| 1 | !*********************************************************************** |
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| 2 | |
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| 3 | module chimiedata_h |
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| 4 | |
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| 5 | !*********************************************************************** |
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| 6 | ! |
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| 7 | ! subject: |
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| 8 | ! -------- |
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| 9 | ! |
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| 10 | ! data for photochemistry |
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| 11 | ! |
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| 12 | ! update 06/03/2021 set to module - add global variable (Yassin Jaziri) |
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| 13 | ! |
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| 14 | ! |
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| 15 | !*********************************************************************** |
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| 16 | |
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| 17 | implicit none |
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| 18 | |
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| 19 | character*30, save, allocatable :: chemnoms(:) ! name of chemical tracers |
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| 20 | |
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| 21 | !-------------------------------------------- |
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| 22 | ! dimensions of photolysis lookup table |
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| 23 | !-------------------------------------------- |
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| 24 | |
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| 25 | integer, save :: nd ! species |
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| 26 | integer, save :: nz ! altitude |
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| 27 | integer, save :: nozo ! ozone |
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| 28 | integer, save :: nsza ! solar zenith angle |
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| 29 | integer, save :: ntemp ! temperature |
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| 30 | integer, save :: ntau ! dust |
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| 31 | integer, save :: nch4 ! ch4 |
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| 32 | |
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| 33 | !-------------------------------------------- |
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| 34 | |
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| 35 | real, parameter :: kb = 1.3806e-23 |
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| 36 | |
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| 37 | ! photolysis |
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| 38 | real, save, allocatable :: jphot(:,:,:,:,:,:,:) |
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| 39 | real, save, allocatable :: ephot(:,:,:,:,:,:,:) |
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| 40 | real, save, allocatable :: colairtab(:) |
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| 41 | real, save, allocatable :: szatab(:) |
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| 42 | real, save, allocatable :: table_ozo(:) |
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| 43 | real, save, allocatable :: tautab(:) |
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| 44 | real, save, allocatable :: table_ch4(:) |
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| 45 | |
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| 46 | ! deposition |
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| 47 | real, save, allocatable :: SF_value(:) ! SF_mode=1 (vmr) SF_mode=2 (cm.s-1) |
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| 48 | real, save, allocatable :: prod_rate(:) ! production flux in molecules/m2/s |
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| 49 | real, save, allocatable :: surface_flux(:,:) ! Surface flux from deposition molecules/m2/s |
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| 50 | real, save, allocatable :: surface_flux2(:,:) ! Surface flux mean molecules/m2/s |
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| 51 | real, save, allocatable :: escape(:,:) ! escape rate in molecules/m2/s |
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| 52 | integer, save, allocatable :: SF_mode(:) ! SF_mode=1 (fixed mixing ratio) / 2 (fixed sedimentation velocity in cm/s and/or flux in molecules/m^3) |
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| 53 | |
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| 54 | !-------------------------------------------- |
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| 55 | |
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| 56 | real, save, allocatable :: albedo_snow_chim(:) ! albedo snow on chemistry wavelenght grid |
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| 57 | real, save, allocatable :: albedo_co2_ice_chim(:) ! albedo co2 ice on chemistry wavelenght grid |
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| 58 | real, save, allocatable :: fluxUV(:,:,:) ! total actinic flux at each ngrid, wavelength and altitude (photon.s-1.nm-1.cm-2) |
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| 59 | |
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| 60 | !-------------------------------------------- |
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| 61 | ! For hard coding reactions |
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| 62 | !-------------------------------------------- |
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| 63 | |
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| 64 | integer, parameter :: nphot_hard_coding = 0 |
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| 65 | integer, parameter :: n4_hard_coding = 0 |
