |
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| 171 | ! UMIST database |
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| 172 | 4.3d-7 -0.37 0. |
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| 173 | ! ch76: H+ + O3p --> O+ + H |
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| 174 | ! UMIST database |
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| 175 | 6.86d-10 0.26 -224.3 |
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| 176 | ! ch85: N+ + CO2 --> CO2+ + N |
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| 177 | ! UMIST database |
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| 178 | 7.5d-10 0. 0. |
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| 179 | ! ch86: H2 + CO2+ --> H + HCO2+ |
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| 180 | ! UMIST database |
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| 181 | 9.5d-10 0. 0. |
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| 182 | ! ch87: HCO2+ + e -> CO2 + H |
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| 183 | ! Krasnopolsky, JGR 2002 |
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| 184 | 3.4d-7 -0.5 0. |
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