| 1 | real*8 function psv(T) |
|---|
| 2 | ! saturation vapor pressure of H2O ice [Pascal] |
|---|
| 3 | ! input is temperature [Kelvin] |
|---|
| 4 | implicit none |
|---|
| 5 | real*8 T |
|---|
| 6 | |
|---|
| 7 | !-----parametrization 1 |
|---|
| 8 | ! real*8 DHmelt,DHvap,DHsub,R,pt,Tt,C |
|---|
| 9 | ! parameter (DHmelt=6008.,DHvap=45050.) |
|---|
| 10 | ! parameter (DHsub=DHmelt+DHvap) ! sublimation enthalpy [J/mol] |
|---|
| 11 | ! parameter (R=8.314,pt=6.11e2,Tt=273.16) |
|---|
| 12 | ! C = (DHsub/R)*(1./T - 1./Tt) |
|---|
| 13 | ! psv = pt*exp(-C) |
|---|
| 14 | |
|---|
| 15 | !-----parametrization 2 |
|---|
| 16 | ! eq. (2) in Murphy & Koop, Q. J. R. Meteor. Soc. 131, 1539 (2005) |
|---|
| 17 | ! differs from parametrization 1 by only 0.1% |
|---|
| 18 | real*8 A,B |
|---|
| 19 | parameter (A=-6143.7, B=28.9074) |
|---|
| 20 | psv = exp(A/T+B) ! Clapeyron |
|---|
| 21 | |
|---|
| 22 | !-----parametrization 3 |
|---|
| 23 | ! eq. (7) in Murphy & Koop, Q. J. R. Meteor. Soc. 131, 1539 (2005) |
|---|
| 24 | ! psv = exp(9.550426 - 5723.265/T + 3.53068*log(T) - 0.00728332*T) |
|---|
| 25 | |
|---|
| 26 | end |
|---|
| 27 | |
|---|
| 28 | |
|---|
| 29 | |
|---|
| 30 | real*8 function frostpoint(p) |
|---|
| 31 | ! inverse of psv |
|---|
| 32 | ! input is partial pressure [Pascal] |
|---|
| 33 | ! output is temperature [Kelvin] |
|---|
| 34 | implicit none |
|---|
| 35 | real*8 p |
|---|
| 36 | |
|---|
| 37 | !-----inverse of parametrization 1 |
|---|
| 38 | ! real*8 DHmelt,DHvap,DHsub,R,pt,Tt |
|---|
| 39 | ! parameter (DHmelt=6008.,DHvap=45050.) |
|---|
| 40 | ! parameter (DHsub=DHmelt+DHvap) |
|---|
| 41 | ! parameter (R=8.314,pt=6.11e2,Tt=273.16) |
|---|
| 42 | ! frostpoint = 1./(1./Tt-R/DHsub*log(p/pt)) |
|---|
| 43 | |
|---|
| 44 | !-----inverse of parametrization 2 |
|---|
| 45 | ! inverse of eq. (2) in Murphy & Koop (2005) |
|---|
| 46 | real*8 A,B |
|---|
| 47 | parameter (A=-6143.7, B=28.9074) |
|---|
| 48 | frostpoint = A / (log(p) - B) |
|---|
| 49 | |
|---|
| 50 | !-----approximate inverse of parametrization 3 |
|---|
| 51 | ! eq. (8) in Murphy & Koop (2005) |
|---|
| 52 | ! frostpoint = (1.814625*log(p) + 6190.134)/(29.120 - log(p)) |
|---|
| 53 | |
|---|
| 54 | end |
|---|