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| 66 | integer, parameter :: n3_hard_coding = 0 |
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| 67 | |
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| 68 | contains |
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| 69 | |
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| 70 | subroutine indice_HC(nb_phot,nb_reaction_4,nb_reaction_3) |
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| 71 | |
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| 72 | use types_asis |
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| 73 | |
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| 74 | implicit none |
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| 75 | |
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| 76 | integer, intent(inout) :: nb_phot |
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| 77 | integer, intent(inout) :: nb_reaction_4 |
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| 78 | integer, intent(inout) :: nb_reaction_3 |
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| 79 | |
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| 80 | !!!!!!!!!!! Hard coding reaction !!!!!!!!!!!!!!!!!!!!!!!!!!! |
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| 81 | !=========================================================== |
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| 82 | ! d022 : HO2 + NO + M -> HNO3 + M |
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| 83 | !=========================================================== |
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| 84 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 85 | !indice_4(nb_reaction_4) = z4spec(1.0, indexchim('ho2'), 1.0, indexchim('no'), 1.0, indexchim('hno3'), 0.0, 1) |
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| 86 | |
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| 87 | !=========================================================== |
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| 88 | ! e001 : CO + OH -> CO2 + H |
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| 89 | !=========================================================== |
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| 90 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 91 | !indice_4(nb_reaction_4) = z4spec(1.0, indexchim('co'), 1.0, indexchim('oh'), 1.0, indexchim('co2'), 1.0, indexchim('h')) |
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| 92 | |
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| 93 | !=========================================================== |
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| 94 | ! f028 : CH + CH4 -> C2H4 + H |
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| 95 | !=========================================================== |
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| 96 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 97 | !indice_4(nb_reaction_4) = z4spec(1.0, indexchim('ch'), 1.0, indexchim('ch4'), 1.0, indexchim('c2h4'), 1.0, indexchim('h')) |
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| 98 | |
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| 99 | !=========================================================== |
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| 100 | ! r001 : HNO3 + rain -> H2O |
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| 101 | !=========================================================== |
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| 102 | !nb_phot = nb_phot + 1 |
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| 103 | !indice_phot(nb_phot) = z3spec(1.0, indexchim('hno3'), 1.0, indexchim('h2o_vap'), 0.0, 1) |
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| 104 | |
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| 105 | !=========================================================== |
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| 106 | ! e001 : CO + OH -> CO2 + H |
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| 107 | !=========================================================== |
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| 108 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 109 | !indice_4(nb_reaction_4) = z4spec(1.0, indexchim('co'), 1.0, indexchim('oh'), 1.0, indexchim('co2'), 1.0, indexchim('h')) |
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| 110 | |
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| 111 | !ccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccc |
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| 112 | ! photodissociation of NO : NO + hv -> N + O |
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| 113 | !ccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccc |
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| 114 | !nb_phot = nb_phot + 1 |
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| 115 | !indice_phot(nb_phot) = z3spec(1.0, indexchim('no'), 1.0, indexchim('n'), 1.0, indexchim('o')) |
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| 116 | |
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| 117 | !!!!!!!!!!! END Hard coding reaction !!!!!!!!!!!!!!!!!!!!!!! |
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| 118 | end subroutine indice_HC |
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| 119 | |
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| 120 | subroutine reactionrates_HC(nlayer,nesp,dens,t,press,zmmean,sza,c,v_phot,v_4,v_3,nb_phot,nb_reaction_4,nb_reaction_3) |
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| 121 | |
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| 122 | use comcstfi_mod, only: g, avocado |
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| 123 | use types_asis |
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| 124 | |
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| 125 | implicit none |
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| 126 | |
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| 127 | integer, intent(in) :: nlayer ! number of atmospheric layers |
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| 128 | integer, intent(in) :: nesp ! number of chemical species |
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| 129 | integer, intent(inout) :: nb_phot |
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| 130 | integer, intent(inout) :: nb_reaction_4 |
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| 131 | integer, intent(inout) :: nb_reaction_3 |
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| 132 | real, intent(in), dimension(nlayer) :: dens ! total number density (molecule.cm-3) |
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| 133 | real, intent(in), dimension(nlayer) :: press ! pressure (hPa) |
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| 134 | real, intent(in), dimension(nlayer) :: t ! temperature (K) |
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| 135 | real, intent(in), dimension(nlayer) :: zmmean ! mean molar mass (g/mole) |
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| 136 | real, intent(in) :: sza ! solar zenith angle (deg) |
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| 137 | real (kind = 8), intent(in), dimension(nlayer,nesp) :: c ! species number density (molecule.cm-3) |
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| 138 | real (kind = 8), intent(inout), dimension(nlayer, nb_phot_max) :: v_phot |
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| 139 | real (kind = 8), intent(inout), dimension(nlayer,nb_reaction_4_max) :: v_4 |
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| 140 | real (kind = 8), intent(inout), dimension(nlayer,nb_reaction_3_max) :: v_3 |
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| 141 | |
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| 142 | ! local |
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| 143 | |
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| 144 | real, dimension(nlayer) :: colo3 ! ozone columns (molecule.cm-2) |
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| 145 | integer :: ilev |
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| 146 | real :: k1a0, k1b0, k1ainf, k1a, k1b, fc, fx, x, y |
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| 147 | real :: ak0, ak1, rate, xpo, deq, rate1, rate2, xpo1, xpo2 |
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| 148 | real :: rain_h2o, rain_rate |
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| 149 | |
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| 150 | !!!!!!!!!!! Hard coding reaction !!!!!!!!!!!!!!!!!!!!!!!!!!! |
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| 151 | !---------------------------------------------------------------------- |
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| 152 | ! nitrogen reactions |
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| 153 | !---------------------------------------------------------------------- |
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| 154 | |
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| 155 | !--- d022: ho2 + no + m -> hno3 + m |
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| 156 | ! Butkovskaya et al. 2007 |
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| 157 | |
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| 158 | !d022(:) = 6.4e-14*exp(1644/T(:)) |
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| 159 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 160 | !v_4(:,nb_reaction_4) = 3.3e-12*exp(270./t(:))*((530/T(:)+6.4*1e-4*press(:)/1.33322-1.73))*1e-2 |
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| 161 | |
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| 162 | !---------------------------------------------------------------------- |
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| 163 | ! carbon reactions |
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| 164 | !---------------------------------------------------------------------- |
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| 165 | |
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| 166 | !--- e001: oh + co -> co2 + h |
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| 167 | |
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| 168 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 169 | |
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| 170 | ! jpl 2003 |
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| 171 | |
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| 172 | !e001(:) = 1.5e-13*(1 + 0.6*press(:)/1013.) |
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| 173 | |
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| 174 | ! mccabe et al., grl, 28, 3135, 2001 |
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| 175 | |
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| 176 | !e001(:) = 1.57e-13 + 3.54e-33*dens(:) |
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| 177 | |
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| 178 | ! jpl 2006 |
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| 179 | |
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| 180 | !ak0 = 1.5e-13*(t(:)/300.)**(0.6) |
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| 181 | !ak1 = 2.1e-9*(t(:)/300.)**(6.1) |
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| 182 | !rate1 = ak0/(1. + ak0/(ak1/dens(:))) |
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| 183 | !xpo1 = 1./(1. + alog10(ak0/(ak1/dens(:)))**2) |
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| 184 | |
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| 185 | !ak0 = 5.9e-33*(t(:)/300.)**(-1.4) |
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| 186 | !ak1 = 1.1e-12*(t(:)/300.)**(1.3) |
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| 187 | !rate2 = (ak0*dens(:))/(1. + ak0*dens(:)/ak1) |
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| 188 | !xpo2 = 1./(1. + alog10((ak0*dens(:))/ak1)**2) |
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| 189 | |
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| 190 | !e001(:) = rate1*0.6**xpo1 + rate2*0.6**xpo2 |
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| 191 | |
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| 192 | ! jpl 2015 |
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| 193 | |
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| 194 | !do ilev = 1,nlayer |
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| 195 | !!oh + co -> h + co2 |
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| 196 | ! rate1 = 1.5e-13*(t(ilev)/300.)**(0.0) |
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| 197 | !!oh + co + m -> hoco |
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| 198 | ! ak0 = 5.9e-33*(t(ilev)/300.)**(-1.0) |
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| 199 | ! ak1 = 1.1e-12*(t(ilev)/300.)**(1.3) |
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| 200 | ! rate2 = (ak0*dens(ilev))/(1. + ak0*dens(ilev)/ak1) |
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| 201 | ! xpo2 = 1./(1. + alog10((ak0*dens(ilev))/ak1)**2) |
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| 202 | ! |
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| 203 | ! v_4(ilev,nb_reaction_4) = rate1 + rate2*0.6**xpo2 |
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| 204 | !end do |
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| 205 | |
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| 206 | ! joshi et al., 2006 |
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| 207 | |
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| 208 | !do ilev = 1,nlayer |
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| 209 | ! k1a0 = 1.34*2.5*dens(ilev) & |
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| 210 | ! *1/(1/(3.62e-26*t(ilev)**(-2.739)*exp(-20./t(ilev))) & |
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| 211 | ! + 1/(6.48e-33*t(ilev)**(0.14)*exp(-57./t(ilev)))) ! typo in paper corrected |
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| 212 | ! k1b0 = 1.17e-19*t(ilev)**(2.053)*exp(139./t(ilev)) & |
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| 213 | ! + 9.56e-12*t(ilev)**(-0.664)*exp(-167./t(ilev)) |
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| 214 | ! k1ainf = 1.52e-17*t(ilev)**(1.858)*exp(28.8/t(ilev)) & |
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| 215 | ! + 4.78e-8*t(ilev)**(-1.851)*exp(-318./t(ilev)) |
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| 216 | ! x = k1a0/(k1ainf - k1b0) |
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| 217 | ! y = k1b0/(k1ainf - k1b0) |
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| 218 | ! fc = 0.628*exp(-1223./t(ilev)) + (1. - 0.628)*exp(-39./t(ilev)) & |
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| 219 | ! + exp(-t(ilev)/255.) |
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| 220 | ! fx = fc**(1./(1. + (alog(x))**2)) ! typo in paper corrected |
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| 221 | ! k1a = k1a0*((1. + y)/(1. + x))*fx |
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| 222 | ! k1b = k1b0*(1./(1.+x))*fx |
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| 223 | ! |
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| 224 | ! v_4(ilev,nb_reaction_4) = k1a + k1b |
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| 225 | !end do |
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| 226 | |
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| 227 | !--- f028: ch + ch4 + m -> c2h4 + h + m |
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| 228 | ! Romani 1993 |
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| 229 | |
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| 230 | !nb_reaction_4 = nb_reaction_4 + 1 |
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| 231 | !v_4(:,nb_reaction_4) = min(2.5e-11*exp(200./t(:)),1.7e-10) |
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| 232 | |
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| 233 | !---------------------------------------------------------------------- |
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| 234 | ! washout r001 : HNO3 + rain -> H2O |
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| 235 | !---------------------------------------------------------------------- |
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| 236 | |
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| 237 | !nb_phot = nb_phot + 1 |
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| 238 | ! |
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| 239 | !rain_h2o = 100.e-6 |
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| 240 | !!rain_rate = 1.e-6 ! 10 days |
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| 241 | !rain_rate = 1.e-8 |
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| 242 | ! |
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| 243 | !do ilev = 1,nlayer |
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| 244 | ! if (c(ilev,indexchim('h2o_vap'))/dens(ilev) >= rain_h2o) then |
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| 245 | ! v_phot(ilev,nb_phot) = rain_rate |
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| 246 | ! else |
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| 247 | ! v_phot(ilev,nb_phot) = 0. |
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| 248 | ! end if |
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| 249 | !end do |
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| 250 | |
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| 251 | !ccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccc |
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| 252 | ! photodissociation of NO |
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| 253 | !ccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccc |
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| 254 | |
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| 255 | !nb_phot = nb_phot + 1 |
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| 256 | ! |
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| 257 | !colo3(nlayer) = 0. |
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| 258 | !! ozone columns for other levels (molecule.cm-2) |
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| 259 | !do ilev = nlayer-1,1,-1 |
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| 260 | ! colo3(ilev) = colo3(ilev+1) + (c(ilev+1,indexchim('o3')) + c(ilev,indexchim('o3')))*0.5*avocado*1e-4*((press(ilev) - press(ilev+1))*100.)/(1.e-3*zmmean(ilev)*g*dens(ilev)) |
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| 261 | !end do |
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| 262 | !call jno(nlayer, c(nlayer:1:-1,indexchim('no')), c(nlayer:1:-1,indexchim('o2')), colo3(nlayer:1:-1), dens(nlayer:1:-1), press(nlayer:1:-1), sza, v_phot(nlayer:1:-1,nb_phot)) |
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| 263 | |
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| 264 | !!!!!!!!!!! END Hard coding reaction !!!!!!!!!!!!!!!!!!!!!!! |
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| 265 | end subroutine reactionrates_HC |
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| 266 | |
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| 267 | subroutine jno(nivbas, c_no, c_o2, o3t, hnm, pm, sza, tjno) |
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| 268 | |
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| 269 | !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! |
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| 270 | ! ! |
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| 271 | ! parametrisation de la photodissociation de no ! |
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| 272 | ! d'apres minschwaner and siskind, a new calculation ! |
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| 273 | ! of nitric oxide photolysis in the stratosphere, ! |
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| 274 | ! mesosphere, and lower thermosphere, j. geophys. res., ! |
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| 275 | ! 98, 20401-20412, 1993 ! |
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| 276 | ! ! |
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| 277 | !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! |
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| 278 | |
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| 279 | implicit none |
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| 280 | |
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| 281 | ! input |
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| 282 | |
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| 283 | integer, intent(in) :: nivbas |
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| 284 | real (kind = 8), dimension(nivbas), intent(in) :: c_no, c_o2 |
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| 285 | real, dimension(nivbas), intent(in) :: hnm, o3t, pm |
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| 286 | real, intent(in) :: sza |
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| 287 | |
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| 288 | ! output |
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| 289 | |
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| 290 | real, dimension(nivbas), intent(out) :: tjno |
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| 291 | |
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| 292 | ! local |
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| 293 | |
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| 294 | real, parameter :: factor = 3.141592/180. |
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| 295 | real, dimension(nivbas) :: colo2, colno, colo3 |
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| 296 | real, dimension(nivbas) :: r_o2, r_no |
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| 297 | real, dimension(nivbas) :: p, t_o3_1, t_o3_2, t_o3_3 |
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| 298 | real, dimension(nivbas) :: bd1, bd2, bd3 |
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| 299 | real, dimension(6,3) :: sigma_o2, sigma_no_1, sigma_no_2 |
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| 300 | real, dimension(6,3) :: w_no_1, w_no_2 |
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| 301 | real, dimension(3) :: delta_lambda, i0, sigma_o3 |
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| 302 | real :: a, d, kq, n2 |
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| 303 | real :: sec, zcmt, dp |
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| 304 | integer :: iniv |
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| 305 | |
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| 306 | ! sections efficaces |
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| 307 | |
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| 308 | sigma_o2(:,1) = (/1.12e-23, 2.45e-23, 7.19e-23, & |
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| 309 | 3.04e-22, 1.75e-21, 1.11e-20/) |
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| 310 | sigma_o2(:,2) = (/1.35e-22, 2.99e-22, 7.33e-22, & |
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| 311 | 3.07e-21, 1.69e-20, 1.66e-19/) |
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| 312 | sigma_o2(:,3) = (/2.97e-22, 5.83e-22, 2.05e-21, & |
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| 313 | 8.19e-21, 4.80e-20, 2.66e-19/) |
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| 314 | |
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| 315 | sigma_no_1(:,1) = (/0.00e+00, 1.32e-18, 6.35e-19, & |
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| 316 | 7.09e-19, 2.18e-19, 4.67e-19/) |
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| 317 | sigma_no_1(:,2) = (/0.00e+00, 0.00e+00, 3.05e-21, & |
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| 318 | 5.76e-19, 2.29e-18, 2.21e-18/) |
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| 319 | sigma_no_1(:,3) = (/1.80e-18, 1.50e-18, 5.01e-19, & |
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| 320 | 7.20e-20, 6.72e-20, 1.49e-21/) |
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| 321 | |
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| 322 | sigma_no_2(:,1) = (/0.00e+00, 4.41e-17, 4.45e-17, & |
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| 323 | 4.50e-17, 2.94e-17, 4.35e-17/) |
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| 324 | sigma_no_2(:,2) = (/0.00e+00, 0.00e+00, 3.20e-21, & |
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| 325 | 5.71e-17, 9.09e-17, 6.00e-17/) |
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| 326 | sigma_no_2(:,3) = (/1.40e-16, 1.52e-16, 7.00e-17, & |
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| 327 | 2.83e-17, 2.73e-17, 6.57e-18/) |
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| 328 | |
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| 329 | ! facteurs de ponderation |
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| 330 | |
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| 331 | w_no_1(:,1) = (/0.00e+00, 5.12e-02, 1.36e-01, & |
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| 332 | 1.65e-01, 1.41e-01, 4.50e-02/) |
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| 333 | w_no_1(:,2) = (/0.00e+00, 0.00e+00, 1.93e-03, & |
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| 334 | 9.73e-02, 9.75e-02, 3.48e-02/) |
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| 335 | w_no_1(:,3) = (/4.50e-02, 1.80e-01, 2.25e-01, & |
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| 336 | 2.25e-01, 1.80e-01, 4.50e-02/) |
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| 337 | |
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| 338 | w_no_2(:,1) = (/0.00e+00, 5.68e-03, 1.52e-02, & |
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| 339 | 1.83e-02, 1.57e-02, 5.00e-03/) |
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| 340 | w_no_2(:,2) = (/0.00e+00, 0.00e+00, 2.14e-04, & |
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| 341 | 1.08e-02, 1.08e-02, 3.86e-03/) |
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| 342 | w_no_2(:,3) = (/5.00e-03, 2.00e-02, 2.50e-02, & |
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| 343 | 2.50e-02, 2.00e-02, 5.00e-03/) |
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| 344 | |
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| 345 | ! largeurs spectrales pour les trois bandes considerees (nm) |
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| 346 | |
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| 347 | delta_lambda = (/2.3, 1.5, 1.5/) |
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| 348 | |
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| 349 | ! flux pour les trois bandes considerees (s-1 cm-2 nm-1) |
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| 350 | |
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| 351 | i0 = (/3.98e+11, 2.21e+11, 2.30e+11/) |
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| 352 | |
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| 353 | ! sections efficaces de l'ozone pour les trois bandes |
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| 354 | ! considerees (cm2) d'apres wmo 1985 |
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| 355 | |
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| 356 | sigma_o3 = (/4.6e-19, 6.7e-19, 7.1e-19/) |
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| 357 | |
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| 358 | ! zcmt: gas constant/boltzmann constant*g |
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| 359 | |
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| 360 | zcmt = 287.0/(1.38e-23*9.81) |
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| 361 | |
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| 362 | ! d: taux de predissociation spontanee (s-1) |
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| 363 | |
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| 364 | d = 1.65e+09 |
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| 365 | |
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| 366 | ! a: taux d'emission spontanee (s-1) |
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| 367 | |
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| 368 | a = 5.1e+07 |
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| 369 | |
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| 370 | ! kq: quenching rate constant (cm3 s-1) |
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| 371 | |
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| 372 | kq = 1.5e-09 |
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| 373 | |
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| 374 | ! rapports de melange |
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| 375 | |
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| 376 | r_no(:) = c_no(:)/hnm(:) |
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| 377 | r_o2(:) = c_o2(:)/hnm(:) |
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| 378 | |
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| 379 | !============================================================= |
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| 380 | ! calcul des colonnes de o2 et no |
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| 381 | !============================================================= |
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| 382 | |
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| 383 | ! premier niveau du modele (mol/cm2) |
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| 384 | |
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| 385 | colo2(1) = 6.8e+05*c_o2(1) |
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| 386 | colno(1) = 6.8e+05*c_no(1) |
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| 387 | colo3(1) = o3t(1) |
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| 388 | |
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| 389 | ! cas general |
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| 390 | |
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| 391 | do iniv = 2,nivbas |
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| 392 | dp = (pm(iniv) - pm(iniv - 1))*100. |
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| 393 | dp = max(dp, 0.) |
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| 394 | colo2(iniv) = colo2(iniv - 1) & |
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| 395 | + zcmt*(r_o2(iniv-1) + r_o2(iniv))*0.5*dp*1.e-4 |
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| 396 | colno(iniv) = colno(iniv - 1) & |
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| 397 | + zcmt*(r_no(iniv-1) + r_no(iniv))*0.5*dp*1.e-4 |
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| 398 | colo3(iniv) = o3t(iniv) |
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| 399 | end do |
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| 400 | |
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| 401 | !============================================================= |
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| 402 | ! boucle sur les niveaux |
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| 403 | !============================================================= |
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| 404 | |
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| 405 | do iniv = 1,nivbas |
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| 406 | if (sza <= 89.0) then |
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| 407 | |
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| 408 | sec = 1./cos(sza*factor) |
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| 409 | |
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| 410 | colo2(iniv) = colo2(iniv)*sec |
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| 411 | colno(iniv) = colno(iniv)*sec |
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| 412 | colo3(iniv) = colo3(iniv)*sec |
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| 413 | |
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| 414 | ! facteurs de transmission de l'ozone |
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| 415 | |
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| 416 | t_o3_1(iniv) = exp(-sigma_o3(1)*colo3(iniv)) |
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| 417 | t_o3_2(iniv) = exp(-sigma_o3(2)*colo3(iniv)) |
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| 418 | t_o3_3(iniv) = exp(-sigma_o3(3)*colo3(iniv)) |
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| 419 | |
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| 420 | ! calcul de la probabilite de predissociation |
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| 421 | |
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| 422 | n2 = hnm(iniv)*0.78 |
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| 423 | p(iniv) = d/(a + d + kq*n2) |
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| 424 | |
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| 425 | end if |
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| 426 | end do |
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| 427 | |
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| 428 | ! calcul proprement dit, pour les 3 bandes |
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| 429 | |
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| 430 | do iniv = 1,nivbas |
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| 431 | if (sza <= 89.0) then |
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| 432 | |
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| 433 | bd1(iniv) = delta_lambda(1)*i0(1)*t_o3_1(iniv)*p(iniv)*( & |
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| 434 | exp(-sigma_o2(1,1)*colo2(iniv)) & |
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| 435 | *(w_no_1(1,1)*sigma_no_1(1,1)*exp(-sigma_no_1(1,1)*colno(iniv)) & |
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| 436 | + w_no_2(1,1)*sigma_no_2(1,1)*exp(-sigma_no_2(1,1)*colno(iniv))) & |
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| 437 | + exp(-sigma_o2(2,1)*colo2(iniv)) & |
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| 438 | *(w_no_1(2,1)*sigma_no_1(2,1)*exp(-sigma_no_1(2,1)*colno(iniv)) & |
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| 439 | + w_no_2(2,1)*sigma_no_2(2,1)*exp(-sigma_no_2(2,1)*colno(iniv))) & |
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| 440 | + exp(-sigma_o2(3,1)*colo2(iniv)) & |
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| 441 | *(w_no_1(3,1)*sigma_no_1(3,1)*exp(-sigma_no_1(3,1)*colno(iniv)) & |
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| 442 | + w_no_2(3,1)*sigma_no_2(3,1)*exp(-sigma_no_2(3,1)*colno(iniv))) & |
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| 443 | + exp(-sigma_o2(4,1)*colo2(iniv)) & |
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| 444 | *(w_no_1(4,1)*sigma_no_1(4,1)*exp(-sigma_no_1(4,1)*colno(iniv)) & |
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| 445 | + w_no_2(4,1)*sigma_no_2(4,1)*exp(-sigma_no_2(4,1)*colno(iniv))) & |
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| 446 | + exp(-sigma_o2(5,1)*colo2(iniv)) & |
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| 447 | *(w_no_1(5,1)*sigma_no_1(5,1)*exp(-sigma_no_1(5,1)*colno(iniv)) & |
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| 448 | + w_no_2(5,1)*sigma_no_2(5,1)*exp(-sigma_no_2(5,1)*colno(iniv))) & |
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| 449 | + exp(-sigma_o2(6,1)*colo2(iniv)) & |
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| 450 | *(w_no_1(6,1)*sigma_no_1(6,1)*exp(-sigma_no_1(6,1)*colno(iniv)) & |
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| 451 | + w_no_2(6,1)*sigma_no_2(6,1)*exp(-sigma_no_2(6,1)*colno(iniv))) & |
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| 452 | ) |
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| 453 | |
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| 454 | bd2(iniv) = delta_lambda(2)*i0(2)*t_o3_2(iniv)*p(iniv)*( & |
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| 455 | exp(-sigma_o2(1,2)*colo2(iniv)) & |
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| 456 | *(w_no_1(1,2)*sigma_no_1(1,2)*exp(-sigma_no_1(1,2)*colno(iniv)) & |
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| 457 | + w_no_2(1,2)*sigma_no_2(1,2)*exp(-sigma_no_2(1,2)*colno(iniv))) & |
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| 458 | + exp(-sigma_o2(2,2)*colo2(iniv)) & |
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| 459 | *(w_no_1(2,2)*sigma_no_1(2,2)*exp(-sigma_no_1(2,2)*colno(iniv)) & |
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| 460 | + w_no_2(2,2)*sigma_no_2(2,2)*exp(-sigma_no_2(2,2)*colno(iniv))) & |
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| 461 | + exp(-sigma_o2(3,2)*colo2(iniv)) & |
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| 462 | *(w_no_1(3,2)*sigma_no_1(3,2)*exp(-sigma_no_1(3,2)*colno(iniv)) & |
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| 463 | + w_no_2(3,2)*sigma_no_2(3,2)*exp(-sigma_no_2(3,2)*colno(iniv))) & |
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| 464 | + exp(-sigma_o2(4,2)*colo2(iniv)) & |
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| 465 | *(w_no_1(4,2)*sigma_no_1(4,2)*exp(-sigma_no_1(4,2)*colno(iniv)) & |
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| 466 | + w_no_2(4,2)*sigma_no_2(4,2)*exp(-sigma_no_2(4,2)*colno(iniv))) & |
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| 467 | + exp(-sigma_o2(5,2)*colo2(iniv)) & |
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| 468 | *(w_no_1(5,2)*sigma_no_1(5,2)*exp(-sigma_no_1(5,2)*colno(iniv)) & |
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| 469 | + w_no_2(5,2)*sigma_no_2(5,2)*exp(-sigma_no_2(5,2)*colno(iniv))) & |
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| 470 | + exp(-sigma_o2(6,2)*colo2(iniv)) & |
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| 471 | *(w_no_1(6,2)*sigma_no_1(6,2)*exp(-sigma_no_1(6,2)*colno(iniv)) & |
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| 472 | + w_no_2(6,2)*sigma_no_2(6,2)*exp(-sigma_no_2(6,2)*colno(iniv))) & |
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| 473 | ) |
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| 474 | |
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| 475 | bd3(iniv) = delta_lambda(3)*i0(3)*t_o3_3(iniv)*p(iniv)*( & |
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| 476 | exp(-sigma_o2(1,3)*colo2(iniv)) & |
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| 477 | *(w_no_1(1,3)*sigma_no_1(1,3)*exp(-sigma_no_1(1,3)*colno(iniv)) & |
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| 478 | + w_no_2(1,3)*sigma_no_2(1,3)*exp(-sigma_no_2(1,3)*colno(iniv))) & |
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| 479 | + exp(-sigma_o2(2,3)*colo2(iniv)) & |
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| 480 | *(w_no_1(2,3)*sigma_no_1(2,3)*exp(-sigma_no_1(2,3)*colno(iniv)) & |
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| 481 | + w_no_2(2,3)*sigma_no_2(2,3)*exp(-sigma_no_2(2,3)*colno(iniv))) & |
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| 482 | + exp(-sigma_o2(3,3)*colo2(iniv)) & |
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| 483 | *(w_no_1(3,3)*sigma_no_1(3,3)*exp(-sigma_no_1(3,3)*colno(iniv)) & |
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| 484 | + w_no_2(3,3)*sigma_no_2(3,3)*exp(-sigma_no_2(3,3)*colno(iniv))) & |
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| 485 | + exp(-sigma_o2(4,3)*colo2(iniv)) & |
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| 486 | *(w_no_1(4,3)*sigma_no_1(4,3)*exp(-sigma_no_1(4,3)*colno(iniv)) & |
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| 487 | + w_no_2(4,3)*sigma_no_2(4,3)*exp(-sigma_no_2(4,3)*colno(iniv))) & |
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| 488 | + exp(-sigma_o2(5,3)*colo2(iniv)) & |
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| 489 | *(w_no_1(5,3)*sigma_no_1(5,3)*exp(-sigma_no_1(5,3)*colno(iniv)) & |
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| 490 | + w_no_2(5,3)*sigma_no_2(5,3)*exp(-sigma_no_2(5,3)*colno(iniv))) & |
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| 491 | + exp(-sigma_o2(6,3)*colo2(iniv)) & |
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| 492 | *(w_no_1(6,3)*sigma_no_1(6,3)*exp(-sigma_no_1(6,3)*colno(iniv)) & |
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| 493 | + w_no_2(6,3)*sigma_no_2(6,3)*exp(-sigma_no_2(6,3)*colno(iniv))) & |
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| 494 | ) |
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| 495 | |
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| 496 | tjno(iniv) = bd1(iniv) + bd2(iniv) + bd3(iniv) |
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| 497 | |
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| 498 | else ! night |
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| 499 | tjno(iniv) = 0. |
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| 500 | end if |
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| 501 | end do |
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| 502 | |
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| 503 | end subroutine jno |
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| 504 | |
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| 505 | function indexchim(traceurname) |
|---|
| 506 | |
|---|
| 507 | use tracer_h, only: noms, nqtot, is_chim |
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| 508 | |
|---|
| 509 | implicit none |
|---|
| 510 | |
|---|
| 511 | !======================================================================= |
|---|
| 512 | ! Get index of tracer in chemistry with its name using traceur tab |
|---|
| 513 | ! |
|---|
| 514 | ! version: April 2019 - Yassin Jaziri (update September 2020) |
|---|
| 515 | !======================================================================= |
|---|
| 516 | |
|---|
| 517 | ! input/output |
|---|
| 518 | |
|---|
| 519 | integer :: indexchim ! index of tracer in chemistry |
|---|
| 520 | character(len=*) :: traceurname ! name of traceur to find |
|---|
| 521 | |
|---|
| 522 | ! local variables |
|---|
| 523 | |
|---|
| 524 | integer :: iq, iesp |
|---|
| 525 | |
|---|
| 526 | |
|---|
| 527 | iesp = 0 |
|---|
| 528 | indexchim = 0 |
|---|
| 529 | do iq = 1,nqtot |
|---|
| 530 | if (is_chim(iq)==1) then |
|---|
| 531 | iesp = iesp + 1 |
|---|
| 532 | if (trim(traceurname)==trim(noms(iq))) then |
|---|
| 533 | indexchim = iesp |
|---|
| 534 | exit |
|---|
| 535 | end if |
|---|
| 536 | end if |
|---|
| 537 | end do |
|---|
| 538 | |
|---|
| 539 | if (indexchim==0) then |
|---|
| 540 | print*, 'Error indexchim: wrong traceur name ', trim(traceurname) |
|---|
| 541 | print*, 'Check if the specie ', trim(traceurname),' is in traceur.def' |
|---|
| 542 | print*, 'Check if the specie ', trim(traceurname),' is a chemical species' |
|---|
| 543 | print*, '(option is_chim = 1)' |
|---|
| 544 | call abort |
|---|
| 545 | end if |
|---|
| 546 | |
|---|
| 547 | return |
|---|
| 548 | end function indexchim |
|---|
| 549 | |
|---|
| 550 | end module chimiedata_h |
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